Category: Thiomorpholine

In 2019 TETRAHEDRON LETT published article about CATALYZED DENITROGENATIVE ANNULATION; TERT-BUTYL NITRITE; NEMATOCIDAL ACTIVITIES; SELECTIVE SYNTHESIS; DERIVATIVES; 1,2,3-BENZOTRIAZINE-4-(3H)-ONES; ACID in [Barak, Dinesh S.; Mukhopadhyay, Sushobhan; Dahatonde, Dipak J.; Batra, Sanjay] CSIR Cent Drug Res Inst, Med & Proc Chem Div, Sect 10,Jankipuram Extens,Sitapur Rd, Lucknow 226031, Uttar Pradesh, India; [Batra, Sanjay] CSIR HRDC, Postal Staff Coll Area, Sect 19, Ghaziabad 201002, India in 2019, Cited 39. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6. Application In Synthesis of 2-Aminobenzamide

An efficient transformation of 2-aminobenzamides to 1,2,3-benzotriazin-4(3H)-ones in the presence of sodium nitrite (NaNO2) and Iodine (I-2) is described. The reaction is proposed to proceed via formation of nitrosyl halide that induces nitrosylation of the amino group of 2-aminobenzamide leading to diazotization followed by intramolecular cyclization. (C) 2018 Elsevier Ltd. All rights reserved.

Application In Synthesis of 2-Aminobenzamide. About 2-Aminobenzamide, If you have any questions, you can contact Barak, DS; Mukhopadhyay, S; Dahatonde, DJ; Batra, S or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Hybrid Cobalt Doped-Cerium Oxide as a Multifunctional Nanocatalyst for Various Organic Transformations WOS:000482173100015 published article about PALLADIUM-CATALYZED CYANATION; AEROBIC OXIDATIVE CONVERSION; REDUCTIVE AMINATION; HIGHLY EFFICIENT; ARYL BROMIDES; NITRILES; ALDEHYDES; ACID; NANOPARTICLES; ALCOHOLS in [Ghosh, Topi; Mohammad, Akbar; Mobin, Shaikh M.] Indian Inst Technol Indore, Discipline Chem, Khandwa Rd, Indore 453552, Madhya Pradesh, India; [Mobin, Shaikh M.] Indian Inst Technol Indore, Discipline Met Engn & Mat Sci, Khandwa Rd, Indore 453552, Madhya Pradesh, India; [Mobin, Shaikh M.] Indian Inst Technol Indore, Discipline Biosci & Biomed Engn, Khandwa Rd, Indore 453552, Madhya Pradesh, India in 2019, Cited 91. Application In Synthesis of 4-Methoxybenzyl acetate. The Name is 4-Methoxybenzyl acetate. Through research, I have a further understanding and discovery of 104-21-2

Development of a low-cost, environmentally benign and robust catalyst for multipurpose industrially relevant organic transformations is highly desirable for the sustainable future of chemical industries. A hybrid cobalt doped-cerium oxide nanocatalyst (Co@CeO2NC) was prepared via simple coprecipitation method using water as the solvent. The characterization of Co@CeO2NC was performed using different techniques such as XRD, TGA, FE-SEM, HR-TEM, EDAX-mapping, BET, and XPS analysis. The structural characterization of the prepared sample by XRD and XPS analysis revealed the presence of the mixed phase of cobalt oxide and cobalt doped-cerium oxide as a hybrid (Co@CeO2NC). Industrially relevant organic transformations such as (i) nitrile formation using aldehyde with hydroxyl amine hydrochloride, (ii) reductive amination of aldehydes to form tertiary N,N-dimethyl amines, and (iii) direct acetylation of alcohols/amines with acetic acid were achieved in an excellent manner using Co@CeO2NC hybrid as the multifunctional catalyst. Excellent catalytic activity of Co@CeO2NC was noticed for the conversion of 4-chlorobenzaldehyde to 4-chlorobenzonitrile with 99% conversion and 99% selectivity and 100% conversion of benzaldehyde to N,N-dimethylbenzylamine using DMF as NMe2 source, reductant, and solvent. Moreover, acetylation of 4-methoxybenzyl alcohol and 2-methyl aniline gave excellent conversion and selectivity toward the formation of -O and -N acetyl. The scope of the Co@CeO2NC was further evaluated for other aldehydes, alcohols, and amines with an excellent conversion and high selectivity.

Application In Synthesis of 4-Methoxybenzyl acetate. About 4-Methoxybenzyl acetate, If you have any questions, you can contact Ghosh, T; Mohammad, A; Mobin, SM or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Improvement of pesticide removal in contaminated media using aqueous extracts from contaminated biopurification systems WOS:000504009600071 published article about BIOREMEDIATION SYSTEMS; BACTERIAL COMMUNITY; INCP-1 PLASMIDS; DEGRADATION; DIURON; SOIL; BIODEGRADATION; MINERALIZATION; HYDROLASE; IMPACTS in [Aguilar Romero, Ines; van Dillewijn, Pieter; Romero, Esperanza] CSIC, EEZ, Dept Environm Protect, C Prof Albareda 1, E-18008 Granada, Spain; [Nesme, Joseph; Sorensen, Soren J.] Univ Copenhagen, Dept Biol, Sect Microbiol, DK-2100 Copenhagen, Denmark in 2019.0, Cited 44.0. Category: thiomorpholine. The Name is 1-Phenylurea. Through research, I have a further understanding and discovery of 64-10-8

Despite certain limitations, bioaugmentation enhances the efficiency of bioremediation systems. In this study, three aqueous extracts (APE, ACE and APE) from aged residual biomixtures in three biopurification systems (BPSs) exposed to pesticides at a pilot scale were found to improve pesticide removal. The addition of ACEs and AVEs to solutions containing the model compound diuron increased removal rates 6- and 17-fold, respectively, as compared to APEs. These extracts also increased the removal of the metabolite 3,4-dichloroaniline, while AVEs, in particular, were found to remove all pesticides within 9 days. Three metabolites less hazardous than 3,4-dichloroaniline were identified by SPME/GC/MS. AVEs, which also enhance linuron removal in liquid media, were found to increase diuron removal 6-fold in BPSs. We observed an increase in the relative abundance of taxa, such as Chloroflexi, Acidobacteria, Gemmatimonadetes, Firmicutes, Deinococcus-Thermus and especially Proteobacteria (10%), in AV biomixtures, as well as an enrichment of gamma-proteobacteria and the actinobacterial genus Dokdonella in AVEs with respect to initial noncontaminated IV biomixture. We demonstrate that extracts containing a pollutant-acclimatized microbiome could be used as part of a bioaugmentation strategy to improve the functioning of on-farm BPSs and contaminated systems. (c) 2019 Elsevier B.V. All rights reserved.

Category: thiomorpholine. About 1-Phenylurea, If you have any questions, you can contact Romero, IA; van Dillewijn, P; Nesme, J; Sorensen, SJ; Romero, E or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article An expeditious synthesis of 2,3-dihydroquinozoline-4(1H)-ones using graphene-supported sulfonic acid WOS:000501404400001 published article about ONE-POT SYNTHESIS; IONIC-LIQUID; HIGHLY EFFICIENT; ENANTIOSELECTIVE SYNTHESIS; QUINAZOLINONE DERIVATIVES; HETEROGENEOUS CATALYSIS; OXIDE NANOSHEETS; GREEN; ADSORPTION; WATER in [Gajare, Shivanand; Jagadale, Megha; Naikwade, Altafhusen; Bansode, Prakash; Patil, Pradnya; Rashinkar, Gajanan] Shivaji Univ, Dept Chem, Kolhapur 416004, Maharashtra, India in 2020, Cited 86. Computed Properties of C7H8N2O. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6

Graphene-supported sulfonic acid (Gr@SO3H) has been prepared by covalent grafting of (3-mercaptopropyl)trimethoxysilane in the matrix of graphene followed by treatment with sulfuric acid and hydrogen peroxide. Gr@SO3H has been successfully characterized by Fourier transform infrared (FT-IR) spectroscopy, Fourier transform Raman (FT-Raman) spectroscopy, CP-MAS C-13 NMR spectroscopy, thermogravimetric analysis (TGA), energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET) analysis, and X-ray diffractometer (XRD) analysis. Gr@SO3H served as a robust heterogeneous catalyst for the synthesis of bioactive 2,3-dihydroquinazolin-4(1H)-ones from anthranilamide and aryl aldehydes in ethanol. Recyclability experiments were executed successfully for six consecutive runs.

Computed Properties of C7H8N2O. About 2-Aminobenzamide, If you have any questions, you can contact Gajare, S; Jagadale, M; Naikwade, A; Bansode, P; Patil, P; Rashinkar, G or concate me.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Viti, ML; Mendes, KF; dos Reis, FC; Guimaraes, ACD; Soria, MTM; Tornisielo, VL in [Viti, Marcela Lembi; dos Reis, Fabricia Cristina; Tornisielo, Valdemar Luiz] Univ Sao Paulo, Ctr Nucl Energy Agr, Piracicaba, SP, Brazil; [Mendes, Kassio Ferreira] Univ Fed Vicosa, Vicosa, MG, Brazil; [Dias Guimaraes, Ana Carolina] Univ Mato Grosso State, Alta Floresta, Mato Grosso, Brazil; [Martinez Soria, Maria Teresa] Univ La Rioja, Logrono, La Rioja, Spain published Characterization and Metabolism of Bound Residues of Three Herbicides in Soils Amended with Sugarcane Waste in 2021.0, Cited 47.0. Computed Properties of C7H8N2O. The Name is 1-Phenylurea. Through research, I have a further understanding and discovery of 64-10-8.

This study evaluated the remobilization, mineralization, and metabolism of herbicide-bound residues in soils amended with various types of sugarcane waste. Soil with bound residues of three herbicides and fresh soil samples were added to the biometric flasks, followed by the addition of vinasse, filter cake, or sugarcane straw in order to reactivate the microbial activity. In sandy loam soil, higher mineralization was observed where filter cake was added, and the maximum mineralized percentage was 7.7, 46.7, and 8.1% of diuron-, hexazinone-, and metribuzin-bound residues, respectively. Conversely, this soil presented a greater percentage of re-extractable hexazinone and metribuzin residues when vinasse was added. Among the examined herbicides, a higher percentage of bound metribuzin residues remained in the soil (57.5-75.6%). It was possible to identify both metabolites and parent compounds in the re-extracted residues, implying either species could bind to the soil. Therefore, this study has shown that bound residues of three herbicides and their metabolites can become bioavailable, and mineralized or returned to the soil solution, which could adversely affect subsequent crops or non-target organisms. Hence, the remobilization of bound residues must be taken into account when assessing the environmental risk of herbicides in soils in registration processes.

About 1-Phenylurea, If you have any questions, you can contact Viti, ML; Mendes, KF; dos Reis, FC; Guimaraes, ACD; Soria, MTM; Tornisielo, VL or concate me.. Computed Properties of C7H8N2O

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Authors Devaraj, K; Ingner, FJL; Sollert, C; Gates, PJ; Orthaber, A; Pilarski, LT in AMER CHEMICAL SOC published article about BENZYNE; INSERTION; GENERATION; PHENOLS in [Devaraj, Karthik; Ingner, Fredric J. L.; Sollert, Carina; Pilarski, Lukasz T.] Uppsala Univ, Dept Chem BMC, Box 576, S-75123 Uppsala, Sweden; [Gates, Paul J.] Univ Bristol, Sch Chem, Cantocks Close, Bristol BS8 1TS, Avon, England; [Orthaber, Andreas] Uppsala Univ, Dept Chem, Angstrom Labs, Box 523, S-75120 Uppsala, Sweden in 2019, Cited 90. Quality Control of 2-Aminobenzamide. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6

A new, operationally simple approach is presented to access arynes and their fluoride-activated precursors based on Ru-catalyzed C-H silylation of arylboronates. Chromatographic purification may be deferred until after aryne capture, rendering the arylboronates de facto precursors. Access to various new arynes and their derivatives is demonstrated, including, for the first time, those based on a 2,3-carbazolyne and 2,3-fluorenyne core, which pave the way for novel derivatizations of motifs relevant to materials chemistry.

Quality Control of 2-Aminobenzamide. About 2-Aminobenzamide, If you have any questions, you can contact Devaraj, K; Ingner, FJL; Sollert, C; Gates, PJ; Orthaber, A; Pilarski, LT or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Authors Kannan, V; Sreekumar, K in WILEY published article about ALDER REACTION; STEREOSELECTIVE-SYNTHESIS; LEWIS-ACID; COMPLEXES; PYRANO; CIS; DERIVATIVES; ZINC(II) in [Kannan, V.] Govt Coll, Dept Chem, Kattappana, India; [Sreekumar, K.] Cochin Univ Sci & Technol, Dept Appl Chem, Cochin 682022, Kerala, India in 2021.0, Cited 39.0. Product Details of 99-61-6. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6

Clay supported catalysts based on 2- hydroxy naphthaldehyde and amino acids, their copper and titanium complexes have been described. The catalysts were found to be active toward the synthesis of pyrano-, furanoquinolines through Aza-Diels Alder reaction. The catalysts gave good yield and high enantioselectivity. The catalysts were environmentally friendly, economical, synthetically robust and reusable.

Product Details of 99-61-6. About 3-Nitrobenzaldehyde, If you have any questions, you can contact Kannan, V; Sreekumar, K or concate me.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Computed Properties of C14H10O. Authors Otsuka, H; Dohi, Y; Matsui, T; Hanada, K in IRON STEEL INST JAPAN KEIDANREN KAIKAN published article about in [Otsuka, Hiroshi; Dohi, Yusuke; Matsui, Takashi] JFE Steel Corp, Steel Res Lab, 1 Kokan Cho, Fukuyama, Hiroshima 7218510, Japan; [Hanada, Kazutoshi] JFE Technores Corp, Steel Res Lab, Chuo Ku, Kawasaki Cho, Chiba, Chiba 2600835, Japan in 2019, Cited 16. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8

Coal fluidity is an important parameter in coal blending techniques for coke making because it strongly influences coke qualities. On the other hand, recently, the amount of high fluidity coal has been limited. To cope with this problem, caking additive method which improves fluidity of coal has been developed and commercialized. However, since tight supply of high fluidity coal is anticipated in the future, it is of great importance to develop more effective caking additive. Therefore, in this study, we investigated effect of 11 kinds of polyaromatic hydrocarbons which include oxygen, sulfur and nitrogen containing compounds on coal fluidity in order to search for more effective chemical substances. The additives were added to low fluidity coal, and fluidity analyses were carried out according to the Gieseler plastometer method. Addition of sulfur and oxygen containing compounds lowered fluidity of coal, whereas addition of aromatic amines enhanced fluidity of coal. Coal fluidity ameliorated with increasing the molecular weight of aromatic amine, and N,N’-di-2-naphthyl-1,4-phenylenediamine (DNPD) was the most effective aromatic amine in this study. Carbonization tests in an electric furnace were conducted to investigate an effect of DNPD on coke strength. As a result of adding only 1 wt% DNPD, fluidity of blended coal and coke strength (Drum Index) were highly improved.

Computed Properties of C14H10O. About Anthrone, If you have any questions, you can contact Otsuka, H; Dohi, Y; Matsui, T; Hanada, K or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Category: thiomorpholine. In 2019 ACTA CRYSTALLOGR C published article about ENANTIOSELECTIVE TOTAL-SYNTHESIS; ASYMMETRIC-SYNTHESIS; NATURAL-PRODUCTS; DERIVATIVES; ACID; CYCLOADDITION; QUINAZOLINONE; CONSTRUCTION; ANALOGS; SET in [Chernyshov, Vladimir V.; Gatilov, Yuri, V; Yarovaya, Olga, I; Koskin, Igor P.; Salakhutdinov, Nariman F.] NN Vorozhtsov Novosibirsk Inst Organ Chem SB RAS, 9 Acad Lavrentiev Ave, Novosibirsk 630090, Russia; [Chernyshov, Vladimir V.; Gatilov, Yuri, V; Yarovaya, Olga, I; Brylev, Konstantin A.] Novosibirsk State Univ, Pirogova St 2, Novosibirsk 630090, Russia; [Yarovoy, Spartak S.; Brylev, Konstantin A.] Nikolaey Inst Inorgan Chem SB RAS, 3 Acad Lavrentiev Ave, Novosibirsk 630090, Russia in 2019, Cited 41. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6.

The possibility of a single-stage solvent-free stereoselective synthesis of a spirocyclic compound from the natural bicyclic monoterpenoid (-)-fenchone and anthranilamide has been shown for the first time. The molecular and crystal structure of (1R,2S,4S)-1,3,3-trimethyl-10H-spiro[bicyclo[2.2.1]heptane-2,2′-quinazolin]-4′(3’H)-one, C17H22N2O, was established by X-ray diffraction though the chirality was assumed via the known reactant connectivity and H-1 and C-13 NMR spectroscopy. It has shown that in the molecule, for steric reasons, there is an elongation of the Me2C-C(N)N bond to 1.603 (5) A degrees. The formation of dimers via N-H center dot center dot center dot O C hydrogen bonds with an interaction energy of 93.30 kJ mol(-1) and through cavities (33.7% of the unit-cell volume) was established in the packing of the molecules. There are no pi-stacking interactions in the structure.

Category: thiomorpholine. About 2-Aminobenzamide, If you have any questions, you can contact Chernyshov, VV; Gatilov, YV; Yarovaya, OI; Koskin, IP; Yarovoy, SS; Brylev, KA; Salakhutdinov, NF or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Computed Properties of C7H5NO3. Authors Ma, RN; Xiao, ZY; Zhong, W; Lu, CX; Shen, ZQ; Zhao, D; Liu, XM in WILEY published article about in [Ma, Ruonan; Xiao, Zhiyin; Zhong, Wei; Lu, Chunxin; Shen, Zhongquan; Liu, Xiaoming] Jiaxing Univ, Coll Biol Chem Sci & Engn, Jiaxing 314001, Peoples R China; [Ma, Ruonan; Zhao, Dan; Liu, Xiaoming] Nanchang Univ, Sch Chem, Nanchang 330031, Jiangxi, Peoples R China in 2021.0, Cited 35.0. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6

Cuprous halides, best described as (CuX)(n) (X = Cl-, Br-, and I-) in their solid state, catalyse selective aerobic oxidation of alcohols with the assistance of both NMI (N-methylimidazole) and TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl), and the iodide generally demonstrates the highest activity, for example, in the oxidation of 1-octanol at ambient temperature under 24 h’ reaction. However, in the aerobic oxidation of benzylic alcohols, the chloride showed superiority to the iodide in that the aerobic oxidation was quantitatively completed within 3 h at ambient temperature whereas the iodide showed only about half the activity of the chloride analogue. By probing the system using electrochemistry, electric conductivity, and H-1 NMR titration, it was revealed that the surprising anomaly was due to the difference in the rate of forming active species, [Cu (NMI)(2)X(MeCN)], from the polymeric solid in a two-stage process. Substrates expansion of 11 benzylic alcohols indicated that CuCl/NMI/TEMPO system demonstrated quantitative conversion of benzylic alcohols into corresponding aldehydes within 3 h and showed great tolerance to the substituents on the phenyl ring of the substrates. Furthermore, electron-withdrawing substituent was beneficial to the oxidation and could offset the steric effect at orthro-substituent. Such a behaviour suggested that in the catalysis, increasing the acidity of the hydroxyl group (OH) of the substrates could ease the oxidation, which implied that the deprotonation via an internal pathway might be one of the rate-determining steps. Our results also showed that the anion halide participated actively in the catalysis by coordinating to Cu(I) in the active species.

About 3-Nitrobenzaldehyde, If you have any questions, you can contact Ma, RN; Xiao, ZY; Zhong, W; Lu, CX; Shen, ZQ; Zhao, D; Liu, XM or concate me.. Computed Properties of C7H5NO3

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem