Category: Thiomorpholine

Quality Control of Anthrone. Chhanda, SA; Itsuno, S in [Chhanda, Sadia Afrin; Itsuno, Shinichi] Toyohashi Univ Technol, Dept Appl Chem & Life Sci, Toyohashi, Aichi 4418580, Japan published Design and synthesis of chiral hyperbranched polymers containing cinchona squaramide moieties and their catalytic activity in the asymmetric Michael addition reaction in 2019, Cited 39. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8.

Chiral hyperbranched polymers (HBP) containing cinchona alkaloids were synthesized using a Mizoroki-Heck (MH) coupling polymerization reaction between a cinchona squaramide dimer and tri- or tetrasubstituted aromatic iodides. This is a new type of polymeric chiral organocatalyst. We found that the as-obtained chiral HBPs show excellent catalytic activity in the asymmetric Michael reaction. Almost perfect enantioselectivity (>99% ee) was achieved in the reaction of beta-ketoester and trans-beta-nitrostyrene. The three-dimensional network structure of the chiral HBPs is structurally robust and can be reused for further reaction without any loss in their catalytic activity. (C) 2019 Elsevier Inc. All rights reserved.

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Category: thiomorpholine. In 2020 J MOL STRUCT published article about 2-PHOTON ABSORPTION; OPTICAL PROPERTIES; MOLECULES; DESIGN; FLUORESCENCE; EXCITATION in [Saha, Amrita] Assam Univ, Dept Chem, Silchar 788011, India; [Singh, Asha; Chari, Rama; Jayabalan, J.] Raja Ramanna Ctr Adv Technol, Mat Sci Sect, Nano Sci Lab, Indore 452013, India; [Chari, Rama; Jayabalan, J.] Homi Bhabha Natl Inst, Training Sch Complex, Mumbai 400094, Maharashtra, India in 2020, Cited 50. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8.

Using green chemical method a series of fifteen systematically substituted 3-(9-substituted anthracen-10-yl)-1-(4-phenyl substituted)prop-2-en-1-one derivatives having high nonlinear absorption coefficient have been synthesized. The nonlinear absorption properties of these compounds were studied using nanosecond pulses at 532 nm wavelength. All 15 derivatives are found to show high nonlinear absorption in the range of 35-640 cm/GW. Among these the derivatives with-NO2 as one of the substitution group show higher nonlinear absorption. The origin of high nonlinear absorption with low linear absorption in the compounds has been attributed to two-step two-photon absorption process. We have shown that the energy bands of these compounds are distributed such that for excitation at 532 nm they have strong nonlinear absorption. These properties of the reported compounds make them a potential candidate for biological imaging and other applications which are based on nonlinear absorption. (C) 2020 Elsevier B.V. All rights reserved.

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Recently I am researching about BIOLOGICAL EVALUATION; DERIVATIVES; PI3K/AKT/MTOR; GEFITINIB; PATHWAY; DESIGN; GROWTH, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [81430085]; Natural Science Foundation of Henan [182300410321]. Published in ELSEVIER FRANCE-EDITIONS SCIENTIFIQUES MEDICALES ELSEVIER in ISSY-LES-MOULINEAUX ,Authors: Li, ED; Lin, Q; Meng, YQ; Zhang, LY; Song, PP; Li, N; Xin, JC; Yang, P; Bao, CN; Zhang, DQ; Zhang, Y; Wang, JK; Zhang, QR; Liu, HM. The CAS is 88-68-6. Through research, I have a further understanding and discovery of 2-Aminobenzamide. Computed Properties of C7H8N2O

A series of novel 2,4-disubstituted quinazolines were synthesized and evaluated for their anti-tumor activity against five human cancer cells (MDA-MB-231, MCF-7, PC-3, HGC-27 and MGC-803) using MIT assay. Among them, compound 9n showed the most potent cytotoxicity against breast cancer cells. Compound 9n also significantly inhibited the colony formation and migration of MDA-MB-231 and MCF-7 cells. Meanwhile, compound 9n induced cell cycle arrest at G1 phase and cell apoptosis, as well as increased accumulation of intracellular ROS. Furthermore, compound 9n exerted anti-tumor effects in vitro via decreasing the expression of anti-apoptotic protein Bcl-2 and increasing the pro-apoptotic protein Bax and p53. Mechanistically, compound 9n markedly decreased p-EGFR and p-PI3K expression, which revealed that compound 9n targeted breast cancer cells via interfering with EGFR-PI3K signaling pathway. Molecular docking suggested that compound 9n could indeed bind into the active pocket of EGFR. All the findings suggest that compound 9n might be a valuable lead compound for anti-tumor agents targeting breast cancer cells. (C) 2019 Elsevier Masson SAS. All rights reserved.

Welcome to talk about 88-68-6, If you have any questions, you can contact Li, ED; Lin, Q; Meng, YQ; Zhang, LY; Song, PP; Li, N; Xin, JC; Yang, P; Bao, CN; Zhang, DQ; Zhang, Y; Wang, JK; Zhang, QR; Liu, HM or send Email.. Computed Properties of C7H8N2O

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In 2019 ASIAN PAC J TROP BIO published article about ANTIOXIDANT; EXTRACT; GLUCOSE; METABOLISM in [Bouhrim, Mohamed; Ouassou, Hayat; Loukili, El Hassania; Ramdani, Mohammed; Mekhfi, Hassane; Ziyyat, Abderrahim; Legssyer, Abdelkhaleq; Aziz, Mohammed; Bnouham, Mohamed] Univ Mohamed First, Fac Sci, Oujda, Morocco in 2019, Cited 39. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8. Category: thiomorpholine

Objective: To assess the antidiabetic effect of Opuntia dillenii seed oil on rats with diabetes mellitus. Methods: A rat diabetes model was established by intraperitoneal injection of rats with 50 mg/kg streptozotocin. Thirty albino Wistar rats were divided into five groups: the diabetic control group and normal control group were treated only with distilled water, two diabetic groups received 1 and 2 mL/kg of oil per day, respectively, for 30 days and one diabetic group received 2 mg/kg of glibenclamide. In addition, blood glucose was determined weekly. Body weight, average daily food, water intake and urinary volume of each animal were determined before and after the treatment period. After the treatment period, hepatic glycogen was determined using the anthrone reagent, and glycosuria, total cholesterol, triglycerides, alanine aminotransferase, aspartate aminotransferase, urea, creatinine and uric acid were estimated using common clinical diagnostic kits. Results: Oral intake of the oil at 1 and 2 mL/kg for the diabetic animals significantly diminished blood glucose, glycosuria, total cholesterol, triglycerides, alanine aminotransferase, aspartate aminotransferase, urea, creatinine and uric acid, accompanied by a noticeable elevation in the amount of hepatic glycogen in comparison with the diabetic control group. Similarly, Opuntia dillenii seed oil significantly increased the food intake and decreased the urinary volume per day in treated rats of the same groups in comparison with the period before the treatment intervention and attenuated body weight loss in the diabetic rats. Moreover, this effect of the oil was dose dependent. On the other hand, the oil did not affect their need for water. Conclusions: The results show that Opuntia dillenii seed oil has a very important antidiabetic effect on streptozotocin-induced diabetic rats. Hence, we suggest it as a preventive control of diabetes mellitus.

Category: thiomorpholine. Welcome to talk about 90-44-8, If you have any questions, you can contact Bouhrim, M; Ouassou, H; Loukili, E; Ramdani, M; Mekhfi, H; Ziyyat, A; Legssyer, A; Aziz, M; Bnouham, M or send Email.

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In 2019 CHEMISTRYSELECT published article about MIXED-METAL OXIDES; OXIDATIVE SYNTHESIS; FACILE; QUINAZOLIN-4(3H)-ONES in [Hase, Dattatraya, V; Jayaram, Radha, V] Inst Chem Technol, Dept Chem, Mumbai 400019, Maharashtra, India; [Thirumalai, Kuppulingam; Swaminathan, Meenakshisundaram] Annamalai Univ, Photocatalysis Lab, Dept Chem, Annamalainagar 608002, Tamil Nadu, India; [Swaminathan, Meenakshisundaram] Kalasalingam Univ, Int Res Ctr, Dept Chem, Nanomat Lab, Krishnan Kovil 626126, Tamil Nadu, India in 2019, Cited 35. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6. Computed Properties of C7H8N2O

In the present study, ZnO modified with rare earth oxides GdxMn; M=Mo, V, W) were synthesized by hydrothermal process and their catalytic activity was tested in an oxidative cyclization reaction for the selective synthesis of quinazolinones. The catalysts were characterized by various techniques such as BET surface area analysis, XRD, SEM-EDX, DSC-TGA, ICP-MS and elemental color mapping. 5 wt% Gd2MoO6/ZnO exhibited good catalytic activity and gave 60-91% of Quinazolin-4(3H) ones in toluene. The catalysts could be reused at least four times without loss of catalytic activity.

Welcome to talk about 88-68-6, If you have any questions, you can contact Hase, DV; Jayaram, RV; Thirumalai, K; Swaminathan, M or send Email.. Computed Properties of C7H8N2O

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Yang, L; Chen, X; Ni, KD; Li, YS; Wu, JH; Chen, WL; Ji, Y; Feng, LL; Li, F; Chen, DY in [Yang, Lei; Chen, Xuan; Ni, Kaidong; Li, Yuansheng; Wu, Jianhong; Chen, Weilin; Li, Fei; Chen, Dongyin] Nanjing Med Univ, Sch Pharm, Dept Med Chem, Nanjing 211166, Peoples R China; [Feng, Lili] Nanjing Med Univ, Sch Pharm, Key Lab Cardiovasc & Cerebrovasc Med, Nanjing 211166, Peoples R China; [Chen, Dongyin] China Pharmaceut Univ, State Key Lab Nat Med, Nanjing 210009, Peoples R China; [Ji, Yin] Simcere Pharmaceut Grp, State Key Lab Translat Med & Innovat Drug Dev, Nanjing, Peoples R China published Proton-exchanged montmorillonite-mediated reactions of hetero-benzyl acetates: Application to the synthesis of Zafirlukast in 2020, Cited 32. COA of Formula: C10H12O3. The Name is 4-Methoxybenzyl acetate. Through research, I have a further understanding and discovery of 104-21-2.

Proton-exchanged montmorillonite (H-mont) with outstanding surface characteristics can provide abundant acidic sites in the mesopores, and serve as an efficient heterogeneous catalyst for the synthesis of heterocycle-containing diarylmethanes via Friedel-Crafts-like alkylation of (hetero)arenes by heterobenzyl acetates under mild reaction conditions without requiring any additives or an inert atmosphere. Using this strategy, the gram-scale synthesis of indole-containing diarylmethane 13 has been accomplished in good yield for the preparation of Zafirlukast. In addition, H-mont can be applied to the nucleophilic substitution reactions of heterobenzyl acetate 5p with a variety of alcohols and 1,3-dicarbonyl compounds. (C) 2020 Elsevier Ltd. All rights reserved.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Glinski, M; Markowska, A; Wronska, L; Jerzak, A; Tarkowska, M in [Glinski, Marek; Markowska, Anna; Wronska, Laura; Jerzak, Anna; Tarkowska, Magdalena] Warsaw Univ Technol, Fac Chem, PL-00664 Warsaw, Poland published Highly Selective Vapor and Liquid Phase Transfer Hydrogenation of Diaryl and Polycyclic Ketones with Secondary Alcohols in the Presence of Magnesium Oxide as Catalyst in 2021, Cited 47. Application In Synthesis of Anthrone. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8.

MgO has been shown to catalyze an almost quantitative hydrogen transfer from 2-octanol as the hydrogen donor to benzophenone to form benzhydrol, a useful intermediate product in the pharmaceutical industry. The hydrogen transfer from a series of alcohols to the carbonyl group of benzophenone, its ten derivatives, four polycyclic ketones, and 2-naphthyl phenyl ketone was carried out in liquid (LP) or vapor phase (VP). The dependence of reactivity on the structure of the hydrogen donor, reaction temperature, donor-acceptor ratio, amount of catalyst, and the type and position of substituents has been established. For both reaction modes, optimal conditions for selective synthesis of the alcohols were determined and side reactions were investigated. The results indicate that the reactivity of the ketone is suppressed by the presence of a methyl substituent in the ortho position to a much greater extent in LP mode. A scale-up was demonstrated in the liquid phase mode.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

In 2021.0 J PEPT SCI published article about ARTIFICIAL METALLOENZYMES; ASYMMETRIC HYDROGENATION; PEPTIDES; COMPLEXES; 8-AMINO-5,6,7,8-TETRAHYDROQUINOLINE; KETONES in [Rimoldi, Isabella; Bucci, Raffaella; Feni, Lucia; Facchetti, Giorgio; Pellegrino, Sara] Univ Milan, Dipartimento Sci Farmaceut, Via Venezian 21, I-20133 Milan, Italy; [Santagostini, Laura] Univ Milan, Dipartimento Chim, Milan, Italy in 2021.0, Cited 48.0. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6. Quality Control of 3-Nitrobenzaldehyde

Mets7is a methionine-rich motif present in hCtr-1 transporter that is involved in copper cellular trafficking. Its ability to bind Cu(I) was recently exploited to develop metallopeptide catalysts for Henry condensation. Here, the catalytic activity ofMets7-Cu(I)complex in Michael addition reactions has been evaluated. Furthermore,His7peptide, in which Met residues have been substituted with His ones, was also prepared. This substitution allowedHis7to coordinate Cu (II), with the obtainment of a stable turn conformation as evicted by CD experiments.His7-Cu (II)proved also to be a better catalyst thanMets7-Cu(I)in the addition reaction. In particular, when the substrate was the (E)-1-phenyl-3-(pyridin-2-yl)prop-2-en-1-one, a conversion of 71% and a significative 58% of e.e. was observed.

Welcome to talk about 99-61-6, If you have any questions, you can contact Rimoldi, I; Bucci, R; Feni, L; Santagostini, L; Facchetti, G; Pellegrino, S or send Email.. Quality Control of 3-Nitrobenzaldehyde

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Thiomorpholine – Wikipedia,
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SDS of cas: 119-61-9. Authors Biliskov, N in AMER CHEMICAL SOC published article about in [Biliskov, Nikola] Rudjer Boskovic Inst, Dept Organ Chem & Biochem, Zagreb 10000, Croatia in 2021.0, Cited 19.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

Diphenylamine reacts with benzophenone in the solid state through the formation of a eutectic liquid intermediate, from which the final product, in the form of a hydrogen-bonded cocrystal, is finally formed. By a simple experiment, the phase diagram of the benzophenone/diphenylamine system is effectively divided into two parts, which enabled monitoring of the overall process from the side of each reactant separately. Accompanied by isothermal and nonisothermal spectroscopic monitoring of the system, this provides additional details of the mechanistic pathway of the process of cocrystal formation through a metastable liquid intermediate phase.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Formula: C7H8N2O. Authors Dan, YT; Ji, MY; Tao, SP; Luo, G; Shen, Z; Zhang, YL; Sang, WJ in ELSEVIER published article about in [Dan, Yitong; Ji, Mengyuan; Sang, Wenjing] Donghua Univ, Coll Environm Sci & Engn, Text Pollut Controlling Engn Ctr, Minist Environm Protect, Shanghai 201620, Peoples R China; [Tao, Shuping; Shen, Zheng; Zhang, Yalei] Tongji Univ, Natl Engn Res Ctr Protected Agr, Inst New Rural Dev, Shanghai 200092, Peoples R China; [Luo, Gang] Fudan Univ, Dept Environm Sci & Engn, Shanghai Key Lab Atmospher Particle Pollut & Prev, Shanghai 200433, Peoples R China in 2021.0, Cited 76.0. The Name is 1-Phenylurea. Through research, I have a further understanding and discovery of 64-10-8

The application of phenylurea herbicides (PUHs) may lead to the extensive distribution in soils, while the role of straw biochar as a soil amendment on the transport and sorption of PUHs are still unclear. Thus, the transport and sorption behavior of three typical PUHs with rice straw biochar (RSB) was studied in both adsorption simulation experiments of aqueous solution and packed column experiments:the sorption mechanism of RSB to herbicides was investigated through batch sorption studies with three influencing factors including dosage of RSB, pH, and ionic strength (IS) with orthogonal test. The sorption coeff icients were improved significantly by increasing the dosage of RSB, while there was no obvious influence by enhancing the pH and IS value. The optimal sorption conditions (pH value at 3, IS at 0.1 M, and RSB dosage at 60 mg) of three herbicides were set and the maximum removal rates of Monuron, Diuron, and Linuron were 41.9%, 25%, and 56.8%, respectively. The co-transport process of RSB and PUHs were investigated under different RSB dosage, pH value, and IS value. The retention effect increased greatly with enhancing the RSB dosage and pH value. However, IS did not have a significant influence on the retention of RSB, and therefore it had little effect on the adsorption capacity, which was consistent with the results of sorption experiments. The breakthrough curves (BTCs) for co-transport were well simulated by the two-site non-equilibrium convection-dispersion equation (CDE). Most of the regression coefficients (R-2) were above 0.99, which uncovered the co-transport in packed column were affected by physical absorption and chemical forces. According to the fitting parameters analysis, the RSB particles and PUHs were subjected to a greater resistance and a stronger stability by reducing pH value in porous media. The presence of RSB increased the amount of dynamic sorption sites in the entire co-transport system, which led to a significant promotion of the PUHs’ sorption and interception. (C) 2021 Elsevier B.V. All rights reserved.

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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem