Tag: M.W=150-200

Authors Sayago-Ayerdi, SG; Venema, K; Tabernero, M; Sarria, B; Bravo, LL; Mateos, R in ELSEVIER published article about PLANT FOODS; BIOAVAILABILITY; PRODUCTS; ACID; QTOF in [Sayago-Ayerdi, Sonia G.] Tecnol Nacl Mexico, Inst Tecnol Tepic, Av Inst Tecnol 2595, Tepic 63175, Nayarit, Mexico; [Venema, Koen] Maastricht Univ, Ctr Hlth Eating & Food Innovat, Campus Venlo,St Jansweg 20, NL-5928 RC Venlo, Netherlands; [Tabernero, Maria] CEI UAM CSIC, IMDEA Food Inst, Carretera Canto Blanco 8, Madrid 28049, Spain; [Sarria, Beatriz; Bravo, L. Laura; Mateos, Raquel] CSIC, Inst Food Sci Technol & Nutr ICTAN CSIC, Jose Antonio Novais 10, Madrid 28040, Spain in 2021.0, Cited 28.0. Application In Synthesis of Benzophenone. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

Gut microbiota bioconversion of polyphenols in predigested mango ‘Ataulfo’ peel was studied using a validated, dynamic in vitro human colon model (TIM-2) with faecal microbial inoculum. Dried peels were predigested with enzymatic treatment, followed by TIM-2 fermentation (72 h). Samples were taken at 0, 24, 48 and 72 h and analyzed by HPLC-QToF. Derivatives of hydroxyphenylpropionic, hydroxyphenylacetic and hydroxybenzoic acids, as well as, pyrogallol were the main polyphenols identified. These metabolites might derivate from flavonoid (flavanols and flavonols), gallate and gallotannin biotransformation. Despite the high content of ellagic acid in mango peel, low amounts were detected in TIM-2 samples due to transformation into urolythins A and C, mainly. Xanthone and benzophenone derivatives, specific to mango, remained after the colonic biotransformation, contrary to flavonoids, which completely disappeared. In conclusion, microbial-derived metabolites, such as xanthone and benzophenone derivatives, among others, are partially stable after colonic fermentation, and thus have the potential to contribute to mango peel bioactivity.

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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Product Details of 90-44-8. In 2019 PLANT CELL TISS ORG published article about WRKY TRANSCRIPTION FACTOR; ABSCISIC-ACID; STRESS TOLERANCE; OSMOTIC-STRESS; SALT-TOLERANCE; FACTOR GENE; ARABIDOPSIS; OVEREXPRESSION; EXPRESSION; DROUGHT in [Che Yongmei; Zhang Zhen; Zhu Dan; Hao Jie; Hou Lixia; Liu Xin] Qingdao Agr Univ, Key Lab Plant Biotechnol Univ Shandong Prov, Coll Life Sci, Qingdao 266109, Shandong, Peoples R China in 2019, Cited 38. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8.

WRKY transcription factors participate in the salt stress responses of various plant species, but the underlying functional mechanisms are not well understood, particularly in grape. In this study, the role of VvWRKY13 in the salt stress response was characterized and the underlying physiological and molecular mechanisms were explored. The results show that VvWRKY13 expression was induced by salt stress, and the VvWRKY13 transcript level in the salt stress-sensitive cultivar was significantly higher than that in the resistant cultivars. Overexpression of VvWRKY13 in Arabidopsis significantly inhibited the growth of transgenic plants under salt stress, indicating that VvWRKY13 has a negative effect on the salt stress response. The photosynthetic rate, contents of proline and soluble sugars, activities of superoxide dismutase (SOD) and catalase (CAT), as well as transcriptional levels of proline and soluble sugar metabolic genes, such as P5CS1, SS1, SS2 and G6PDH, as well as SOD and CAT encoding genes CAT1, CAT2, and Cu/Zn-SOD, all decreased under salt stress, whereas hydrogen peroxide and oxygen-free radical contents increased in transgenic Arabidopsis plants compared with those of wild-type plants. VvWRKY13 suppressed upregulation of SnRK2.3, ABF1, ABF2, ABF3, RD29B, RD29A, and RAB18 induced by salt stress, but showed no significant effect on the transcript levels of SnRK2.2, SnRK2.6, or RD22, indicating that VvWRKY13 affects salt stress tolerance via a specific abscisic acid signaling pathway. Key message VvWRKY13, isolated from grapevine, negatively regulate salt stress tolerance by depressing photosynthetic capacity, inhibiting salt-induced accumulation of osmolytes andup-regulation in antioxidant activity as well as expression of related genes. VvWRKY13 may affects salt stress tolerance by specific ABA signalling.

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Thiomorpholine – Wikipedia,
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An article Co-delivery of resolvin D1 and antibiotics with nanovesicles to lungs resolves inflammation and clears bacteria in mice WOS:000590011700001 published article about LIPID MEDIATORS; NEUTROPHILS; INFECTION; CHALLENGES; RESISTANCE; RESOLUTION; IMMUNITY; HEALTH; PHASE; SITE in [Gao, Jin; Wang, Sihan; Dong, Xinyue; Wang, Zhenjia] Washington State Univ, Coll Pharm & Pharmaceut Sci, Dept Pharmaceut Sci, Spokane, WA 99202 USA; [Leanse, Leon G.; Dai, Tianhong] Harvard Med Sch, Massachusetts Gen Hosp, Wellman Ctr Photomed, Boston, MA 02115 USA in 2020, Cited 48. SDS of cas: 90-44-8. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8

Gao et al. design a lung targeting nanovesicles made from human neutrophils membrane, and co-loaded inflammatory resolving mediator RvD1 and antibiotic CAZ inside the nanovesicles. These nanovesicles could accelerate the inflammation resolution and release the antibiotics to treat bacterial infections in mice. This approach is useful in developing multifunctional nanoparticle-based therapeutics for lung bacterial infections treatment. Resolution is an active process that protects the host damage from inflammation responses induced by infections. Simultaneously resolving inflammation and eliminating pathogens may be effective to treat infectious diseases, but it is required to deliver therapeutics to infectious sites. Here, we proposed a strategy to incorporate RvD1 and an antibiotic (ceftazidime) in human neutrophil-membrane derived nanovesicles that can specifically target inflamed vasculature for treatment of lung infection caused by P. aeruginosa. Using the nitrogen cavitation method, we generated liposome-like nanovesicles from human neutrophil membrane. The results showed that nanovesicles loaded with RvD1 decreased cytokine levels and neutrophil lung infiltration, thus shortening the resolution intervals of lung inflammation. When RvD1 and ceftazidime were co-loaded in nanovesicles, they alleviated both inflammation and bacterial growth in the mouse lung. The studies reveal a new strategy to treat infectious diseases by designing nanoparticles to simultanesouly target host inflammatory pathways and pathogens.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Waste-Minimized Cyanosilylation of Carbonyls Using Fluoride on Polymeric Ionic Tags in Batch and under Continuous Flow Conditions WOS:000644738000026 published article about METAL-ORGANIC FRAMEWORKS; SELECTIVE ALDEHYDE CYANOSILYLATION; SOLVENT-FREE CYANOSILYLATION; LEWIS-BASE ACTIVATION; ENANTIOSELECTIVE CYANOSILYLATION; KNOEVENAGEL CONDENSATION; TRIMETHYLSILYL CYANIDE; EFFICIENT SYNTHESIS; CHEMICAL-REACTIONS; BETA-AZIDATION in [Ferlin, Francesco; Valentini, Federica; Brufani, Giulia; Vaccaro, Luigi] Univ Perugia, Lab Green SOC, Dipartimento Chim Biol & Biotecnol, I-06123 Perugia, Italy; [Lanari, Daniela] Univ Perugia, Dipartimento Sci Farmaceut, I-06123 Perugia, Italy in 2021.0, Cited 82.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9. Recommanded Product: Benzophenone

Herein, we report the development of a tailor-made fluoride-based heterogeneous catalyst, POLITAG-F, for the waste-minimized continuous production of cyanohydrin silyl ethers. The careful designing of the polymeric support and the choice of fluoride ion as the anionic species resulted in the improvement of catalytic efficiency and allowed the effective conversion of different carbonyls (aldehydes, ketones, and unsaturated ketones). The POLITAG-F catalyst, employed under flow conditions, led to the conversion of large amounts (over 100 mmol) of the substrate with a productivity of 0.1 mmol min(-1). In addition, flow conditions allowed to minimize the waste production reaching an associated E-factor value of 0.04. An exhaustive evaluation of the environmental impact of our protocol has been reported by considering several green metrics (process mass intensity, atom economy, and reaction mass efficiency) and also the benign index and the safety hazard index of the process.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Application In Synthesis of Anthrone. I found the field of Polymer Science very interesting. Saw the article Highly transparent and organosoluble poly(ether amide)s derived from new diamine: 10,10-bis [4-(4-amino-2-pyridinoxy)phenyl]-9(10H)-anthracenone published in 2020, Reprint Addresses Huang, ZZ (corresponding author), Jiangxi Normal Univ, Minist Educ, Key Lab Funct Small Organ Mol, Nanchang, Jiangxi, Peoples R China.. The CAS is 90-44-8. Through research, I have a further understanding and discovery of Anthrone.

A new aromatic diamine, 10,10-bis [4-(4-amino-2-pyridinoxy)phenyl]-9(10H)-anthracenone (BAPPA) was synthesized from anthrone as the starting material, and the corresponding pyridine- and anthrone-containing poly(ether amide)s (PEAs) were prepared from BAPPA with various aromatic diacid chlorides via a low-temperature solution polycondensation. The resulting PEAs having number-average molecular weights (M-n) of 29,500-33,400 g/mol with the polydispersity index ranged from 1.75 to 1.84, were all amorphous, and displayed excellent thermal stability with the glass transition temperatures of 263-355 degrees C, the temperatures of 415-441 degrees C at 5% weight loss and the higher than 50% residues at 800 degrees C in nitrogen. These new PEAs were soluble in polar solvents such as N-methyl-2-pyrrolidone, N,N-dimethylacetamide and pyridine, even almost in tetrahydrofuran at room temperature and could form transparent, strong and flexible films with tensile strengths of 84-97 MPa, tensile moduli of 2.1-3.2 GPa and elongations at break of 4-13%. Also, the present PEAs exhibited high optical transparence with the UV cutoff wavelength in the 342-362 nm range, and 83-90% transmittance at 500 nm. These results indicated the introduction of anthrone and pyridine groups into the backbone could improve the solubility and transparence of polyamides.

Application In Synthesis of Anthrone. Welcome to talk about 90-44-8, If you have any questions, you can contact Zhou, YF; Huang, ZZ; Mao, XC; Song, C or send Email.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Generation of Strong Basic Site on Hypercrosslinked Porous Polymers as Catalyst for the Catalytic Oxidation of Methylene Compounds WOS:000507660100017 published article about MESOPOROUS SOLID SUPERBASES; HETEROGENEOUS CATALYSIS; ORGANIC POLYMERS; EFFICIENT; SILICA; NANOPARTICLES; CONVERSION; REDUCTION; STRATEGY; LIQUID in [Lu, Xia; Du, Zhongtian] Dalian Univ Technol, Sch Petr & Chem Engn, Panjin 124221, Peoples R China; [Lu, Xia; Shi, Song; Zhu, Guozhi; Zhao, Li; Wang, Min; Gao, Jin; Xu, Jie] Chinese Acad Sci, State Key Lab Catalysis Dept, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China; [Zhu, Guozhi; Zhao, Li] Univ Chinese Acad Sci, Beijing 100049, Peoples R China in 2020, Cited 40. Name: Anthrone. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8

Solid base is a kind of important heterogeneous catalyst for the transformation of various chemicals. Although many different novel solid bases have reported, it is a still challenging process to generate strong basic site on many functional supports due to the high temperature treatment of strong base preparation. In this paper, the strong basic site was successfully generated on hypercrosslinked porous polymers (HCPs) via a reducing group strategy. With the reducing groups on HCPs, the decomposition temperature of base precursor KNO3 could be as low as 320 degrees C. Further investigation illustrated the reducing groups participated in the KNO3 decomposition through a redox strategy. The obtained solid base catalysts showed good oxidation capacity of methylene compounds.

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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

I found the field of Chemistry very interesting. Saw the article Continuous Flow Sodiation of Substituted Acrylonitriles, Alkenyl Sulfides and Acrylates published in 2021.0. Application In Synthesis of Benzophenone, Reprint Addresses Knochel, P (corresponding author), Ludwig Maximilians Univ Munchen, Dept Chem, Butenandtstr 5-13,Haus F, D-81377 Munich, Germany.. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone

The sodiation of substituted acrylonitriles and alkenyl sulfides in a continuous flow set-up using NaDA (sodium diisopropylamide) in EtNMe2 or NaTMP (sodium 2,2,6,6-tetramethylpiperidide).TMEDA in n-hexane provides sodiated acrylonitriles and alkenyl sulfides, which are subsequently trapped in batch with various electrophiles such as aldehydes, ketones, disulfides and allylic bromides affording functionalized acrylonitriles and alkenyl sulfides. This flow-procedure was successfully extended to other acrylates by using Barbier-type conditions.

Application In Synthesis of Benzophenone. Welcome to talk about 119-61-9, If you have any questions, you can contact Harenberg, JH; Weidmann, N; Karaghiosoff, K; Knochel, P or send Email.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

HPLC of Formula: C13H10O. In 2021.0 CHEMCATCHEM published article about UNSATURATED TRIS(TRIMETHYLSILYL)SILYL COMPLEXES; IRON-CATALYZED HYDROSILYLATION; SELECTIVE REDUCTION; CARBONYL; NICKEL; COBALT; METAL in [Saito, Kyoka] Chuo Univ, Fac Sci & Engn, Dept Appl Chem, Bunkyo Ku, 1-13-27 Kasuga, Tokyo, Japan; [Ito, Tatsuyoshi] Kanagawa Inst Ind Sci & Technol KISTEC, Meguro Ku, 4-6-1 Komaba, Tokyo, Japan; [Arata, Shogo; Sunada, Yusuke] Univ Tokyo, Sch Engn, Dept Appl Chem, Meguro Ku, 4-6-1 Komaba, Tokyo, Japan; [Sunada, Yusuke] Univ Tokyo, Inst Ind Sci, Meguro Ku, 4-6-1 Komaba, Tokyo, Japan in 2021.0, Cited 49.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9.

The coordinatively unsaturated manganase(II) bis(supersilyl) complex Mn[Si(SiMe3)(3)](2)(THF)(2) (2) was synthesized in one step via the reaction of MnBr2 with two equivalents of KSi(SiMe3)(3) in THF. Complex 2 acts as an effective precatalyst for the catalytic hydrosilylation of aldehydes and ketones with 1,1,3,3-tetramethyldisiloxane (TMDS). The catalytic efficiency can be improved by combining 2 and adamantyl isocyanide (CNAd). The stoichiometric reaction of 2 and two equivalents of CNAd led to the isolation of Mn[Si(SiMe3)(3)](2)(CNAd)(2) (3) in high yield. Complex 3 shows superior catalytic performance than 2 in the hydrosilylation of relatively unreactive ketones.

Welcome to talk about 119-61-9, If you have any questions, you can contact Saito, K; Ito, T; Arata, S; Sunada, Y or send Email.. HPLC of Formula: C13H10O

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Authors Wan, X; Liu, Q; Dong, B; Pillai, SV; Huang, FH; Singh, SP; Zhou, XR in BMC published article about RICINUS-COMMUNIS L; FATTY-ACID; TRIACYLGLYCEROL BIOSYNTHESIS; CYPERUS-ESCULENTUS; ARABIDOPSIS; THIOESTERASE; RICINOLEATE; SYNTHETASE; METABOLISM; INCREASES in [Wan, Xia; Huang, Feng-Hong] Chinese Acad Agr Sci, Oil Crops Res Inst, Wuhan 430062, Hubei, Peoples R China; [Wan, Xia; Liu, Qing; Dong, Bei; Pillai, Sapna Vibhakaran; Singh, Surinder P.; Zhou, Xue-Rong] CSIRO Agr & Food, POB 1700, Canberra, ACT 2601, Australia; [Wan, Xia; Huang, Feng-Hong] Minist Agr, Key Lab Biol & Genet Improvement Oil Crops, Wuhan 430062, Hubei, Peoples R China; [Wan, Xia; Huang, Feng-Hong] Minist Agr, Key Lab Oilseeds Proc, Wuhan 430062, Hubei, Peoples R China; [Wan, Xia; Huang, Feng-Hong] Hubei Key Lab Lipid Chem & Nutr, Wuhan 430062, Hubei, Peoples R China in 2019, Cited 43. Application In Synthesis of Anthrone. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8

BackgroundWith the increasing demand for vegetative oil and the approach of peak seed oil production, it is important to develop new oil production platforms from non-seed tissues. Castor bean (Ricinus communis) is one of the crops for vegetable oil for industrial applications with yield around 1.4 ton oil per hectare produced in seed. The castor caruncle is a non-seed tissue attached to seed.ResultsCaruncle accumulates up to 40% oil by weight in the form of triacylglycerol (TAG), with a highly contrasting fatty acid composition when compared to the seed oil. Biochemical analysis indicated that the caruncle synthesizes TAGs independent of the seed. Such non-seed tissue has provided an excellent resource for understanding the mechanism of oil accumulation in tissues other than seeds. Transcriptome analysis revealed the key members of gene families involved in fatty acid synthesis and TAG assembly in the caruncle. A transient expression assay of these selected genes resulted in a 20-fold increased TAG accumulation in leaves.ConclusionsCastor caruncle utilizes an independent system to synthesize TAGs. Results provide the possibility of exploiting caruncle gene set to engineer oil production in non-seed tissues or microbes.

Application In Synthesis of Anthrone. Welcome to talk about 90-44-8, If you have any questions, you can contact Wan, X; Liu, Q; Dong, B; Pillai, SV; Huang, FH; Singh, SP; Zhou, XR or send Email.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

In 2019 J ASIAN NAT PROD RES published article about FUNGI in [Li, Jian-Song; Zhang, Hui; Qi, Huan; Wang, Ji-Dong] Zhejiang Hisun Pharmaceut Co Ltd, Zhejiang Key Lab Antifungal Drugs, Taizhou 318000, Peoples R China; [Xiang, Wen-Sheng] Northeast Agr Univ, Sch Life Sci, Life Sci & Biotechnol Res Ctr, Harbin 150030, Heilongjiang, Peoples R China in 2019, Cited 16. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8. Category: thiomorpholine

Two new naphthalenone derivatives, 5-hydroxy-4-oxo-2-(2-oxopropyl)-1,2,3,4-tetrahydronaphthalen-1-yl acetate (1) and 5-hydroxy-2-(2-hydroxypropyl)naphthalene-1,4-dione (2), together with two new anthrone derivatives, (S)-2,5-dihydroxy-2-methyl-1,2,3,4-tetrahydroanthracene-9,10-dione (3) and 4,5-dihydroxy-2-methyl-9H-xanthen-9-one (4), were isolated from the fermentation broth of endophytic Micromonospora sp. NEAU-gq13. Their structures were determined by 1D-NMR, 2D-NMR, and HR-ESI-MS analysis. Compounds 2 and 3 exhibited strong cytotoxic activity against human central nervous system cancer (SF-268) with the IC50 values of 3.04 and 5.66 mu g/ml, respectively. Moreover, compound 2 also displayed potent activity against human liver cancer (HepG2) with an IC50 value of 1.01 mu g/ml.

Category: thiomorpholine. Welcome to talk about 90-44-8, If you have any questions, you can contact Li, JS; Zhang, H; Qi, H; Wang, JD; Xiang, WS or send Email.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem