Tag: M.W:100-200

Academic researchers, R&D teams, teachers, students, policy makers and the media all rely on us to share knowledge that is reliable, accurate and cutting-edge. In an article, author is Shainyan, BA, once mentioned the application of 7311-34-4, Name is 3,5-Dimethoxybenzaldehyde, molecular formula is C9H10O3, molecular weight is 166.17, MDL number is MFCD00003366, category is thiomorpholine. Now introduce a scientific discovery about this category, Recommanded Product: 7311-34-4.

Reactions of secondary cyclic amines (piperidine, morpholine, thiomorpholine, 1lambda(6), 4-thiazinane-1,1-dione) with trifluoromethanesulfonic anhydride or with N-phenyltriflimide both in the presence and in the absence of a base (Et3N) result in formation of corresponding triflamides and triflates of the initial amines. The triflates and triflamides can be distinguished by their F-19 and N-15 NMR spectra and the presence in the IR spectra of salts of absorption bands in the region 3270-3000 cm(-1) lacking in the spectra of triflamides.

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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Related Products of 99-10-5, Chemical engineers ensure the efficiency and safety of chemical processes, adapt the chemical make-up of products to meet environmental or economic needs, and apply new technologies to improve existing processes. 99-10-5, Name is 3,5-Dihydroxybenzoic acid, SMILES is O=C(O)C1=CC(O)=CC(O)=C1, belongs to thiomorpholine compound. In a article, author is Saikia, Anil K., introduce new discover of the category.

A one-pot, metal-free procedure has been developed for the synthesis of 4-tosylthiomorpholine from N-tethered thioalkenols via bromination, cyclization and subsequent elimination reaction in good yields. The reaction is found to be highly regioselective.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

When developing chemical systems it’s of course important to gain a deep understanding of the chemical reaction process. In an article, author is Capperucci, Antonella, once mentioned the application of 2996-92-1, Name is Trimethoxy(phenyl)silane, molecular formula is C9H14O3Si, molecular weight is 198.2912, MDL number is MFCD00025689, category is thiomorpholine. Now introduce a scientific discovery about this category, Recommanded Product: 2996-92-1.

delta-Hydroxy- and delta-amino alpha-thio-esters, easily obtainable through S-alkylation of beta-mercapto alcohols and delta-amino thiols with bromo acetate, behave as suitable starting compounds to obtain various 2-hydroxy-1,4-oxathianes and (S)-3,4-dihydro-2H-1,4-thiazines via a reductive ring closure. Under similar conditions, selenated heterocycles are also synthesized. [GRAPHICS] .

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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Chemical engineers work across a number of sectors, but chemistry and chemical engineering roles are found throughout, creation and manufacturing process of chemical products and materials. In an article, author is Jovanovic, VM, once mentioned the application of 1074-36-8, Name is 4-Mercaptobenzoic acid, molecular formula is C7H6O2S, molecular weight is 154.1863, MDL number is MFCD00016617, category is thiomorpholine. Now introduce a scientific discovery about this category, Electric Literature of 1074-36-8.

Eight mixed-ligand cobalt(III) complexes with the macrocyclic amine 1,4,8,11 -tetraazacyclotetradecane (cyclam) and a heterocyclic dithiocarbamate (Rdtc(-)) i.e., morpholine- (Morphdtc), thiomorpholine- (Timdtc), piperazine- (Pzdtc), N-methylpiperazine- (Mepzdtc), piperidine- (Pipdtc), 2-, 3- or 4-methylpiperidine- (2-, 3- and 4-Mepipdtc) carbodithionato-S,S ions, of the general formula [Co(cyclam)Rdtc](ClO4)(2), were investigated in deoxygenated 0.1 M HClO4 solutions. Cyclic voltammetry data at a glassy carbon (GC) electrode demonstrate a redox reaction of cobalt(III) from the complexes at potentials strongly influenced by the presence of different heterocyclic Rdtc(-) ligands. In this respect, the complexes were separated into two groups: the first, with a heteroatom O, S or N in the heterocyclic ring, and the second, with a methyl group on the piperidine ring of the Rdtc(-) ligand. Anodic polarization of an Fe electrode in the presence of the complexes shows their influence not only on the dissolution of iron but also on the hydrogen evolution reactions and on this basis complexes the complexes could be divided into the same two groups. It was found that the weaker the inhibiting effect of the free heterocyclic amines is, the significantly higher is the efficiency of the corresponding complexes.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

In chemical reaction engineering, simulations are useful for investigating and optimizing a particular reaction process or system. In an article, author is Martynov, Alexander V., once mentioned the application of 90-01-7, Name is Salicyl Alcohol, molecular formula is C7H8O2, molecular weight is 124.1372, MDL number is MFCD00004617, category is thiomorpholine. Now introduce a scientific discovery about this category, Formula: https://www.ambeed.com/products/90-01-7.html.

An efficient method for preparation of earlier unknown S-oxide of 2(E),6(E)-bis(chloromethylidene)-4-thiomorpholinamine by oxidation of 2(E), 6(E)-bis(chloromethylidene)-4-thiomorpholinamine hydrochloride with hydrogen peroxide in H2O or EtOH/H2O followed by the reaction mixture neutralization with Na2CO3 has been described. Interaction of the S-oxide with acetaldehyde, butanal, benzaldehyde, 4-methoxybenzaldehyde and 4-pyridinecarboxaldehyde in EtOH, C6H6, in the mixture of acetonitrile and ethanol or ethanol and benzene affords the unknown hydrazones, N-organylmethylidene-2(E), 6(E)-bis(chloromethylidene)-4-thiomorpholinamine-1-oxides. [GRAPHICS] .

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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

In chemical reaction engineering, simulations are useful for investigating and optimizing a particular reaction process or system. In an article, author is Mitra, S, once mentioned the application of 114-83-0, Name is 1-Acetyl-2-phenylhydrazine, molecular formula is C8H10N2O, molecular weight is 150.1778, MDL number is MFCD00008672, category is thiomorpholine. Now introduce a scientific discovery about this category, Electric Literature of 114-83-0.

Dichloro – (DCA) and trichloroacetate (TCA) -cyclic ligand morpholine (Morph)/thiomorpholine (Tmorph)/methylmorpholine (Mmorph)/ dimethyl-piperazine (DMP) complexes of nickel (II), copper (II), zinc (II) and cadmium (II) with the compositions [Ni(tmorph)(2) (DCA)(2)], [Ni(tmorph)(2) (TCA)(2)]. 2H(2)O, [Cu (DMP)(2) (TCA)(2)], [ML2X2]. nH(2)O where M = Zn-II or Cd-II, L = Morph, DMP or tmorph and X = DCA or TCA and n = O except in case of [Cd(Morph)(2) (TCA)(2)] where n = 1 have been synthesised. Some intermediate complexes have been isolated by temperature arrest technique (pyrolysis) and characterised. Configurational and conformational changes have been studied by elemental analyses. IR and electronic spectra, magnetic moment data (in the case of Ni(II) and Cu(II) complexes) and thermal analysis. E-a*, Delta H and Delta S for the decomposition reaction of these complexes are evaluated and the stability of the complexes with respect to activation energy has also been compared. A linear correlation has been found between E-a* and Delta S for the decomposition of the complexes.

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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

You could be based in a university, combining chemical research with teaching; or in a public-sector research center, helping to ensure national healthcare provision keeps pace with new discoveries. In an article, author is Yurttas, Leyla, once mentioned the application of 2579-22-8, Name is 3-Phenylpropiolaldehyde, molecular formula is C9H6O, molecular weight is 130.14, MDL number is MFCD00006995, category is thiomorpholine. Now introduce a scientific discovery about this category, COA of Formula: https://www.ambeed.com/products/2579-22-8.html.

Background: In this study, 2-(substituted-sulfanyl)-N, N-dicyclohexylacetamide derivatives (2a-2g) and 2-(dicyclohexylamino)-2-oxoethyl-1-substituted carbodithioate derivatives (2h-2m) were synthesized and screened for their antimicrobial activity. Methods: Newly synthesized compounds were screened against two gram negative bacteria (S. typhimurium and E. coli), three gram positive bacteria (S. aureus, B. cereus and L. monocytogenes), four Candida species, four Aspergillus spp. and three Penicillium spp. Among them (2a-2m), compounds 2i (2-(dicyclohexylamino)-2-oxoethyl-thiomorpholine-4-carbodithioate) and 2k (2( dicyclohexylamino)-2-oxoethyl-4-(4-methoxyphenyl) piperazine-1-carbodithioate) were detected to have higher inhibitory effect than other compounds. Results and Conclusion: Minumum inhibitor concentrations (MICs) of the compounds were determined between the range of 97.5-390 mu g/mL. Additionally, parameters determined that some physicochemical and toxic properties were predicted using computational methods.

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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Healthcare careers for chemists are once again largely based in laboratories, although increasingly there is opportunity to work at the point of care, helping with patient investigation. 103-30-0, Name is (E)-1,2-Diphenylethene, molecular formurla is C14H12. In a document, author is Combourieu, B, introducing its new discovery. SDS of cas: 103-30-0.

In order to see if the biodegradative pathways for morpholine and thiomorpholine during degradation by Mycobacterium aurum MO1 could be generalized to other heterocyclic compounds, the degradation of piperidine by this strain was investigated by performing H-1-nuclear magnetic rc:resonance directly with the incubation medium. Ionspray mass spectrometry, performed without purification of the samples, was also used to confirm the structure of some metabolites during morpholine and thiomorpholine degradation. The results obtained with these tyro techniques suggested a general pathway for degradation of nitrogen heterocyclic compounds by M. aurum MO1. The first step of the degradative pathway is cleavage of the C-N bond; this leads formation of an intermediary amino acid, which is followed by deamination and oxidation of this amino acid into a diacid. Except in the case of thiodiglycolate obtained from thiomorpholine degradation, the dicarboxylates are completely mineralized by the bacterial cells. A comparison with previously published data showed that this pathway could be a general pathway for degradation by other strains of members of the genus Mycobacterium.

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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Chemical engineers work across a number of sectors, but chemistry and chemical engineering roles are found throughout, creation and manufacturing process of chemical products and materials. In an article, author is PECCI, L, once mentioned the application of 585-32-0, Name is 2-Phenylpropan-2-amine, molecular formula is C9H13N, molecular weight is 135.2062, MDL number is MFCD00134680, category is thiomorpholine. Now introduce a scientific discovery about this category, Recommanded Product: 2-Phenylpropan-2-amine.

In continuation of a previous work (Pecci et al., 1993), dedicated to the detection of the autoxidation products of S-aminoethylcysteine ketimine (AECK), we give here data for the identification of 2,3,6,7-tetrahydro-4H-[1,4]thiazino[2,3-b]thiazine, thiomorpholine-3-one and 5,5′, 6,6′-tetrahydro-2,2′-dihydroxy-3,3′-bi-2H-thiazine among the products of AECK autoxidation. Identification has been done on the basis of mass spectrometry and NMR spectral analyses of the isolated products.

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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Researchers are common within chemical engineering and are often tasked with creating and developing new chemical techniques, frequently combining other advanced and emerging scientific areas. In an article, author is Baiocco, Paola, once mentioned the application of 446-32-2, Name is 2-Amino-4-fluorobenzoic acid, molecular formula is C7H6FNO2, molecular weight is 155.13, MDL number is MFCD00075553, category is thiomorpholine. Now introduce a scientific discovery about this category, Related Products of 446-32-2.

Herein we report a study aimed at discovering a new class of compounds that are able to inhibit Leishmania donovani cell growth. Evaluation of an in-house library of compounds in a whole-cell screening assay highlighted 4-((1-(4-ethylphenyl)-2-methyl-5-(4-(methylthio)phenyl)-1H-pyrrol-3-yl)methyl)thiomorpholine (compound 1) as the most active. Enzymatic assays on Leishmania infantum trypanothione reductase (LiTR, belonging to the Leishmania donovani complex) shed light on both the interaction with, and the nature of inhibition by, compound 1. A molecular modeling approach based on docking studies and on the estimation of the binding free energy aided our rationalization of the biological data. Moreover, X-ray crystal structure determination of LiTR in complex with compound 1 confirmed all our results: compound 1 binds to the T(SH)2 binding site, lined by hydrophobic residues such as Trp21 and Met113, as well as residues Glu18 and Tyr110. Analysis of the structure of LiTR in complex with trypanothione shows that Glu18 and Tyr110 are also involved in substrate binding, according to a competitive inhibition mechanism.

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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem