Tag: M.W=150-200

Recently I am researching about ONE-POT; MULTICOMPONENT REACTIONS; MALONONITRILE DIMER; ACTIVATED NITRILES; DERIVATIVES; CHEMISTRY; REARRANGEMENT; ANTIOXIDANT; REACTIVITY; INHIBITORS, Saw an article supported by the Kuban Science Foundation [MFI-20.1-26/20, MFI-20.1/45]; Ministry of Education and Science of the Russian FederationMinistry of Education and Science, Russian Federation [0795-2020-0031]. Published in MAIK NAUKA/INTERPERIODICA/SPRINGER in NEW YORK ,Authors: Ismiyev, AI; Dotsenko, VV; Aksenov, NA; Aksenova, IV; Magarramov, AM. The CAS is 99-61-6. Through research, I have a further understanding and discovery of 3-Nitrobenzaldehyde. Category: thiomorpholine

The reaction of aromatic aldehydes with malononitrile, ethyl or butyl cyanoacetate and acetylacetone in the presence of NaOH under mild conditions (EtOH, 25 degrees C) led to the formation of new series of (1S,5R,6R,9R)/(1R,5S,6S,9S)-2-amino-6,9-diaryl-7-acetyl-8-methyl-4-oxo-5-cyano-3-azabicyclo[3.3.1]nona-2,7-diene-1-carboxylic acids esters. A plausible mechanism of the cascade reaction was proposed.

Category: thiomorpholine. Welcome to talk about 99-61-6, If you have any questions, you can contact Ismiyev, AI; Dotsenko, VV; Aksenov, NA; Aksenova, IV; Magarramov, AM or send Email.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

SDS of cas: 90-44-8. In 2021 MOLECULES published article about VAR NATALENSIS BERGER; CHEMICAL-CONSTITUENTS; SAPONARIA-HAW; TETRAHYDROANTHRACENE DERIVATIVES; STRUCTURE ELUCIDATION; C-GLUCOSYLANTHRONES; CHROMONE COMPONENTS; MOLECULAR-DYNAMICS; ANTIVIRAL ACTIVITY; CALLUS-TISSUE in [Abouelela, Mohamed E.; Assaf, Hamdy K.; Abdelhamid, Reda A.; Elkhyat, Ehab S.] Al Azhar Univ, Fac Pharm, Dept Pharmacognosy, Assiut Branch, Assiut 71524, Egypt; [Sayed, Ahmed M.] Nanda Univ, Fac Pharm, Dept Pharmacognosy, Bani Suwayf 62513, Egypt; [Oszako, Tomasz] Forest Res Inst, Dept Forest Protect, PL-05090 Sekocin Stary, Poland; [Belbahri, Lassaad] Univ Neuchatel, Lab Soil Biol, CH-2000 Neuchatel, Switzerland; [El Zowalaty, Ahmed E.] Univ Gothenburg, Sahlgrenska Ctr Canc Res, Inst Clin Sci, Dept Surg, S-40530 Gothenburg, Sweden; [El Zowalaty, Ahmed E.] Univ Gothenburg, Wallenberg Ctr Mol & Translat Med, S-40530 Gothenburg, Sweden; [Abdelkader, Mohamed Salaheldin A.] Sohag Univ, Fac Pharm, Dept Pharmacognosy, Nasr City 82524, Sohag, Egypt in 2021, Cited 182. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8.

Severe acute respiratory syndrome coronavirus (SARS-CoV-2) disease is a global rapidly spreading virus showing very high rates of complications and mortality. Till now, there is no effective specific treatment for the disease. Aloe is a rich source of isolated phytoconstituents that have an enormous range of biological activities. Since there are no available experimental techniques to examine these compounds for antiviral activity against SARS-CoV-2, we employed an in silico approach involving molecular docking, dynamics simulation, and binding free energy calculation using SARS-CoV-2 essential proteins as main protease and spike protein to identify lead compounds from Aloe that may help in novel drug discovery. Results retrieved from docking and molecular dynamics simulation suggested a number of promising inhibitors from Aloe. Root mean square deviation (RMSD) and root mean square fluctuation (RMSF) calculations indicated that compounds 132, 134, and 159 were the best scoring compounds against main protease, while compounds 115, 120, and 131 were the best scoring ones against spike glycoprotein. Compounds 120 and 131 were able to achieve significant stability and binding free energies during molecular dynamics simulation. In addition, the highest scoring compounds were investigated for their pharmacokinetic properties and drug-likeness. The Aloe compounds are promising active phytoconstituents for drug development for SARS-CoV-2.

Bye, fridends, I hope you can learn more about C14H10O, If you have any questions, you can browse other blog as well. See you lster.. SDS of cas: 90-44-8

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Wang, M; Liang, G; Wang, YH; Fan, T; Yuan, BL; Liu, MX; Yin, Y; Li, LC in [Wang, Man; Liang, Gan; Wang, Yunhao; Fan, Tao; Yuan, Baoling; Liu, Mingxian; Yin, Ying; Li, Liangchun] Tongji Univ, Shanghai Key Lab Chem Assessment & Sustainabil, Sch Chem Sci & Engn, Shanghai 200092, Peoples R China published Merging N-Hydroxyphthalimide into Metal-Organic Frameworks for Highly Efficient and Environmentally Benign Aerobic Oxidation in 2021, Cited 80. Product Details of 119-61-9. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9.

Two highly efficient metal-organic framework catalysts TJU-68-NHPI and TJU-68-NDHPI have been successfully synthesized through solvothermal reactions of which the frameworks are merged with N-hydroxyphthalimide (NHPI) units, resulting in the decoration of pore surfaces with highly active nitroxyl catalytic sites. When t-butyl nitrite (TBN) is used as co-catalyst, the as-synthesized MOFs are demonstrated to be highly efficient and recyclable catalysts for a novel three-phase heterogeneous oxidation of activated C-H bond of primary and secondary alcohols, and benzyl compounds under mild conditions. Based on the high efficiency and selectivity, an environmentally benign system with good sustainability, mild conditions, simple work-up procedure has been established for practical oxidation of a wide range of substrates.

Product Details of 119-61-9. Welcome to talk about 119-61-9, If you have any questions, you can contact Wang, M; Liang, G; Wang, YH; Fan, T; Yuan, BL; Liu, MX; Yin, Y; Li, LC or send Email.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

SDS of cas: 104-21-2. Khaligh, NG; Mihankhah, T; RafieJohan, M; Ching, JJ in [Khaligh, Nader Ghaffari; RafieJohan, Mohd; Ching, Juan Joon] Univ Malaya, Nanotechnol & Catalysis Res Ctr, Inst Postgrad Studies, 3rd Floor,Block A, Kuala Lumpur 50603, Malaysia; [Mihankhah, Taraneh] Kharazmi Univ, Fac Engn, Civil Engn Dept, Tehran, Iran published 4-Imidazol-1-yl-butane-1-sulfonic acid ionic liquid: Synthesis, structural analysis, physical properties and catalytic application as dual solvent-catalyst in 2019, Cited 51. The Name is 4-Methoxybenzyl acetate. Through research, I have a further understanding and discovery of 104-21-2.

4-Imidazol-1-yl-butane-1-sulfonic acid (ImBu-SO3H) has been successfully synthetized and fully characterized by FT-IR and high-resolution NMR spectroscopy (H-1, C-13). The plausible alternative structures of ImBu-SO3H were discussed on the basis of its NMR data. The ionic liquid showed interesting dual solvent-catalyst property, which was studied experimentally for the acetylation of a variety of functionalized alcohols, phenols, thiols, amines and a-tocopherol (a-CTP) as the most active form of vitamin E with acetic anhydride and which provided good yields within a short reaction time. ImBu-SO3H was successfully recycled by product extraction with an average recovered yield of 82% for 5 subsequent runs. The catalytic activity of the recycled ImBu-SO3H showed almost no loss even after five consecutive runs. [GRAPHICS] .

SDS of cas: 104-21-2. Welcome to talk about 104-21-2, If you have any questions, you can contact Khaligh, NG; Mihankhah, T; RafieJohan, M; Ching, JJ or send Email.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Product Details of 119-61-9. Authors Kimura, N; Katta, S; Kitazawa, Y; Kochi, T; Kakiuchi, F in AMER CHEMICAL SOC published article about in [Kimura, Naoki; Katta, Shiori; Kitazawa, Yoichi; Kochi, Takuya; Kakiuchi, Fumitoshi] Keio Univ, Fac Sci & Technol, Dept Chem, Yokohama, Kanagawa 2238522, Japan in 2021.0, Cited 90.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

We report here a C-H homoallylation reaction of aromatic ketones with methylenecyclopropanes (MCPs) only using a catalytic amount of Fe(PMe3)(4). A variety of aromatic ketones and MCPs are applicable to the reaction to form ortho-homoallylated aromatic ketones selectively via regioselective scission of the three-membered rings. The homoallylated products are amenable to further elaborations, providing functionalized 1,2-dihydronaphthalenes.

Product Details of 119-61-9. Bye, fridends, I hope you can learn more about C13H10O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Application In Synthesis of 3-Nitrobenzaldehyde. Authors Khademi, S; Zahmatkesh, S; Aghili, A; Badri, R in WILEY published article about in [Khademi, Shima; Badri, Rashid] Islamic Azad Univ, Khouzestan Sci & Res Branch, Dept Chem, Ahvaz, Iran; [Zahmatkesh, Saeed] Payame Noor Univ, Dept Sci, Tehran 193954697, Iran; [Aghili, Alireza] Islamic Azad Univ, Shiraz Branch, Dept Polymer Engn, Shiraz, Iran in 2021.0, Cited 41.0. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6

A new magnetic nanocatalyst based on the immobilization of tungstic acid onto new design robust, cost-effective, green, and scalable zirconium-L-aspartate amino acid metal-organic framework (MOF)-grafted L-(+)-tartaric acid stabilized magnetite nanoparticles (Fe3O4/tart-NPs) was synthesized by two successive solvo (hydro)-thermal methods. This catalyst was characterized by Fourier-transform infrared (FT-IR), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), Brunauer-Emmett-Teller (BET), Barrett-Joyner-Halenda (BJH), zeta potential, Thermogravimetry Analysis-Differential Thermal Analysis (TGA-DTA), and vibrating sample magnetometer (VSM) analyses. This catalyst is outstanding to prepare l-(4-phenyl)-2,4-dihydropyrano[2,3-c] pyrazole derivatives in aqueous media due to the open metal sites, high and steady proton conductivity in the zirconium-MOF, MIP-202(Zr), and MOF and also due to Bronsted acid properties of tungstic acid. This acidic catalyst can easily be extracted by an outward magnetic field after completion of the reaction without any deactivation or selectivity loss. The products were characterized by spectroscopic analysis (FT-IR, H-1-NMR, and C-13-NMR). The optimized reaction conditions and a possible reaction mechanism are outlined.

Welcome to talk about 99-61-6, If you have any questions, you can contact Khademi, S; Zahmatkesh, S; Aghili, A; Badri, R or send Email.. Application In Synthesis of 3-Nitrobenzaldehyde

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Insight into the chemoselective aromatic vs. side-chain hydroxylation of alkylaromatics with H2O2 catalyzed by a non-heme imine-based iron complex WOS:000609012400013 published article about HYDROGEN-PEROXIDE; C-H; POLYAZADENTATE COMPLEXES; SELECTIVE HYDROXYLATION; IRON(IV)-OXO COMPLEXES; EFFICIENT CATALYSTS; BENZOIC-ACIDS; OXIDATION; BENZENE; PHENOL in [Ticconi, Barbara; Capocasa, Giorgio; Cerrato, Andrea; Di Stefano, Stefano; Lapi, Andrea; Marincioni, Beatrice; Lanzalunga, Osvaldo] Univ Roma La Sapienza, Dipartimento Chim, Ple A Moro 5, I-00185 Rome, Italy; [Ticconi, Barbara; Capocasa, Giorgio; Cerrato, Andrea; Di Stefano, Stefano; Lapi, Andrea; Marincioni, Beatrice; Lanzalunga, Osvaldo] Univ Roma La Sapienza, Dipartimento Chim, Sez Meccanismi Reaz, Ist CNR & Sistemi Biol ISB CNR, Ple A Moro 5, I-00185 Rome, Italy; [Olivo, Giorgio] Univ Girona, Inst Quim Computac & Catalisi IQCC, Campus Montilivi,C Maria Aurelia Capmany 69, Girona 17003, Spain; [Olivo, Giorgio] Univ Girona, Dept Quim, Campus Montilivi,C Maria Aurelia Capmany 69, Girona 17003, Spain; [Olivo, Giorgio] Univ Girona, Inst Quim Computac & Catalisi IQCC, Campus Montilivi, Girona 17071, Spain; [Olivo, Giorgio] Univ Girona, Dept Quim, Campus Montilivi, Girona 17071, Spain in 2021, Cited 75. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8. COA of Formula: C14H10O

The oxidation of a series of alkylaromatic compounds with H2O2 catalyzed by an imine-based non-heme iron complex prepared in situ by reaction of 2-picolylaldehyde, 2-picolylamine, and Fe(OTf)(2) in a 2 : 2 : 1 ratio leads to a marked chemoselectivity for aromatic ring hydroxylation over side-chain oxidation. This selectivity is herein investigated in detail. Side-chain/ring oxygenated product ratio was found to increase upon decreasing the bond dissociation energy (BDE) of the benzylic C-H bond in line with expectation. Evidence for competitive reactions leading either to aromatic hydroxylation via electrophilic aromatic substitution or side-chain oxidation via benzylic hydrogen atom abstraction, promoted by a metal-based oxidant, has been provided by kinetic isotope effect analysis.

Bye, fridends, I hope you can learn more about C14H10O, If you have any questions, you can browse other blog as well. See you lster.. COA of Formula: C14H10O

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Product Details of 119-61-9. Authors Zhang, H; Xu, T; Li, DD; Cheng, T; Chen, J; Zhou, Y in ELSEVIER published article about in [Zhang, Hua] Xian Univ Technol, Sch Mat Sci & Engn, Xian 710048, Peoples R China; [Zhang, Hua; Xu, Ting; Chen, Jing; Zhou, Yang] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Cixi Inst Biomed Engn, Ningbo 315201, Peoples R China; [Li, Dongdong] Nanjing Forestry Univ, Coll Chem Engn, 159 Long Pan Rd, Nanjing 210037, Peoples R China; [Cheng, Tao] Pharmaron Ningbo Technol Dev Co Ltd, Ningbo 315366, Peoples R China in 2021.0, Cited 37.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

A novel series of bis Indy-NHC gold complexes have been developed and investigated via a mild Agcarbene transfer route. The obtained complexes were characterized by NMR spectroscopy and X-ray diffraction analysis. The catalytic property of these gold complexes was further evaluated in the oxidation of benzylic. The gold complex E1 showed a high catalytic activity in the oxidation of various benzylic substrates, resulting in the corresponding carbonyl compounds with excellent yields using TBHP as oxidant. (C) 2021 Elsevier B.V. All rights reserved.

Product Details of 119-61-9. Bye, fridends, I hope you can learn more about C13H10O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

In 2021 LETT ORG CHEM published article about DERIVATIVES in [Suryawanshi, Vikas B.] KMC Coll, Dept Chem, Khopoli 410203, Maharashtra, India; [Suryawanshi, Vikas B.] Mumbai Univ, Mumbai, Maharashtra, India; [Momin, Kalimoddin, I] Rajarshi Shahu Coll, Dept Chem, Latur 413512, Maharashtra, India; [Momin, Kalimoddin, I; Dawle, Jairaj K.] SRTM Univ, Nanded, India; [Dawle, Jairaj K.] Maharashtra Mahavidyalaya, Res Lab Pure & Appl Chem, Nilanga 413521, India; [Mathapati, Sushil R.] Shri Madhavrao Patil Mahavidyalaya, Dept Chem, Murum 413605, India; [Mathapati, Sushil R.] Dr BAM Univ, Aurangabad, Maharashtra, India in 2021, Cited 31. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6. HPLC of Formula: C7H5NO3

Solvent free synthesis of dihydropyrano[3,2-b]chromenediones was formulated via multicomponent reactions of kojic acid, dimedone and several substituted aromatic aldehydes catalyzed with BCl3. Reactions progressed efficiently and the corresponding heterocyclic products were obtained in good to high yields within short period. The developed protocol is one of the better and efficient alternative methods for the synthesis of dihydropyrano[3,2-b]chromenediones. The simple reaction procedure, easy separation of products, radially available catalyst are certain benefits of this reported protocol.

HPLC of Formula: C7H5NO3. Welcome to talk about 99-61-6, If you have any questions, you can contact Suryawanshi, VB; Momin, KI; Dawle, JK; Mathapati, SR or send Email.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Formula: C13H10O. Authors Ye, JH; Bellotti, P; Paulisch, TO; Daniliuc, CG; Glorius, F in WILEY-V C H VERLAG GMBH published article about in [Ye, Jian-Heng; Bellotti, Peter; Paulisch, Tiffany O.; Daniliuc, Constantin G.; Glorius, Frank] Westfalische Wilhelms Univ Munster, Organ Chem Inst, Corrensstr 40, D-48149 Munster, Germany in 2021.0, Cited 61.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

We report the synthesis of beta-lactams from alpha-ketoacylsilanes and imines, which proceeds via a formal [2+2] photochemical cycloaddition with in situ generation of siloxyketene. This mild and operationally simple reaction proceeds in an atom-economic fashion with broad substrate scope, including aldimines, ketimines, hydrazones, and fused nitrogen heterocycles, affording a variety of important beta-lactams with satisfactory diastereoselectivities in most cases. This reaction also features good functional-group tolerance, facile scalability and product diversification. Experimental and computational studies suggest that alpha-ketoacylsilanes can serve as photochemical precursors by engaging in a 1,3 silicon shift to the distal carbonyl group.

Formula: C13H10O. Bye, fridends, I hope you can learn more about C13H10O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem