Tag: M.W=150-200

Authors Olyaei, A; Aghajanzadeh, A; Feizy, E; Sadeghpour, M in WILEY-V C H VERLAG GMBH published article about DOMINO REACTIONS; 4-COMPONENT SYNTHESIS; NATURAL-PRODUCTS; EFFICIENT; CATALYST; PHENAZINES; BENZOPHENAZINES; DABCO; BENZO in [Olyaei, Abolfazl; Aghajanzadeh, Atiye; Feizy, Elaheh] Payame Noor Univ PNU, Dept Chem, POB 19395-4697, Tehran, Iran; [Sadeghpour, Mahdieh] Islamic Azad Univ, Dept Chem, Takestan Branch, Takestan, Iran in 2021, Cited 35. Category: thiomorpholine. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6

A simple and efficient synthesis of novel 6,6 ‘-(arylmethylene)bis(benzo[a]phenazin-5-ol) derivatives has been developed via a sequential one-pot, two-step, pseudo-five-component tandem reaction starting from 2-hydroxynaphthalene-1,4-dione, o-phenylenediamine, and aromatic aldehydes in the presence of 2-aminopyridine as co-catalyst and p-TsOH as catalyst at 90 degrees C under solvent-free conditions. This sequential green process offers several advantages, such as operational simplicity, high yield, low cost, easy handling, clean reactions, absence of any tedious work-up, and purification of products by non-chromatographic methods.

About 3-Nitrobenzaldehyde, If you have any questions, you can contact Olyaei, A; Aghajanzadeh, A; Feizy, E; Sadeghpour, M or concate me.. Category: thiomorpholine

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

In 2021.0 TALANTA published article about PHASE MICROEXTRACTION; ANALYTICAL-CHEMISTRY; CHROMATOGRAPHY; CONTAMINANTS; AUTOMATION; FILTERS in [Will, Camila; Huelsmann, Ricardo Dagnoni; Mafra, Gabriela; Carasek, Eduardo] Univ Fed Santa Catarina, Dept Quim, BR-88040900 Florianopolis, SC, Brazil; [Carasek, Eduardo] Univ Fed Ciencias Saude Porto Alegre, Dept Farmacociencias, BR-90050170 Porto Alegre, RS, Brazil; [Anderson, Jared L.] Iowa State Univ, Dept Chem, Ames, IA 50011 USA in 2021.0, Cited 38.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9. Quality Control of Benzophenone

In this work, a novel and high-throughput parallel-dispersive droplet extraction (Pa-DDE) based on in situ formation of the hydrophobic MILs ([Co(C4IM)(4)(+2)]2[NTf2-], [Ni(C4IM)(4)(+2)]2[NTf2-] and [Ni(BeIM)(4)(+2)]2[NTf2]) is demonstrated, for the first time, for the determination of benzophenone, metolachlor, triclocarban, pendimethalin, 4-methylbenzylidene camphor, and 2-ethylhexyl-4-methoxycinnamate from aqueous environmental samples. This experimental setup is comprised of a 96-well plate system containing a set of magnetic pins which were used to collect the MIL droplet after in situ formation. This consolidated system enabled simultaneous extraction of up to 96 samples and MIL production in one step. Using this apparatus, sample preparation times of 0.78 min per sample was achieved. The experimental conditions were carefully optimized using uni and multivariate approaches. The optimal conditions were comprised of sample volume of 1.25 mL, 4 mg of [Co (C4IM)(4)(+2)]2[Cl] and 40 mu L of LiNTf2 for the in situ formation, and dilution in 20 mu L of acetonitrile. The analytical parameters of merit were successfully determined with LODs ranging from 7.5 to 25 mu g L-1 and coefficients of determination higher than 0.989. Intraday and interday precision ranged from 6.4 to 20.6% (n = 3) and 11.6-22.9% (n = 9), respectively, with analyte relative recovery ranging between 53.9 and 129.1%.

Quality Control of Benzophenone. About Benzophenone, If you have any questions, you can contact Will, C; Huelsmann, RD; Mafra, G; Merib, J; Anderson, JL; Carasek, E or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Formula: C13H10O. Recently I am researching about PHOTOREDOX-CATALYZED SULFONYLATION; SULFUR-DIOXIDE; INSERTION; INHIBITORS; SULFONES, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21871053, 21532001]; Leading Innovative and Entrepreneur Team Introduction Program of Zhejiang [2019R01005]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Yao, YF; Yin, ZQ; Chen, WY; Xie, WL; He, FS; Wu, J. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone

A three-component reaction of aryldiazonium tetrafluoroborates, sodium metabisulfite, and 3-azido-2-methylbut-3-en-2-ol under mild conditions is described. By using abundant and cheap sodium metabisulfite as the sulfur dioxide surrogate, this protocol features good functional group compatibility, affording 2-arylsulfonylacetonitriles in moderate to good yields. The reaction proceeds smoothly at room temperature without the need of any catalysts or additives. Moreover, the synthetic utility of this method is demonstrated by the transformation of 2-arylsulfonylacetonitrile into 2-arylsulfonyl acetamide and 2-arylsulfonylethylamine.

Formula: C13H10O. About Benzophenone, If you have any questions, you can contact Yao, YF; Yin, ZQ; Chen, WY; Xie, WL; He, FS; Wu, J or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Computed Properties of C13H10O. Authors Etemadi-Davan, E; Khalili, D; Banazadeh, AR; Sadri, G; Arshad, P in SPRINGER published article about in [Etemadi-Davan, Elham; Khalili, Dariush; Sadri, Ghazal; Arshad, Pourya] Shiraz Univ, Dept Chem, Shiraz 71454, Iran; [Banazadeh, Ali Reza] Texas Tech Univ, Dept Chem & Biochem, Lubbock, TX 79409 USA in 2021.0, Cited 60.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

A practical and heterogeneously catalyzed Stille, homo-coupling, and Suzuki carbonylation reaction has been reported using Pd nanoparticles supported on amino-vinyl silica-functionalized magnetic carbon nanotube (CNT@Fe3O4@SiO2-Pd) for the efficient synthesis of symmetrical and unsymmetrical diaryl ketones from aryl iodides. A wide variety of symmetrical and unsymmetrical diaryl ketones were obtained in high yields under CO gas-free conditions using Mo(CO)(6) as an efficient carbonyl source. Considering the atom economy of Ph3SnCl, less than an equimolar amount can be applied in Stille transformation, which is of great importance due to the toxicity of organotin derivatives. Moreover, no phosphine ligand and external reducing agent were necessary in these coupling carbonylation reactions. This heterogeneous Pd catalyst offers high activity with very low palladium leaching. Finally, the catalyst can be reused and recycled for six steps without loss in activity, exhibiting good example of sustainable methodology. Graphic abstract

Computed Properties of C13H10O. About Benzophenone, If you have any questions, you can contact Etemadi-Davan, E; Khalili, D; Banazadeh, AR; Sadri, G; Arshad, P or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

In 2021.0 J ORGANOMET CHEM published article about AEROBIC OXIDATION; SCHIFF-BASE; MECHANISTIC INSIGHT; TRIPHENYLPHOSPHINE; AZIRIDINES; KETONES; TEMPO; RING in [Hao, Zhiqiang; Li, Ying; Han, Zhangang; Lin, Jin] Hebei Normal Univ, Coll Chem & Mat Sci, Natl Demonstrat Ctr Expt Chem Educ, Hebei Key Lab Organ Funct Mol, Shijiazhuang 050024, Hebei, Peoples R China; [Ma, Zhihong] Hebei Med Univ, Sch Pharm, Shijiazhuang 050017, Hebei, Peoples R China; [Lu, Guo-Liang] Univ Auckland, Auckland Canc Soc, Fac Med & Hlth Sci, Res Ctr, Private Bag 92019, Auckland 1142, New Zealand in 2021.0, Cited 46.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9. HPLC of Formula: C13H10O

A series of novel trinuclear ruthenium carbonyl complexes [mu-eta(2)-2-OC6H4-CH=N Ar)](2)Ru-3(CO)(8)[Ar = Ph (8), C6H4-4-Me (9), C6H4-4-CF3 (10), C6H4-4-Cl (11), C6H3-2,6-Me-2 (12), C6H3-2,6-Et-2 (13)] and [mu-eta(2)-2-OC6H4-CH=N-C6H3-2,6(i)Pr(2)]Ru-3(CO)(9) (14) were designed and synthesized. All the seven novel complexes were fully characterized by elemental analysis, IR and NMR spectroscopy. Molecular structures of 8, 11, 13 and 14 were further confirmed by single-crystal X-ray diffraction. The catalytic performance of these complexes in the oxidation of secondary alcohols was explored and it was found the combination of such complexes and N-methylmorpholine-N-oxide (NMO) exhibits high catalytic activities for the oxidation of secondary alcohols, giving the corresponding carbonyl compounds in excellent yields. (C) 2020 Elsevier B.V. All rights reserved.

About Benzophenone, If you have any questions, you can contact Hao, ZQ; Li, Y; Ma, ZH; Han, ZA; Lin, J; Lu, GL or concate me.. HPLC of Formula: C13H10O

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Graphene Oxide Functionalized Organic-Inorganic Hybrid (GO-Si-NH2-PMo): An Efficient and Green Catalyst for the Synthesis of Tetrahydrobenzo[b]pyran Derivatives WOS:000477282500001 published article about ONE-POT SYNTHESIS; CONVENIENT SYNTHESIS; PYRAN DERIVATIVES; HETEROPOLY ACIDS; NIFE2O4; LIQUID in [Ataie, Farideh; Davoodnia, Abolghasem] Islamic Azad Univ, Mashhad Branch, Dept Chem, Mashhad 9175687119, Razavi Khorasan, Iran; [Khojastehnezhad, Amir] Ferdowsi Univ Mashhad, Fac Sci, Dept Chem, Mashhad 917751436, Razavi Khorasan, Iran in 2021, Cited 46. Application In Synthesis of 3-Nitrobenzaldehyde. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6

In this study, a graphene oxide (GO) functionalized organic-inorganic hybrid was prepared by covalently immobilization of organic (3-aminopropyltrimethoxysilane) and inorganic (H3PMo12O40) groups on the basal plane of GO. Structure of catalyst was characterized with different analysis such as FT-IR, SEM, TEM, EDS, WDX, XRD, and TGA. All analyses approve the successful covalently immobilization of organic and inorganic parts on the GO. The activity of catalyst has been tested for the synthesis of tetrahydrobenzo[b]pyran derivatives under solvent-free condition in short reaction time and good to excellent yields. [GRAPHICS] .

About 3-Nitrobenzaldehyde, If you have any questions, you can contact Ataie, F; Davoodnia, A; Khojastehnezhad, A or concate me.. Application In Synthesis of 3-Nitrobenzaldehyde

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Application In Synthesis of Benzophenone. Recently I am researching about NICKEL PHOSPHIDE; HYDROGEN EVOLUTION; PRIMARY AMINES; DOPED CARBON; CHEMOSELECTIVE HYDROGENATION; SELECTIVE HYDROGENATION; MOLECULAR-HYDROGEN; GENERAL-SYNTHESIS; NANOPARTICLES; EFFICIENT, Saw an article supported by the JSPS KAKENHIMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of ScienceGrants-in-Aid for Scientific Research (KAKENHI) [26105003, 17H03457, 18H01790, 20H02523, 20H05879]; Cooperative Research Program of Institute for Catalysis, Hokkaido University [19A1002, 20B1027]; Nanotechnology Platform Program at Hokkaido University, Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan [A-20-HK-0011]; Nanotechnology Open Facilities in Osaka University, Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan [A-20-OS-0025]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Sheng, M; Fujita, S; Yamaguchi, S; Yamasaki, J; Nakajima, K; Yamazoe, S; Mizugaki, T; Mitsudome, T. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone

The development of metal phosphide catalysts for organic synthesis is still in its early stages. Herein, we report the successful synthesis of single-crystal cobalt phosphide nanorods (Co2P NRs) containing coordinatively unsaturated Co-Co active sites, which serve as a new class of air-stable, highly active, and reusable heterogeneous catalysts for the reductive amination of carbonyl compounds. The Co2P NR catalyst showed high activity for the transformation of a broad range of carbonyl compounds to their corresponding primary amines using an aqueous ammonia solution or ammonium acetate as a green amination reagent at 1 bar of H-2 pressure; these conditions are far milder than previously reported. The air stability and high activity of the Co2P NRs is noteworthy, as conventional Co catalysts are air-sensitive (pyrophorous) and show no activity for this transformation under mild conditions. P-alloying is therefore of considerable importance for nanoengineering air-stable and highly active non-noble-metal catalysts for organic synthesis.

About Benzophenone, If you have any questions, you can contact Sheng, M; Fujita, S; Yamaguchi, S; Yamasaki, J; Nakajima, K; Yamazoe, S; Mizugaki, T; Mitsudome, T or concate me.. Application In Synthesis of Benzophenone

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Recently I am researching about LIMITED ENGLISH PROFICIENCY; PATIENT ACTIVATION MEASURE; EMERGENCY-DEPARTMENT USE; HEALTH-CARE SERVICES; CHILDREN; PARENTS; DISPARITIES; OUTCOMES; CONTINUITY; INSURANCE, Saw an article supported by the Gordon and Betty Moore FoundationGordon and Betty Moore Foundation. Published in AMER ACAD PEDIATRICS in ELK GROVE VILLAGE ,Authors: DeCamp, LR; Godage, SK; Araujo, DV; Cortez, JD; Wu, LX; Psoter, KJ; Quintanilla, K; Rodri’guez, TR; Polk, S. The CAS is 104-21-2. Through research, I have a further understanding and discovery of 4-Methoxybenzyl acetate. Computed Properties of C10H12O3

BACKGROUND AND OBJECTIVES: Latino children in immigrant families experience health care disparities. Text messaging interventions for this population may address disparities. The objective of this study was to evaluate the impact of a Spanish-language text messaging intervention on infant emergency department use and well care and vaccine adherence. METHODS: The Salud al Dia intervention, an educational video and interactive text messages throughout the child’s first year of life, was evaluated via randomized controlled trial conducted in an urban, academic pediatric primary care practice from February 2016 to December 2017. Inclusion criteria were publicly insured singleton infant < 2 months of age; parent age > 18, with Spanish as the preferred health care language; and at least 1 household cellular phone. Primary outcomes were abstracted from the electronic medical record at age 15 months. Intention-to-treat analyses were used. RESULTS: A total of 157 parent-child dyads were randomly assigned to Salud al Dia (n = 79) or control groups (n = 78). Among all participants, mean parent age was 29.3 years (SD: 6.2 years), mean years in the United States was 7.3 (SD: 5.3 years), and 87% of parents had limited or marginal health literacy. The incidence rate ratio for emergency department use for the control versus intervention group was 1.48 (95% confidence interval: 1.04-2.12). A greater proportion of intervention infants received 2 flu vaccine doses compared with controls (81% vs 67%; P = .04). CONCLUSIONS: This Spanish-language text messaging intervention reduced emergency department use and increased flu vaccine receipt among a population at high risk for health care disparities. Tailored text message interventions are a promising method for addressing disparities.

Computed Properties of C10H12O3. About 4-Methoxybenzyl acetate, If you have any questions, you can contact DeCamp, LR; Godage, SK; Araujo, DV; Cortez, JD; Wu, LX; Psoter, KJ; Quintanilla, K; Rodri’guez, TR; Polk, S or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article HFIP-mediated 2-aza-Cope rearrangement: metal-free synthesis of alpha-substituted homoallylamines at ambient temperature WOS:000640673100001 published article about FLUORINATED ALCOHOLS in [Gadde, Karthik; Maes, Bert U. W.; Abbaspour Tehrani, Kourosch] Univ Antwerp, Dept Chem, Groenenborgerlaan 171, B-2020 Antwerp, Belgium in 2021.0, Cited 80.0. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6. Application In Synthesis of 3-Nitrobenzaldehyde

An efficient metal-free strategy for the synthesis of alpha-substituted homoallylamine derivatives has been developed via a 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP)-promoted 2-aza-Cope rearrangement of aldimines, generated in situ by condensation of aldehydes with easily accessible 1,1-diphenylhomoallylamines. This reaction provides rapid access to alpha-substituted homoallylamines with excellent functional group tolerance and yields. The reaction takes place at room temperature and no chromatographic purification is required for product isolation. The synthetic utility of the current method is further demonstrated by the transformation of the obtained benzophenone ketimines into N-unprotected homoallylamines, an alpha-amino alcohol and an alpha-amino amide.

Application In Synthesis of 3-Nitrobenzaldehyde. About 3-Nitrobenzaldehyde, If you have any questions, you can contact Gadde, K; Maes, BUW; Tehrani, KA or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Formula: C14H10O. In 2021 ORG LETT published article about REACTIVITY in [Ueno, Keisuke; Nishii, Yuji; Miura, Masahiro] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan in 2021, Cited 46. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8.

Herein, we disclose a unique directing effect of 9-substituted triptycenes in electrophilic substitution to achieve the regioselective functionalization of the triptycene core. The Hirshfeld population analysis was adopted to predict the selectivity in electrophilic substitution. TMS and t-Bu groups were found to considerably accelerate the reaction at C2 positions to produce C3symmetric isomers. Correlation between distortion and charge distribution within benzene rings was systematically examined.

Formula: C14H10O. About Anthrone, If you have any questions, you can contact Ueno, K; Nishii, Y; Miura, M or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem