Heterocyclic Building Blocks-Thiomorpholine

An article Glucose and insulin responses to an intravenous glucose tolerance test administered to feed-restricted dairy cows receiving folic acid and vitamin B-12 supplements WOS:000471756100036 published article about INTRAMUSCULAR INJECTIONS; LACTATIONAL PERFORMANCE; DIETARY-SUPPLEMENTS; METABOLISM; RESISTANCE; METHIONINE; ENERGY; MILK; FOLATE in [Girard, C. L.; Vanacker, N.; Beaudet, V; Duplessis, M.; Lacasse, P.] Agr & Agroalimentaire Canada, Ctr Rech & Dev Sherbrooke, Sherbrooke, PQ J1M 0C8, Canada; [Vanacker, N.] Univ Sherbrooke, Dept Biol, Fac Sci, Sherbrooke, PQ J1K 2R1, Canada in 2019.0, Cited 37.0. Application In Synthesis of 1-Phenylurea. The Name is 1-Phenylurea. Through research, I have a further understanding and discovery of 64-10-8

The present experiment was conducted to determine whether, during periods of negative energy balance, the increase in glucose availability, despite similar DMI and greater milk production, induced by a combined supplement of folic acid and vitamin B-12 was related to effects of insulin on metabolism. Sixteen multiparous Holstein cows averaging 45 days in milk (standard deviation: 3) were assigned to 8 blocks of 2 animals each according to their milk production (45 kg/d; standard deviation: 6) during the week preceding the beginning of the experiment. Within each block, they received weekly intramuscular injections of either saline (CON) or folic acid and vitamin B-12 (VIT) during 5 consecutive weeks. During the last week, the cows were fed 75% of their ad libitum intake during 4 d. Blood samples were taken the morning before starting the feed restriction and on the third day of feed restriction. On the fourth day of feed restriction, the daily meal was not served and an intravenous glucose tolerance test was performed. During the 4 wk preceding the feed restriction, milk production and DMI were not affected by treatments. During the feed restriction, the vitamin supplement tended to decrease milk fat concentration and increase milk concentration of lactose. Plasma concentrations of homocysteine, Ile, Leu, Val, and branched-chain AA increased in VIT cows during the restriction but not in CON cows. During the glucose tolerance test, insulin peak height was lower and insulin incremental positive area under the curve tended to be lower for VIT than for CON [83 (95% confidence interval, CI: 64-108) vs. 123 (95% CI: 84-180) mu g.180 min/L, respectively]. Free fatty acid nadir was reached earlier for VIT than for CON [34 (95% CI: 26-43) vs. 46 (95% CI: 31-57) min, respectively]. Glucose area under the curve, clearance rate and peak height, insulin time to reach the peak and clearance rate, and free fatty acid nadir did not differ between VIT and CON. The reduction in insulin release during a glucose tolerance test without changes in glucose clearance rate or area under the curve suggests that the vitamin supplement improved insulin sensitivity in feed-restricted lactating dairy cows.

Application In Synthesis of 1-Phenylurea. Welcome to talk about 64-10-8, If you have any questions, you can contact Girard, CL; Vanacker, N; Beaudet, V; Duplessis, M; Lacasse, P or send Email.

Reference:
Thiomorpholine – Wikipedia,
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An article Study on the performance and mechanism of degradation of toluene with non-thermal plasmas synergized supported TiO2/gamma-Al2O3 catalyst WOS:000670392300001 published article about BARRIER DISCHARGE REACTOR; BY-PRODUCTS; PHOTOCATALYTIC ACTIVITIES; ATMOSPHERIC-PRESSURE; VISIBLE-LIGHT; GAS-PHASE; REMOVAL; DECOMPOSITION; CONVERSION; OXIDATION in [Li, Mengyu; Li, Dandan; Zhang, Ziqi; Ji, Chunjie; Zhou, Shuo; Guo, Wenwen; Zhao, Chaocheng; Liu, Fang; Han, Fenglei] China Univ Petr East China, Sch Chem Engn, Qingdao 266580, Shandong, Peoples R China; [Zhao, Chaocheng; Liu, Fang; Han, Fenglei] Minist Sci & Technol, Key Lab Petr & Petrochem Pollut Control & Treatme, Beijing, Peoples R China in 2021.0, Cited 54.0. COA of Formula: C13H10O. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

The degradation of toluene in dielectric barrier discharge (DBD) reactor packed with supported photocatalysts TiO2/gamma-Al2O3, Ce-TiO2/gamma-Al2O3, Ag-TiO2/gamma-Al2O3, La-TiO2/gamma-Al2O3, and Co-TiO2/gamma-Al2O3 was investigated.The supported catalysts were prepared by sol-gel and impregnation methods and were characterized in detail using N-2 adsorption,XRD,TEM,XPS and UV-Vis analysis technology. Compared to the non-thermal plasma (NTP) alone system, the degradation rate of toluene and CO2 selectivity improved significantly with the combination of plasma and photocatalysts, meanwhile, the CO selectivity and the by-products NO2 and O-3 reduced. When the photocatalyst Ag-TiO2/gamma-Al2O3 was packed into the discharge region,this plasma-photocatalytic system could completely remove toluene with above 81% CO2 selectivity and greatly reduced concentration of poisonous byproducts (O-3 and NO2) at 5 kJ.L-1, while exhibiting superior stability. The energy efficiency of the hybrid system was increased by about 1.4-3 times, compared with the separated NTP. The main energy loss was the formation of by-products and the loss of light and heat. Finally, the intermediate products of the toluene degradation process of different catalyst systems were analyzed by GC-MS, and the mechanism of toluene degradation by the NTP-photocatalytic system was concluded. The process of NTP synergistic photocatalytic degradation of toluene mainly included three aspects: NTP degradation of toluene, photocatalytic oxidation degradation of toluene, and the synergistic effect between the two. The results can provide a theoretical basis for the study on the performance of VOCs degradation by NTP, and have certain guiding significance for the application and mechanism research of VOCs degradation by NTP.

COA of Formula: C13H10O. About Benzophenone, If you have any questions, you can contact Li, MY; Li, DD; Zhang, ZQ; Ji, CJ; Zhou, S; Guo, WW; Zhao, CC; Liu, F; Han, FL or concate me.

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Thiomorpholine – Wikipedia,
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Category: thiomorpholine. Authors Gregson, CHU; Noble, A; Aggarwal, VK in WILEY-V C H VERLAG GMBH published article about in [Gregson, Charlotte H. U.; Noble, Adam; Aggarwal, Varinder K.] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England in 2021.0, Cited 44.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

The azetidine moiety is a privileged motif in medicinal chemistry and new methods that access them efficiently are highly sought after. Towards this goal, we have found that azabicyclo[1.1.0]butyl carbinols, readily obtained from the highly strained azabicyclo[1.1.0]butane (ABB), can undergo divergent strain-release reactions upon N-activation. Treatment with trifluoroacetic anhydride or triflic anhydride triggered a semipinacol rearrangement to give keto 1,3,3-substituted azetidines. More than 20 examples were explored, enabling us to evaluate selectivity and the migratory aptitude of different groups. Alternatively, treatment of the same alcohols with benzyl chloroformate in the presence of NaI led to iodohydrin intermediates which gave spiroepoxy azetidines upon treatment with base. The electronic nature of the activating agent dictates which pathway operates.

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I found the field of Chemistry very interesting. Saw the article CuI/I-2-Catalyzed Concise Synthesis of Substituted 6-Aminoisoquinolinoquinazoline Carboxylates from Anthranilamide published in 2020. Name: 2-Aminobenzamide, Reprint Addresses Alla, M (corresponding author), Indian Inst Chem Technol, CSIR, Div Fluoro & Agro Chem, Hyderabad 500007, Andhra Pradesh, India.; Alla, M (corresponding author), Acad Sci & Innovat Res AcSIR, Ghaziabad 201002, India.. The CAS is 88-68-6. Through research, I have a further understanding and discovery of 2-Aminobenzamide

A one pot sequential addition protocol for synthesis of polycyclic quinazolines with beta-amino acid motifs has been achieved starting from anthranilamide. Initialin situformation of 2-(2-bromophenyl)quinazolin-4(3H)-one followed by addition of alkyl cyanoacetates catalyzed by copper (I) salts gives the target compound in good to excellent yields. The expedient and facile cascade protocol involves nucleophilic alpha-arylation, intramolecular cycloamidation of nitriles followed by 1,3-hydrogen shift allowing direct access to 6-amino-8-oxo-8H-isoquinolino[1,2-b]quinazoline-5-carboxylates.

Name: 2-Aminobenzamide. Welcome to talk about 88-68-6, If you have any questions, you can contact Reddy, PG; Indukuri, DR; Alla, M or send Email.

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Thiomorpholine – Wikipedia,
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Ansari, SA; Deshmukh, SU; Patil, RB; Damale, MG; Patil, RH; Alkahtani, HM; Almehizia, AA; Al-Tuwajiri, HM; Aleanizy, FS; Alqahtani, FY; Pathan, SK; Sangshetti, JN in [Ansari, Siddique A.; Alkahtani, Hamad M.; Almehizia, Abdulrahman A.; Al-Tuwajiri, Hanaa M.] King Saud Univ, Dept Pharmaceut Chem, Coll Pharm, POB 2454, Riyadh 11451, Saudi Arabia; [Deshmukh, Satish U.] Deogiri Coll, Dept Chem, Aurangabad 431005, Maharashtra, India; [Patil, Rajesh B.] Smt Kashibai Navale Coll Pharm, Sinhgad Tech Educ Societys, Pune 411048, Maharashtra, India; [Damale, Manoj G.] Srinath Coll Pharm, Dept Pharmaceut Med Chem, Aurangabad 431136, Maharashtra, India; [Patil, Rajendra H.] Savitribai Phule Pune Univ, Dept Biotechnol, Pune 411007, Maharashtra, India; [Aleanizy, Fadilah S.; Alqahtani, Fulwah Y.] King Saud Univ, Dept Pharmaceutcs, Coll Pharm, POB 2454, Riyadh 11451, Saudi Arabia; [Pathan, Shahebaaz K.; Sangshetti, Jaiprakash N.] YB Chavan Coll Pharm, Dr Rafiq Zakaria Campus, Aurangabad 431001, Maharashtra, India published Identification of Promising Biofilm Inhibitory and Cytotoxic Quinazolin-4-one Derivatives: Synthesis, Evaluation, Molecular Docking and ADMET Studies in 2019, Cited 35. COA of Formula: C7H8N2O. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6.

A library of 2,3-dihydroquinazolin-4(1H)-one derivatives (5 a-k) were synthesized in good yield by using 1-Ethyl-3-Methylimidazolium hydrogen sulphate (10 mol %) as a catalyst and were evaluated for their anti-biofilm, antimicrobial and cytotoxicity potential. Among the synthesized compounds, 2-(4-(1H-1,2,4-triazol-1-yl)phenyl)-2,3-dihydroquinazolin-4(1H)-one (5d) and 2,3-dihydro-2-(2,4,6-trimethoxyphenyl) quinazolin-4(1H)-one (5j) displayed better anti-biofilm activity than fluconazole (IC50 = 40 mu M) with IC50 values less than 30 mu M. Compound 5d also appeared to be fungicidal against C. Albicans having MIC=33.5 mu g/ml comparable with standard fluconazole (50 mu g/ml). All the synthesized compounds were also evaluated for cytotoxic activity by using MTT assay against HeLa, A-549 and MDA-MB-231 cell lines. The compound 5d was found to be more potent against MDA-MB-231 and A549 cell lines (IC50 = 11 +/- 2 mu M and 34 +/- 8 mu M respectively) than 5-fluorouracil (IC50 = 19 +/- 3 mu M and 51 +/- 5 mu M respectively). The compounds substituted with 6-methyl-4-oxo-4H-chromen-3-yl (5a), biphenyl (5c) and 2-hydroxy-5-bromophenyl (5e) were also found to be more potent against MDA-MB-231 cell lines (IC50 = 13 +/- 3 – 14 +/- 4 mu M) than 5-fluorouracil. Molecular docking simulations were also carried out using secreted aspartyl protease (SAP5), pepA enzyme of C. albicans for biofilm inhibition and EGFR tyrosine kinase for cyto-toxicity studies. The study reveals that the compounds 5d and 5e can serve as an important lead moiety for biofilm inhibition and cyto-toxicity against MDA-MB-231 and A549 cancer cell-lines indicating their potential in the treatment of tougher fungal infections and breast and lung cancer.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Long, J; Selikhov, AN; Mamontova, E; Lyssenko, KA; Guari, Y; Larionova, J; Trifonov, AA in [Long, Jerome; Mamontova, Ekaterina; Guari, Yannick; Larionova, Joulia] Univ Montpellier, CNRS, Inst Charles Gerhardt, ENSCM,Equipe Ingenierie Mol & Nanoobjets, F-34095 Montpellier 5, France; [Selikhov, Alexander N.; Trifonov, Alexander A.] Russian Acad Sci, Inst Organometall Chem, 49 Tropinina Str,GSP-445, Nizhnii Novgorod 630950, Russia; [Selikhov, Alexander N.; Lyssenko, Konstantin A.; Trifonov, Alexander A.] Russian Acad Sci, Inst Organoelement Cpds, 28 Vavilova Str, Moscow, Russia; [Lyssenko, Konstantin A.] Moscow MV Lomonosov State Univ, Chem Dept, Moscow 119991, Russia published Synthesis, structure, magnetic and luminescence properties of two dysprosium single-molecule magnets based on phenoxide dye ligands in 2020, Cited 34. Formula: C14H10O. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8.

We report here two dysprosium complexes based on phenoxide-based emissive ligands 1-(2,4-dimetylphenylazo)-2-naphtholate (L1) and anthracenolate (L2). While 1 is a dinuclear homoleptic complex [Dy-2(L1)(6)].2C(7)H(8) exhibiting zero-field slow relaxation of magnetization, 2 is a mononuclear complex [Dy(L2)(3)(py)(3)] (py = pyridine) showing field-induced relaxation.

Bye, fridends, I hope you can learn more about C14H10O, If you have any questions, you can browse other blog as well. See you lster.. Formula: C14H10O

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Authors Li, Z; Zhang, JH; Jing, XT; Dong, J; Liu, HF; Lv, HJ; Chi, YN; Hu, CW in ROYAL SOC CHEMISTRY published article about in [Li, Zhen; Zhang, Junhao; Jing, Xiaoting; Dong, Jing; Liu, Huifang; Lv, Hongjin; Chi, Yingnan; Hu, Changwen] Beijing Inst Technol, Key Lab Cluster Sci, Beiing Key Lab Photoelectro Electrophoton Convers, Minist Educ,Sch Chem & Chem Engn, Beijing 100081, Peoples R China in 2021.0, Cited 58.0. Recommanded Product: 119-61-9. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

Electrocatalytic oxidation has been proven as a sustainable and promising alternative to traditional chemical transformation, but its further development is limited by the use of noble-metal electrocatalysts. Herein, a polyoxometalate-based electrode material, H5PMo10V2O40@CTF (denoted as PMo10V2@CTF), has been successfully fabricated through electrostatic assembly of a molecular polyoxometalate catalyst, PMo10V2, with a porous cationic covalent triazine framework (CTF), which, to our knowledge, represents the first combination of polyoxometalate with a cationic CTF. The resulting PMo10V2@CTF exhibits high activity for the selective electrocatalytic oxidation of alcohols to aldehydes, achieving 99% conversion of benzyl alcohol, over 99% selectivity of benzyl aldehyde, and at the same time near unity H-2 production. Notably, the reported electrocatalytic system presents good atom economy, high energy conversion (96% faradaic efficiency), remarkable catalytic activity and robustness for at least eight recycles. Based on the various experimental and spectroscopic analyses, a possible catalytic mechanism was proposed, revealing that such excellent electrocatalytic performance is attributed to the versatile redox ability of PMo10V2 and the good porosity and adsorption property of the CTF in the constructed PMo10V2@CTF composite.

About Benzophenone, If you have any questions, you can contact Li, Z; Zhang, JH; Jing, XT; Dong, J; Liu, HF; Lv, HJ; Chi, YN; Hu, CW or concate me.. Recommanded Product: 119-61-9

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Anthropogenic contaminants in freshwater from the northern Antarctic Peninsula region WOS:000583510100001 published article about MINNOW GOBIOCYPRIS-RARUS; PERSONAL CARE PRODUCTS; ORGANIC UV FILTERS; WASTE-WATER; ULTRAVIOLET FILTERS; PYRETHROID INSECTICIDES; PROTEOMIC RESPONSES; ESTROGENIC ACTIVITY; AQUATIC ECOSYSTEMS; IN-VITRO in [Dominguez-Morueco, Noelia; Valcarcel, Yolanda] Univ Rey Juan Carlos, Grp Invest & Docencia Toxicol Ambiental & Evaluac, Avda Tulipan Sn, Madrid, Spain; [Dominguez-Morueco, Noelia; Valcarcel, Yolanda] Rey Juan Carlos Univ, Fac Hlth Sci, Dept Prevent Med Publ Hlth Immunol & Med Microbio, Avda Atenas S-N, Madrid 28922, Spain; [Moreno-Merino, Luis; Duran Valsero, Juan Jose] Inst Geol & Minero Espana IGME, C Rios Rosas 23, Madrid 28003, Spain; [Molins-Delgado, Daniel; Diaz-Cruz, M. Silvia; Aznar-Alemany, Oscar; Eljarrat, Ethel; Farre, Marinella; Lopez de Alda, Miren] CSIC, Inst Environm Assessment & Water Res IDAEA, Dept Environm Chem, Water Environm & Food Chem Unit ENFO CHEM, C Jordi Girona 18-26, Barcelona 08034, Spain; [Lopez-Martinez, Jeronimo] Univ Autonoma Madrid, Dept Geol & Geoquim, Fac Ciencias, Madrid 28049, Spain; [Silva, Adrian] Inst Nacl Agua, Empalme J Newbery Km 1 620, Buenos Aires, DF, Argentina in 2021.0, Cited 66.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9. Product Details of 119-61-9

This study aimed to evaluate the presence of ultraviolet filters (UV-Fs), benzotriazoles, pyrethroids and per- and polyfluoroalkyl substances (PFASs) in freshwater and wastewater from the northern Antarctic Peninsula region. All water samples analyzed contained UV-Fs residues and high concentrations were detected in anthropogenic impacted sites (< LOD up to 1300 ng/L). Likewise, benzotriazoles were detected in all water samples (< LOQ-920 ng/L). Regarding suspended particulate matter, almost all UV-Fs and all benzotriazoles were measured at concentrations ranging from < LOQ to 33 mu g/g dry weight. Pyrethroids were also detected (< LOQ-250 ng/L) and their presence implies the existence of a gateway to the Antarctica Peninsula from other regions. The data confirmed the presence of PFASs (< LOD-7500 ng/L) in this area, in agreement with previous studies. In light of these results, extended monitoring in Antarctica should be carried out to perform a reliable environmental risk assessment leading to propose recommendations to minimize the anthropic impact. About Benzophenone, If you have any questions, you can contact Dominguez-Morueco, N; Moreno-Merino, L; Molins-Delgado, D; Diaz-Cruz, MS; Aznar-Alemany, O; Eljarrat, E; Farre, M; Lopez-Martinez, J; de Alda, ML; Silva, A; Valsero, JJD; Valcarcel, Y or concate me.. Product Details of 119-61-9

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Recommanded Product: 2-Aminobenzamide. In 2020 J HETEROCYCLIC CHEM published article about AZIDE-ALKYNE CYCLOADDITION; ONE-POT SYNTHESIS; 1,3-DIPOLAR CYCLOADDITION; CATALYST; ANTIBACTERIAL; DENDRIMERS; CHEMISTRY; COPPER(I); ANALOGS in [Keivanloo, Ali; Bakherad, Mohammad; Mokhtarei, Lotfollah] Shahrood Univ Technol, Fac Chem, Shahrood 3619995161, Iran in 2020, Cited 42. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6.

Water soluble sodium 4-amino-5-hydroxy-7-sulfonaphthalene-2-sulfonate ligand was used successfully for the preparation of 1,2,3-triazoles pharmacophore linked-quinazolinone scaffold. The reaction of ethyl 4-oxo-3,4-dihydroquinazoline-2-carboxylate and related amide compounds with propargyl bromide afforded ethyl 4-oxo-3-(prop-2-yn-1-yl)-3,4-dihydroquinazoline-2-carboxylate and its amide derivatives. The reaction of propargylated compounds with azides catalyzed by copper (II) salt, in the presence of Sodium 4-amino-5-hydroxy-7-sulfonaphthalene-2-sulfonate as a ligand in water produced novel 1,2,3-triazole pharmacophore linked-quinazolinone-4-one scaffold with high-to-excellent yields. The ligand assisted in the click reaction and reduced loading of copper salt to 2 mol%. Simplicity, short reaction times, use of water as green solvent, and low catalyst loading are the main advantages of this procedure.

Recommanded Product: 2-Aminobenzamide. About 2-Aminobenzamide, If you have any questions, you can contact Keivanloo, A; Bakherad, M; Mokhtarei, L or concate me.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

In 2021.0 MONATSH CHEM published article about HANTZSCH 1,4-DIHYDROPYRIDINES; POLYMER MICROSPHERES; SELECTIVE OXIDATION; MOLECULAR-OXYGEN; GRAPHENE OXIDE; EFFICIENT; ALCOHOLS; BENZIMIDAZOLES; AROMATIZATION; SURFACE in [Sharma, Sukanya; Choudhary, Anu; Sharma, Shally; Shamim, Tahira; Paul, Satya] Univ Jammu, Dept Chem, Jammu 180006, India in 2021.0, Cited 48.0. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6. Category: thiomorpholine

The present protocol uncover a new strategy to synthesize highly efficient solid TEMPO based catalyst in which 4-oxo-TEMPO was covalently tethered to the surface of amine functionalized magnetic titania. The chemical nature and structure of the synthesized catalyst was authenticated by various techniques such as Fourier transform infrared spectroscopy, thermogravimetric analysis, X-ray powder diffraction, field emission gun scanning electron microscopy, high resolution transmission electron microscopy, energy dispersive X-ray spectroscopy, elemental analysis, and vibrating sample magnetometer. FT-IR confirmed the immobilization of titania, APTES, and TEMPO on the magnetic nanoparticles. Thermal behaviour of the catalyst was studied by TGA. Morphology of the catalyst was investigated by FEG-SEM and HR-TEM analysis. Furthermore, loading content of TEMPO on the catalyst was quantified by elemental analysis and found to be 0.61 mmol/g. Magnetic properties of the catalyst were investigated by VSM analysis. The catalytic performance of the synthesized catalyst has been investigated for the oxidative synthesis of benzimidazoles, oxidative aromatization of 1,4-dihydropyridines, and oxidative trimerization of indoles using molecular oxygen. In addition, the catalyst could be successfully recycled and reused up to five times without the prominent loss of catalytic activity.

Category: thiomorpholine. About 3-Nitrobenzaldehyde, If you have any questions, you can contact Sharma, S; Choudhary, A; Sharma, S; Shamim, T; Paul, S or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem