Tag: M.W=150-200

Authors Tang, JN; Sun, YB; Tang, QF; Sun, YM in ELSEVIER published article about IMPROVED EFFICIENCY; RECENT PROGRESS; DESIGN; DONOR; CONJUGATION; STRATEGY; AIEGENS; GREEN; HOST in [Tang, Jinan; Sun, Yibai] Southeast Univ, Dept Chem & Pharmaceut Engn, Chengxian Coll, Nanjing 210088, Jiangsu, Peoples R China; [Tang, Qifeng; Sun, Yueming] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Jiangsu, Peoples R China in 2021.0, Cited 53.0. Application In Synthesis of Benzophenone. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

Endowing thermally activated delayed fluorescence (TADF) emitter with aggregation-induced emission (AIE) peculiarity is of great significance for realizing more promising commercial applications. Herein, two new dualemitting-cores emitters with a structure of acceptor-donor-donor-acceptor (A-D-D-A), namely 2DBT-BZ-2Cz and 2DFT-BZ-2Cz, were designed and synthesized to explore their luminescence trait. The emitters, adopting dual carbazole as donor segments and dual phenyl ketone in peripheral skeleton as electron acceptor units, were featured with small singlet (S-1)-triplet (T-1) splitting energy (LEST) of 0.02 eV and 0.01 eV. The efficient thermally activated delayed fluorescence (TADF) characteristics and aggregation-induced emission property make them suitable for nondoped OLED devices. The solution-processed green OLEDs based on 2DBT-BZ-2Cz demonstrated greater device performance with current efficiency of 20.7 cd A(-1) and maximum luminescence of 10,000 cd m(-2). This work thus provides the direction to explore luminogens of dual-emitting-cores with TADF and AIE features as promising candidates in solid state lighting.

Application In Synthesis of Benzophenone. About Benzophenone, If you have any questions, you can contact Tang, JN; Sun, YB; Tang, QF; Sun, YM or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Recently I am researching about CATALYZED OXIDATIVE SYNTHESIS; ONE-POT SYNTHESIS; 4(3H)-QUINAZOLINONE DERIVATIVES; CASCADE SYNTHESIS; BENZYL ALCOHOLS; QUINAZOLINONES; METAL; EFFICIENT; SILICA; OXIDE, Saw an article supported by the University Grants CommissionUniversity Grants Commission, India; Council of Scientific and Industrial Research, New Delhi, IndiaCouncil of Scientific & Industrial Research (CSIR) – India. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Gupta, R; Arora, G; Yadav, P; Dixit, R; Srivastava, A; Sharma, RK. The CAS is 99-61-6. Through research, I have a further understanding and discovery of 3-Nitrobenzaldehyde. Product Details of 99-61-6

In the present work, we report the design and fabrication of a copper-containing ionic liquid supported magnetic nanocatalyst via a convenient and straightforward synthetic approach for the formation of 2-phenylquinazolin-4(3H)-ones using o-aminobenzamide and benzaldehydes as the reaction partners. The successful formation and properties of the as-prepared catalyst have been thoroughly investigated using diverse physico-chemical techniques including FT-IR, XRD, FE-SEM, TEM, ICP, VSM, BET and TGA. Using this nanocatalytic system, a variety of 2-phenylquinazolin-4(3H)-ones are synthesized in excellent yields with operational ease and short reaction times in an environmentally preferable solvent under open air and without using any external oxidizing agent. Besides, the catalyst possessed facile magnetic recoverability and remarkable reusability for six consecutive runs without any appreciable decrease in the catalytic efficiency.

About 3-Nitrobenzaldehyde, If you have any questions, you can contact Gupta, R; Arora, G; Yadav, P; Dixit, R; Srivastava, A; Sharma, RK or concate me.. Product Details of 99-61-6

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

In 2019 IND CROP PROD published article about GENOME SEQUENCE; EXPRESSION; CASBENE; PROSTRATIN; PATHWAY; ANALOGS; CLONING; PLANTS in [Zhang, Kaikai; Yang, Yanfang; Qiu, Deyou] Chinese Acad Forestry, Res Inst Forestry, Key Lab Tree Breeding & Cultivat, State Key Lab Tree Genet & Breeding,State Forestr, Beijing 100091, Peoples R China; [Zhang, Kaikai; Chen, Duanfen; Yao, Zhiwang; Li, Yunfeng] Agr Univ Hebei, Coll Hort, Baoding 071001, Peoples R China; [Fan, Wei] Chinese Acad Forestry, State Key Lab Tree Genet & Breeding, Beijing 100091, Peoples R China; [Huang, Zhongwen] Henan Inst Sci & Technol, Henan Collaborat Innovat Ctr Modern Biol Breeding, Xinxiang 453003, Henan, Peoples R China in 2019, Cited 30. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8. Formula: C14H10O

12-Deoxyphorbol-13-phenylacetate (DPP), found in Euphorbia resinifera, is a prototype of a new class of phorbol derivatives that function as protein kinase C activators with potent anti-tumor-promoting activity. To better understand the biosynthesis of DPP in E. resinifera and develop methods for its production, we used next-generation sequencing technologies to build a transcriptome dataset. We obtained a total of approximately 27,102,078 clean reads that were assembled into 90,448 unigenes. Of those, 129 and 59 unigenes were identified in the Terpenoid Backbone Biosynthesis (TBB) (KEGG map00900) and the Diterpenoid Biosynthesis (DB) (KEGG map00904) pathways, respectively. We investigated the expression patterns of 23 DPP biosynthesis-related genes and validated the results by quantitative real time PCR. The results showed that CMK (4-diphosphocytidyl-2-C-methyl-o-erythritol kinase), MECS (2-C-methyl-D-erythritol 2,4-cyclodiphosphate synthase), HDS (1-hydroxy-2-methyl-2-(E)-butenyl 4-diphosphate synthase), and IPI (Isopentenyl-diphosphate Delta-isomerase) of the methylerythritol 4-phosphate (MEP) pathway had a higher expression compared to other genes of TBB, whereas the expression levels of genes involved in the mevalonic acid (MVA) pathway were relatively lower and not significantly different from each other. Furthermore, the expression of the 23 genes in root, stem and young stem differed, and the statistical results indicated that HMGS (Hydroxymethylglutaryl-CoA synthase), MVK (mevalonic acid), MECT (2-C-methyl-D-erythritol 4-phosphate cytidylyltransferase), MECS, HDS and IPI in the TBB pathway as well as KS in the DB pathway were significantly and positively correlated with the CS (casbene synthase) gene. These results suggested that both cytosol-localized MVA and plastid-localized MEP pathways may have a significant contribution in DPP accumulation, with MEP pathway playing a dominant role. To the best of our knowledge, this study is the first transcriptome analysis of E. resinifera and the results reported here will aid the identification of functional genes and better understanding of DPP biosynthesis.

About Anthrone, If you have any questions, you can contact Zhang, KK; Fan, W; Huang, ZW; Chen, DF; Yao, ZW; Li, YF; Yang, YF; Qiu, DY or concate me.. Formula: C14H10O

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Recommanded Product: 99-61-6. I found the field of Chemistry very interesting. Saw the article Asymmetric Synthesis of 3-Methyleneindolines via Rhodium(I)-Catalyzed Alkynylative Cyclization of N-(o-Alkynylaryl)imines published in 2021.0, Reprint Addresses He, CY; Chu, WD; Liu, QZ (corresponding author), China West Normal Univ, Coll Chem & Chem Engn, Chem Synth & Pollut Control Key Lab Sichuan Prov, Nanchong 637002, Peoples R China.. The CAS is 99-61-6. Through research, I have a further understanding and discovery of 3-Nitrobenzaldehyde.

The first asymmetric synthesis of 3-methyleneindolines from alkynyl imines has been developed via a rhodium-catalyzed tandem process: regioselective alkynylation of the internal alkynes and subsequent intramolecular addition to the imines. The reaction proceeded with unconventional chemo-selectivity and provided 3-methyleneindolines with good yields (up to 82% yield) and high enantioselectivities (up to 97% ee). Moreover, this transformation also features mild reaction conditions, perfect atom economy, and a broad substrate scope.

Recommanded Product: 99-61-6. About 3-Nitrobenzaldehyde, If you have any questions, you can contact Yuan, SY; Yan, QQ; Wang, D; Dan, TT; He, L; He, CY; Chu, WD; Liu, QZ or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article 4-Imidazol-1-yl-butane-1-sulfonic acid ionic liquid: Synthesis, structural analysis, physical properties and catalytic application as dual solvent-catalyst WOS:000473970200001 published article about 4-(SUCCINIMIDO)-1-BUTANE SULFONIC-ACID; VITAMIN-E; EFFICIENT ORGANOCATALYST; HYDROGEN SULFATE; ACETYLATION; SUCCINATE; BIOCATALYSIS; DERIVATIVES; EXPRESSION; AMINES in [Khaligh, Nader Ghaffari; RafieJohan, Mohd; Ching, Juan Joon] Univ Malaya, Nanotechnol & Catalysis Res Ctr, Inst Postgrad Studies, 3rd Floor,Block A, Kuala Lumpur 50603, Malaysia; [Mihankhah, Taraneh] Kharazmi Univ, Fac Engn, Civil Engn Dept, Tehran, Iran in 2019, Cited 51. The Name is 4-Methoxybenzyl acetate. Through research, I have a further understanding and discovery of 104-21-2. Name: 4-Methoxybenzyl acetate

4-Imidazol-1-yl-butane-1-sulfonic acid (ImBu-SO3H) has been successfully synthetized and fully characterized by FT-IR and high-resolution NMR spectroscopy (H-1, C-13). The plausible alternative structures of ImBu-SO3H were discussed on the basis of its NMR data. The ionic liquid showed interesting dual solvent-catalyst property, which was studied experimentally for the acetylation of a variety of functionalized alcohols, phenols, thiols, amines and a-tocopherol (a-CTP) as the most active form of vitamin E with acetic anhydride and which provided good yields within a short reaction time. ImBu-SO3H was successfully recycled by product extraction with an average recovered yield of 82% for 5 subsequent runs. The catalytic activity of the recycled ImBu-SO3H showed almost no loss even after five consecutive runs. [GRAPHICS] .

Name: 4-Methoxybenzyl acetate. About 4-Methoxybenzyl acetate, If you have any questions, you can contact Khaligh, NG; Mihankhah, T; RafieJohan, M; Ching, JJ or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

In 2021.0 APPL CATAL A-GEN published article about ZIEGLER-NATTA CATALYSTS; INTERNAL DONORS; ELECTRON-DONORS; TICL4 in [Maslov, D. K.; Bukatov, G. D.] Boreskov Inst Catalysis SB RAS, Novosibirsk, Russia in 2021.0, Cited 21.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9. Category: thiomorpholine

Propylene polymerization titanium-magnesium catalysts (TMCs) were synthesized from different magnesium compounds with diphenylketone (DPK) as the internal donor. The catalysts differed by an order of magnitude and more in the content of titanium and donor, activity, specific surface area and pore size. Sizes of MgCl2 crystallites with 110 or 104 lateral cuts were calculated from the Ti/Mg and DPK/Mg values. For highly active TMCs the composition, XRD and specific surface area were in agreement with the MgCl2 crystallites with 104 lateral cuts, TiCl4 adsorption on one magnesium ion and elongated in the 001 direction. For low-activity TMCs obtained by reacting Mg with BuCl, the sizes of MgCl2 crystallites in different directions were close. Activity of the catalysts was inversely proportional to the crystallite size calculated from the TMC composition. This dependence was preserved for the catalysts obtained via the substitution of ketone by phthalate.

Category: thiomorpholine. About Benzophenone, If you have any questions, you can contact Maslov, DK; Bukatov, GD or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Quality Control of Benzophenone. Authors Das, P; Ganguly, S; Margel, S; Gedanken, A in AMER CHEMICAL SOC published article about in [Das, Poushali; Ganguly, Sayan; Margel, Shlomo; Gedanken, Aharon] Bar Ilan Univ, Bar Ilan Inst Nanotechnol & Adv Mat BINA, Dept Chem, IL-5290002 Ramat Gan, Israel in 2021.0, Cited 69.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

This work presents the facile synthesis of heteroatom-doped fluorescent carbon quantum dots (C-dots), which could serve as an antioxidant. Herein, nitrogen, phosphorous, and sulfur codoped carbon dots (NPSC-dots) have been synthesized by a single-step hydrothermal strategy. Owing to the radical scavenging activity of the NPSC-dots, they were tested against several methods as well as in practical applications. The antioxidant ability of the NPSC-dots was efficiently utilized on plastic films by coating with these NPSC-dots. For the very first time, NPSC-dots were immobilized onto nonpolar plastic films (polypropylene) via photochemical covalent grafting to extend the shelf life of food items or storage without affecting the quality of plastic films. The NPSC-dot-coated PP film with negligible deterioration of transparency was extensively studied using scanning electron microscopy (SEM), atomic force microscopy (AFM), Fourier transform infrared (FTIR) analysis, X-ray photoelectron spectroscopy (XPS), contact angle measurement, and thermogravimetric analysis (TGA). The fluorescent character, antioxidant ability, and durability under different solvent systems of the coated film were examined. Also, the coated films were extensively and rigorously evaluated against simulated drastic environmental conditions to ensure the durability and antifogging application.

Quality Control of Benzophenone. About Benzophenone, If you have any questions, you can contact Das, P; Ganguly, S; Margel, S; Gedanken, A or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Recently I am researching about CHIRAL AMMONIUM BETAINES; APROTIC IMIDAZOLIUM ZWITTERION; MANNICH-TYPE REACTION; AZA-HENRY REACTION; CARBON-DIOXIDE; MOLTEN-SALT; EFFICIENT; ORGANOCATALYSIS; MILD; PROTONATION, Saw an article supported by the Research Grant Council of the Hong Kong Special Administration RegionHong Kong Research Grants Council [CUHK14315716]; Chinese University of Hong Kong Direct GrantChinese University of Hong Kong [4053203, 4053275]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Lam, YP; Wang, XY; Tan, F; Ng, WH; Tse, YLS; Yeung, YY. The CAS is 104-21-2. Through research, I have a further understanding and discovery of 4-Methoxybenzyl acetate. Recommanded Product: 4-Methoxybenzyl acetate

A class of zwitterionic organocatalysts based on an amide anion/iminium cation charge pair has been developed. The zwitterions are easily prepared by reacting aziridines with aminopyridines. They are catalytically applicable to transesterifications and dehydrative esterifications. Mechanistic studies reveal that the amide anion and iminium cation work synergistically in activating the reaction partners, with the iminium cationic moiety interacting with the carbonyl substrates through nonclassical hydrogen bonding. The reaction can be applied to large-scale synthesis of biodiesel under mild conditions.

Recommanded Product: 4-Methoxybenzyl acetate. About 4-Methoxybenzyl acetate, If you have any questions, you can contact Lam, YP; Wang, XY; Tan, F; Ng, WH; Tse, YLS; Yeung, YY or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Authors Sedighinia, E; Badri, R; Kiasat, AR in MAIK NAUKA/INTERPERIODICA/SPRINGER published article about CONJUGATED MAGNETIC NANOPARTICLES; EFFICIENT; CATALYST in [Sedighinia, E.; Badri, R.] Islamic Azad Univ, Dept Chem, Khouzestan Sci & Res Branch, Ahwaz, Iran; [Sedighinia, E.; Badri, R.] Islamic Azad Univ, Dept Chem, Ahvaz Branch, Ahwaz, Iran; [Kiasat, A. R.] Shahid Chamran Univ, Coll Sci, Dept Chem, Ahwaz 6135743169, Iran in 2019, Cited 30. Name: 4-Methoxybenzyl acetate. The Name is 4-Methoxybenzyl acetate. Through research, I have a further understanding and discovery of 104-21-2

The application of yttrium iron garnet (YIG) superparamagnetic nanoparticles as a new recyclable and highly efficient heterogeneous magnetic catalyst for one-pot synthesis of pyrano[2,3-c]pyrazole derivatives under solvent-free conditions, as well as etherification and esterification reactions are described. The advantages of the proposed method include the lack of organic solvents, clean reaction, rapid removal of the catalyst, short reaction times, excellent yields, and recyclability of the catalyst.

About 4-Methoxybenzyl acetate, If you have any questions, you can contact Sedighinia, E; Badri, R; Kiasat, AR or concate me.. Name: 4-Methoxybenzyl acetate

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Stoichiometric Formation of an Oxoiron(IV) Complex by a Soluble Methane Monooxygenase Type Activation of O-2 at an Iron(II)-Cyclam Center WOS:000526393700003 published article about METAL-OXO; NONHEME; REACTIVITY; OXIDATION; DIOXYGEN; INTERMEDIATE; AUTOXIDATION; H2O2 in [Kass, Dustin; Corona, Teresa; Warm, Katrin; Braun-Cula, Beatrice; Ray, Kallol] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany; [Kuhlmann, Uwe; Hildebrandt, Peter] Tech Univ Berlin, Dept Chem, D-10623 Berlin, Germany; [Bill, Eckhard] Max Planck Inst Chem Energiekonvers, D-45470 Mulheim, Germany; [Mebs, Stefan; Dau, Holger; Haumann, Michael] Free Univ Berlin, Dept Phys, D-14195 Berlin, Germany; [Swart, Marcel] ICREA, Barcelona 08010, Spain; [Swart, Marcel] Univ Girona, IQCC, Girona 17003, Spain in 2020, Cited 38. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8. COA of Formula: C14H10O

In soluble methane monooxygenase enzymes (sMMO), dioxygen (O-2) is activated at a diiron(II) center to form an oxodiiron(IV) intermediate Q that performs the challenging oxidation of methane to methanol. An analogous mechanism of O-2 activation at mono- or dinuclear iron centers is rare in the synthetic chemistry. Herein, we report a mononuclear non-heme iron(II)cyclam complex, 1-trans, that activates O-2 to form the corresponding iron(IV)-oxo complex, 2-trans, via a mechanism reminiscent of the O-2 activation process in sMMO. The conversion of 1-trans to 2-trans proceeds via the intermediate formation of an iron(III)-superoxide species 3, which could be trapped and spectroscopically characterized at -50 degrees C. Surprisingly, 3 is a stronger oxygen atom transfer (OAT) agent than 2-trans; 3 performs OAT to 1-trans or PPh 3 to yield 2-trans quantitatively. Furthermore, 2-trans oxidizes the aromatic C-H bonds of 2,6-di-tert-butylphenol, which, together with the strong OAT ability of 3, represents new domains of oxoiron(IV) and superoxoiron(III) reactivities.

About Anthrone, If you have any questions, you can contact Kass, D; Corona, T; Warm, K; Braun-Cula, B; Kuhlmann, U; Bill, E; Mebs, S; Swart, M; Dau, H; Haumann, M; Hildebrandt, P; Ray, K or concate me.. COA of Formula: C14H10O

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem