Tag: M.W=150-200

Recommanded Product: 119-61-9. Authors Wang, H; Qu, JP; Kang, YB in AMER CHEMICAL SOC published article about in [Wang, Hua; Kang, Yan-Biao] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China; [Qu, Jian-Ping] Nanjing Tech Univ, Jiangsu Natl Synerget Innovat Ctr Adv Mat, Sch Chem & Mol Engn, Inst Adv Synth, Nanjing 211816, Peoples R China in 2021.0, Cited 18.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

A recyclable organic photoreductant (1 mol % CBZ6)-catalyzed reductive (pinacol) coupling of aldehydes, ketones, and imines has been developed. Irradiated by purple light (407 nm) using triethylamine as an electron donor, a variety of 1,2-diols and 1,2-diamines could be prepared. The oxidation potential of the excited state of CBZ6 is established as -1.92 V (vs saturated calomel electrode (SCE)). The relative high reductive potential enables the reductive coupling of carbonyl compounds and their derivatives. CBZ6 can be prepared in gram scale and is acid/base- or air-stable. It could be applied in large-scale photoreductive synthesis and recovered in high yield after the reaction.

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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Authors Lan, S; Liu, R; Kong, XW; Liu, JG; Luo, BL; Yang, S; Fang, XQ in AMER CHEMICAL SOC published article about in [Lan, Shouang; Liu, Rui; Kong, Xiangwen; Yang, Shuang; Fang, Xinqiang] Univ Chinese Acad Sci, Ctr Excellence Mol Synth, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350100, Peoples R China; [Lan, Shouang; Liu, Rui; Kong, Xiangwen; Yang, Shuang; Fang, Xinqiang] Univ Chinese Acad Sci, Ctr Excellence Mol Synth, Fujian Inst Res Struct Matter, Key Lab Coal Ethylene Glycol & Its Related Techno, Fuzhou 350100, Peoples R China; [Liu, Jinggong] Guangzhou Univ Chinese Med, Orthoped Dept, Guangdong Prov Hosp Tradit Chinese Med, Affiliated Hosp 2, Guangzhou 510120, Peoples R China; [Luo, Benlong] Pingxiang Univ, Pingxiang 337055, Peoples R China in 2021.0, Cited 65.0. Name: Benzophenone. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

A unique deoxygenative cyclodimerization of alkynyl 1,2-diketones facilitated by Ti((OPr)-Pr-i) (4) is achieved, affording a series of highly functionalized furan products. An unusual C-C bond and C=O bond cleavage of the substrates is observed, and Ti(OiPr)(4) plays triplicate roles in the reaction. Furthermore, the products show uncommon fluorescent emission in the solid state, indicating the potential practical applications of this work.

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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Authors Zhang, HT; Wu, H; Wang, L; Xu, H; He, XM in ELSEVIER published article about in [Zhang, Haitian; Wang, Li; Xu, Hong; He, Xiangming] Tsinghua Univ, Inst Nucl & New Energy Technol, Beijing 100084, Peoples R China; [Wu, Hui] Tsinghua Univ, Sch Mat Sci & Engn, Beijing 100084, Peoples R China in 2021.0, Cited 27.0. Category: thiomorpholine. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

Solid-state electrolytes are regarded as the ?key? materials for enabling the usage of lithium metal in high energy density lithium battery systems. However, recent reports suggest lithium dendrites still exist in solid-state electrolytes after cycling. Moreover, due to the low concentration of lithium dendrite inside solid-state electrolyte and the unique characteristic of lithium, conventional methods such as EDS (Energy Dispersive X-Ray Spectroscopy) cannot detect lithium. Analyzing lithium dendrite in solid-state electrolyte usually requires complicated and expensive equipment such as neutron diffraction, which brings extra barrier to explore the mechanism of growth of lithium dendrite in the solid-state electrolyte and exploring the solution to this problem. In this work, we report a simple and effective method to visualize the existence of lithium metal inside solid-state electrolytes in very early stage. This method may benefit the exploration of the growth mechanism of lithium dendrite inside solid-state electrolytes and solving this problem eventually.

Category: thiomorpholine. Welcome to talk about 119-61-9, If you have any questions, you can contact Zhang, HT; Wu, H; Wang, L; Xu, H; He, XM or send Email.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article 2-Methyltetrahydrofuran as a Solvent of Choice for Spontaneous Metathesis/Isomerization Sequence WOS:000460214700200 published article about RING-CLOSING METATHESIS; OLEFIN METATHESIS; TANDEM CATALYSIS; ISOMERIZATION APPROACH; FRIENDLY SOLVENT; ALLYLIC ALCOHOLS; DECOMPOSITION in [Rajkiewicz, Adam A.; Kajetanowicz, Anna; Grela, Karol] Univ Warsaw, Fac Chem, Biol & Chem Res Ctr, Zwirki & Wigury St 101, PL-02089 Warsaw, Poland; [Skowerski, Krzysztof] Apeiron Synth SA, Dunska 9, PL-54427 Wroclaw, Poland; [Trzaskowski, Bartosz] Univ Warsaw, Ctr New Technol, PL-02097 Warsaw, Poland in 2019, Cited 52. SDS of cas: 90-44-8. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8

A new protocol for ring-closing metathesis/isomerization sequence was developed. The reactions of selected dienes were performed in overheated 2-methyltetrahydrofuran at 120 degrees C and provided a wide range of cyclic vinyl ethers and amides with good yields and selectivities. Computational analysis suggests that the relative yield of products depends on a thermodynamically driven process on the basis of relative stabilities of isomers.

SDS of cas: 90-44-8. Bye, fridends, I hope you can learn more about C14H10O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

In 2019 APPL CATAL A-GEN published article about HIGH-PERFORMANCE; BIO-OIL; BIOMASS; ACTIVATION; CATALYSTS; CATHODES; AEROGELS; PLATFORM; GREEN in [Zhang, Qingqing; Zhang, Chaoyue; Sun, Yingnan; Guo, Yihang; Song, Daiyu] Northeast Normal Univ, Sch Environm, Changchun 130117, Jilin, Peoples R China in 2019, Cited 48. The Name is 4-Methoxybenzyl acetate. Through research, I have a further understanding and discovery of 104-21-2. Application In Synthesis of 4-Methoxybenzyl acetate

Bronsted acidic ionic liquid (BAIL) functionalized hierarchically porous nitrogen-doped carbons (NHPCs) with interesting 3D interconnected macro-meso-microporous structure are successfully prepared by chemical bonding -[C-3][SO3CF3-] (C-3 = PrSO3H) groups throughout the NHPC supports that are obtained via a single step CaCO3 nanoparticle-directed nanocasting approach combined with K2C2O4 chemical activation and urea/melamine self-activation during the process of carbonization of glucose and urea/melamine. By changing initial urea-to-glucose weight ratio in the preparation systems, the macro/meso/micropore proportion of the resulting GU-[C3N] [SO3CF3] catalysts are well-adjusted. The morphological characteristics, porosity properties and chemical structure of the prepared catalysts are well-characterized so that the contribution of the synergistic effect of CaCO3 nanoparticle and K2C2O4 to the formation of hierarchically porous structure is revealed. Owing to super strong Bronsted acidity and unique hierarchically porous structure of the catalysts, they exhibit excellent heterogeneous acid catalytic activity in raw pyrolysis biofuel upgrading via esterification of acetic acid with high boiling point benzyl alcohol or 4-methoxybenzyl alcohol in toluene media, and therefore high acetic acid removal efficiency and efficient production of value-added benzyl acetate or 4-methoxybenzyl acetate are obtained simultaneously. The catalysts also show good reusability in target reactions, attributing to chemical interactions between BAILs and NHPC supports.

Application In Synthesis of 4-Methoxybenzyl acetate. Bye, fridends, I hope you can learn more about C10H12O3, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Recently I am researching about AEROBIC OXIDATION; SCHIFF-BASE; MECHANISTIC INSIGHT; TRIPHENYLPHOSPHINE; AZIRIDINES; KETONES; TEMPO; RING, Saw an article supported by the Hebei Natural Science Foundation of China [B2017205006, B2019205087]; Education Department Foundation of Hebei Province [ZD2018005, QN2019036]; Science Foundation of Hebei Normal University [L2017Z02, L2018B08]. Formula: C13H10O. Published in ELSEVIER SCIENCE SA in LAUSANNE ,Authors: Hao, ZQ; Li, Y; Ma, ZH; Han, ZA; Lin, J; Lu, GL. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone

A series of novel trinuclear ruthenium carbonyl complexes [mu-eta(2)-2-OC6H4-CH=N Ar)](2)Ru-3(CO)(8)[Ar = Ph (8), C6H4-4-Me (9), C6H4-4-CF3 (10), C6H4-4-Cl (11), C6H3-2,6-Me-2 (12), C6H3-2,6-Et-2 (13)] and [mu-eta(2)-2-OC6H4-CH=N-C6H3-2,6(i)Pr(2)]Ru-3(CO)(9) (14) were designed and synthesized. All the seven novel complexes were fully characterized by elemental analysis, IR and NMR spectroscopy. Molecular structures of 8, 11, 13 and 14 were further confirmed by single-crystal X-ray diffraction. The catalytic performance of these complexes in the oxidation of secondary alcohols was explored and it was found the combination of such complexes and N-methylmorpholine-N-oxide (NMO) exhibits high catalytic activities for the oxidation of secondary alcohols, giving the corresponding carbonyl compounds in excellent yields. (C) 2020 Elsevier B.V. All rights reserved.

Formula: C13H10O. Bye, fridends, I hope you can learn more about C13H10O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Quality Control of 3-Nitrobenzaldehyde. In 2021 LETT ORG CHEM published article about PRIMARY ALCOHOLS; TERMINAL ALKYNES; NANOPARTICLES; AMINE; WATER; GAS in [Yu, Min] Nanjing Xiaozhuang Univ, Sch Environm Sci, Nanjing 211171, Peoples R China; [Yu, Min; Wu, Chaolong; Zhou, Li; Yao, Xiaoquan] Nanjing Univ Aeronaut & Astronaut, Coll Mat Sci & Technol, Nanjing 210016, Peoples R China; [Zhu, Li] Nanjing Med Univ, Sch Pharm, Nanjing 210029, Peoples R China in 2021, Cited 59. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6.

The oxidation of aldehydes is an efficient methodology for the synthesis of carboxylic acids. Herein we hope to report a simple, efficient and recyclable protocol for aerobic oxidation of aldehydes to carboxylic acid by using C3N4 supported silver nanoparticles (Ag/C3N4) as a catalyst in aqueous solution under mild conditions. Under standard conditions, the corresponding carboxylic acids can be obtained in good to excellent yields. In addition, Ag/C3N4 is convenient for recovery and could be reused three times with satisfactory yields.

Quality Control of 3-Nitrobenzaldehyde. Bye, fridends, I hope you can learn more about C7H5NO3, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Recommanded Product: 3-Nitrobenzaldehyde. In 2021 J IRAN CHEM SOC published article about SELECTIVE SYNTHESIS; ANTITUMOR-ACTIVITY; DERIVATIVES; CATALYST; SILICA; SYSTEM; ROUTE; WATER in [Gulati, Susheel; Singh, Rajvir; Sangwan, Suman; Rana, Suprita] Chaudhary Charan Singh Haryana Agr Univ, Dept Chem, Hisar 125004, Haryana, India in 2021, Cited 29. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6.

An efficient and facile synthesis of substituted novel benzimidazoles (3a-3h) mediated by fruit juices viz.Cocos nuciferaL. juice,Citrus limettajuice andCitrus sinensisL. juice, via condensation of substituted aldehydes (1a-1h) ando-phenylenediammine (2a) under solvent-free condition at room temperature is presented in this paper. The purity of compounds was confirmed by melting point and thin layer chromatography. All synthesized compounds (3a-3h) were fully characterized via NMR and FTIR spectral data and evaluated for in vitro herbicidal activity againstRaphanus sativusL. (Radish) seeds. The compounds (3a-3h) were also evaluated for their antibacterial activity againstErwinia cartovoraandXanthomonas citriby inhibition zone method. Antifungal activity was also determined againstRhizoctonia solaniandColletotrichum gloeosporioidesby poisoned food techniques method. From activity data, it was found that compounds3dand3ewere most active againstR.sativusL. (root) andR.sativusL. (shoot), respectively. Compound3ghas shown maximum inhibition zone i.e. 8.00 mm againstE.cartovoraat 2000 mu g/mL concentration. MaximumX.citriigrowth was inhibited by compounds3ashowing inhibition zone 5.20 mm at highest concentration. Compound3fwas found most active againstR.solani and C.gloeosporioidesfungus at 2000 mu g/mL concentration. In comparison with the conventional methods, the present method complies with several key requirements of green chemistry principles such as the utilization of renewable feedstock, auxiliary aqueous conditions and reduces waste with the use of nature-derived catalyst. Therefore, the present method offers an attractive option because of its ecological safety, environmental acceptance, cost effective and easy workup process. [GRAPHICS] .

Recommanded Product: 3-Nitrobenzaldehyde. Welcome to talk about 99-61-6, If you have any questions, you can contact Gulati, S; Singh, R; Sangwan, S; Rana, S or send Email.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Antidiabetic effect of Opuntia dillenii seed oil on streptozotocin-induced diabetic rats WOS:000488027500004 published article about ANTIOXIDANT; EXTRACT; GLUCOSE; METABOLISM in [Bouhrim, Mohamed; Ouassou, Hayat; Loukili, El Hassania; Ramdani, Mohammed; Mekhfi, Hassane; Ziyyat, Abderrahim; Legssyer, Abdelkhaleq; Aziz, Mohammed; Bnouham, Mohamed] Univ Mohamed First, Fac Sci, Oujda, Morocco in 2019, Cited 39. Formula: C14H10O. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8

Objective: To assess the antidiabetic effect of Opuntia dillenii seed oil on rats with diabetes mellitus. Methods: A rat diabetes model was established by intraperitoneal injection of rats with 50 mg/kg streptozotocin. Thirty albino Wistar rats were divided into five groups: the diabetic control group and normal control group were treated only with distilled water, two diabetic groups received 1 and 2 mL/kg of oil per day, respectively, for 30 days and one diabetic group received 2 mg/kg of glibenclamide. In addition, blood glucose was determined weekly. Body weight, average daily food, water intake and urinary volume of each animal were determined before and after the treatment period. After the treatment period, hepatic glycogen was determined using the anthrone reagent, and glycosuria, total cholesterol, triglycerides, alanine aminotransferase, aspartate aminotransferase, urea, creatinine and uric acid were estimated using common clinical diagnostic kits. Results: Oral intake of the oil at 1 and 2 mL/kg for the diabetic animals significantly diminished blood glucose, glycosuria, total cholesterol, triglycerides, alanine aminotransferase, aspartate aminotransferase, urea, creatinine and uric acid, accompanied by a noticeable elevation in the amount of hepatic glycogen in comparison with the diabetic control group. Similarly, Opuntia dillenii seed oil significantly increased the food intake and decreased the urinary volume per day in treated rats of the same groups in comparison with the period before the treatment intervention and attenuated body weight loss in the diabetic rats. Moreover, this effect of the oil was dose dependent. On the other hand, the oil did not affect their need for water. Conclusions: The results show that Opuntia dillenii seed oil has a very important antidiabetic effect on streptozotocin-induced diabetic rats. Hence, we suggest it as a preventive control of diabetes mellitus.

Formula: C14H10O. About Anthrone, If you have any questions, you can contact Bouhrim, M; Ouassou, H; Loukili, E; Ramdani, M; Mekhfi, H; Ziyyat, A; Legssyer, A; Aziz, M; Bnouham, M or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Synthesis and characterization of novel polyimides based on 10,10-bis[4-(4-aminophenoxy)-3-methylphenyl]-9(10H)-anthrone WOS:000544441700006 published article about LOW-DIELECTRIC-CONSTANT; T-G; IMIDE)S; DIANHYDRIDE; POLYAMIDES; DIAMINE; PROPANE in [Kuang, Lu; Zhong, Ming; Sang, Xiao-Yan; Huang, Zhen-Zhong] Jiangxi Normal Univ, Key Lab Funct Small Organ Mol, Minist Educ, Nanchang 330022, Jiangxi, Peoples R China in 2020, Cited 30. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8. Safety of Anthrone

10,10-Bis[4-(4-aminophenoxy)-3-methylphenyl]-9(10H)-anthrone, as a novel aromatic diamine, was synthesized from anthrone by three-step process. A series of polyimides containing methyl substituents and 9(10H)-anthrone pendant groups was prepared from this diamine with various aromatic dianhydridesviathe poly(amic acid) (PAA) precursors and subsequent thermal or chemical imidization procedure. Inherent viscosities of PAAs are between 0.87 and 1.58 dL/g, and the corresponding polyimides have the weight-average molecular weight and number-average molecular weight in the range of 49,400-64,200 and 28,700-37,700, respectively. Most of the polyimides obtained through the chemical cyclodehydration method are soluble in NMP, DMF, DMAc, Py andm-cresol at room temperature. These polyimides have glass transition temperatures of 289-313 degrees C, 10% weight loss temperatures of 484-524 degrees C, char yields of 55-63% at 800 degrees C, and temperature at the maximum-rate degradation of 560-584 degrees C in nitrogen, respectively. The polyimide films obtained through the thermal imidization have tensile strength of 76.43-119.74 MPa, elongation at break of 6.93-12.33%, and tensile modulus of 1.91-2.38 GPa.

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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem