Category: Thiomorpholine

Recently I am researching about FOOD-PACKAGING MATERIALS; PRINTING INKS; RECYCLED PAPERBOARD; CONTACT MATERIALS; PHOTO-INITIATORS; AMINE SYNERGISTS; BOARD; SAFETY; MARKET; MODEL, Saw an article supported by the Operative Plan on Food Safety 2017-2020 of the Basque Government (Basque Country, Spain) [PA19/02]; University of the Basque Country (UPV/EHU) [DOKBERRI 2018-11, DOKBERRI 2018-I]. Published in ELSEVIER SCI LTD in OXFORD ,Authors: Blanco-Zubiaguirre, L; Zabaleta, I; Prieto, A; Olivares, M; Zuloaga, O; Elizalde, MP. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone. Safety of Benzophenone

The migration of photoinitiators, phthalates and plasticizers from two paper and cardboard materials into food simulants (50% and 95% EtOH and Tenax) and foodstuffs (rice, cereals and milk powder) was studied. In the case of liquid simulants migration was observed to reach the equilibrium after 60 min and depended on the material type and the physicochemical parameters of the migrants, whereas the temperature (room temperature and 60 degrees C) did not show significant effects. The study of migration of the compounds from a baking paper to Tenax at high temperatures (150 and 250 degrees C) evidenced an increment of migration when increasing temperature, except for the most volatile analytes. Finally, the migration to foodstuffs was studied using fully validated analytical protocols. Overall, the comparison of the migration rates demonstrated that Tenax was adequate for the simulation of the migration to rice and cereals, but underestimated the migration to infant milk powder, for which 95% EtOH resulted a more suitable simulant.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

COA of Formula: C7H5NO3. In 2021 RUSS J BIOORG CHEM+ published article about MAGNETICALLY SEPARABLE CATALYST; COATED NIFE2O4 NANOPARTICLES; POT MULTICOMPONENT REACTIONS; POTENTIAL ANTITUMOR AGENTS; SOLVENT-FREE SYNTHESIS; EFFICIENT SYNTHESIS; HANTZSCH REACTION; HETEROGENEOUS CATALYST; REUSABLE CATALYST; DERIVATIVES in [Fekri, Leila Zare; Zadeh, Leila Hassan] Payame Noor Univ, Dept Chem, POB 19395-3697, Tehran, Iran in 2021, Cited 38. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6.

Fe3O4@SiO2-Pr@L-proline magnetic nanoparticles were synthesized and their efficiency as nanocatalyst for the synthesis of new derivatives of bis dapsone derived dihydropyridines via one-pot three-component condensation reaction of various aromatic aldehydes, dimedone and dapsone in aqueous media was investigated. The products were characterized by H-1 NMR, C-13 NMR, FT-IR and CHNS analysis. These bis-drugs present high antibacterial activities against both gram-negative (Pseudomonas aeruginosa and Escherichia coli) and gram-positive (Micrococcus luteus and Bacillus subtilis) bacteria, which are in general more sensitive to compounds with halogen or hydroxyl functional groups.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Authors Minkner, R; Xu, J; Takemura, K; Boonyakida, J; Watzig, H; Park, EY in BMC published article about EXPRESSION; SEPARATION; PARTICLES; ADSORBENT in [Minkner, Robert; Takemura, Kenshin; Boonyakida, Jirayu; Park, Enoch Y.] Shizuoka Univ, Grad Sch Sci & Technol, Dept Biosci, 836 Ohya, Shizuoka 4228529, Japan; [Minkner, Robert; Waetzig, Hermann] TU Braunschweig, Inst Med & Pharmaceut Chem, Beethovenstr 55, D-38106 Braunschweig, Germany; [Xu, Jian; Park, Enoch Y.] Shizuoka Univ, Res Inst Green Sci & Technol, Green Chem Res Div, Lab Biotechnol, 836 Ohya, Shizuoka 4228529, Japan; [Xu, Jian] East China Normal Univ, Biomed Synthet Biol Res Ctr, Sch Life Sci, Inst Biol & Informat Sci, Shanghai 200062, Peoples R China in 2020, Cited 36. Safety of 2-Aminobenzamide. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6

Purification of recombinant proteins is often a challenging matter because high purity and high recovery are desired. If the expressed recombinant protein is also in a complex matrix, such as from the silkworm expression system, purification becomes more challenging. Even if purification from the silkworm expression system is troublesome, it benefits from a high capacity for the production of recombinant proteins. In this study, magnetic nanoparticles (MNPs) were investigated as a suitable tool for the purification of proteins from the complex matrix of the silkworm fat body. The MNPs were modified with nickel so that they have an affinity for His-tagged proteins, as the MNP purification protocol itself does not need special equipment except for a magnet. Among the three different kinds of investigated MNPs, MNPs with sizes of 100 nm to 200 nm and approximately 20 nm-thick nickel shells were the most suitable for our purpose. With them, the total protein amount was reduced by up to at least approximately 77.7%, with a protein recovery of around 50.8% from the silkworm fat body. The minimum binding capacity was estimated to be 83.3 mu g protein/mg MNP. Therefore, these MNPs are a promising tool as a purification pretreatment of complex sample matrices.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Meerakrishna, RS; Shanmugam, P in [Meerakrishna, Ramakrishnan Suseela; Shanmugam, Ponnusamy] CLRI, CSIR, Organ & Bioorgan Chem Div, Chennai 600020, Tamil Nadu, India published Synthesis of blue-red emissive amido-substituted di(het)aryl and tri(het)aryl amine derivatives via chemoselective N-mono and N,N-diarylation of (het) aryl amino amides using benzyne/arynes in 2019, Cited 48. Safety of 2-Aminobenzamide. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6.

Herein, via chemoselective N-mono and N,N-diarylation of an aryl/hetaryl amino amide reaction using benzyne or arynes, an amide-substituted triaryl amine derivative and diaryl amine derivatives were afforded. The scope and limitation of the present study have been studied. The products thus obtained were synthetically transformed to highly functionalized biphenyl bridged heterocycles via Suzuki coupling and condensation with 4,4-biphenyl dialdehyde. Evaluation of the photophysical properties has revealed that the triaryl amine derivatives are blue emissive with high quantum yields, whereas the heterocyclic triaryl amine derivatives are blue-red emissive. The benzofuran-derived compound 4i was found to be blue emissive with high quantum yield, whereas the pyridine-derived compound 5j was found to be red emissive with low quantum yield.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

COA of Formula: C7H5NO3. Authors Ma, RN; Xiao, ZY; Zhong, W; Lu, CX; Shen, ZQ; Zhao, D; Liu, XM in WILEY published article about in [Ma, Ruonan; Xiao, Zhiyin; Zhong, Wei; Lu, Chunxin; Shen, Zhongquan; Liu, Xiaoming] Jiaxing Univ, Coll Biol Chem Sci & Engn, Jiaxing 314001, Peoples R China; [Ma, Ruonan; Zhao, Dan; Liu, Xiaoming] Nanchang Univ, Sch Chem, Nanchang 330031, Jiangxi, Peoples R China in 2021.0, Cited 35.0. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6

Cuprous halides, best described as (CuX)(n) (X = Cl-, Br-, and I-) in their solid state, catalyse selective aerobic oxidation of alcohols with the assistance of both NMI (N-methylimidazole) and TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl), and the iodide generally demonstrates the highest activity, for example, in the oxidation of 1-octanol at ambient temperature under 24 h’ reaction. However, in the aerobic oxidation of benzylic alcohols, the chloride showed superiority to the iodide in that the aerobic oxidation was quantitatively completed within 3 h at ambient temperature whereas the iodide showed only about half the activity of the chloride analogue. By probing the system using electrochemistry, electric conductivity, and H-1 NMR titration, it was revealed that the surprising anomaly was due to the difference in the rate of forming active species, [Cu (NMI)(2)X(MeCN)], from the polymeric solid in a two-stage process. Substrates expansion of 11 benzylic alcohols indicated that CuCl/NMI/TEMPO system demonstrated quantitative conversion of benzylic alcohols into corresponding aldehydes within 3 h and showed great tolerance to the substituents on the phenyl ring of the substrates. Furthermore, electron-withdrawing substituent was beneficial to the oxidation and could offset the steric effect at orthro-substituent. Such a behaviour suggested that in the catalysis, increasing the acidity of the hydroxyl group (OH) of the substrates could ease the oxidation, which implied that the deprotonation via an internal pathway might be one of the rate-determining steps. Our results also showed that the anion halide participated actively in the catalysis by coordinating to Cu(I) in the active species.

COA of Formula: C7H5NO3. About 3-Nitrobenzaldehyde, If you have any questions, you can contact Ma, RN; Xiao, ZY; Zhong, W; Lu, CX; Shen, ZQ; Zhao, D; Liu, XM or concate me.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Highly selective electrocatalytic oxidation of benzyl C-H using water as safe and sustainable oxygen source WOS:000583614600028 published article about AEROBIC OXIDATION; ANODIC-OXIDATION; ORGANIC ELECTROSYNTHESIS; N-HYDROXYPHTHALIMIDE; ELECTRON-TRANSFER; PRIMARY ALCOHOLS; REDOX CATALYSTS; P-XYLENE; EFFICIENT; HYDROCARBONS in [Sun, Yuxia; Li, Xiaoshan; Yang, Miao; Ding, Mengning] Nanjing Univ, Sch Chem & Chem Engn, Key Lab Mesoscop Chem, Nanjing 210023, Peoples R China; [Xu, Wentao; Xie, Jin] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Jiangsu Key Lab Adv Organ Mat, Nanjing 210023, Peoples R China in 2020, Cited 78. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8. Recommanded Product: 90-44-8

The selective oxidation of C-H bond is critical for feedstock manufacturing in chemical industry. Current strategies typically involve the use of oxygen or peroxide as the oxidation reagent under high temperature, which sets severe challenges in production sustainability and industrial safety. Herein, we demonstrate an environmental-friendly and safe electrocatalytic strategy for the selective oxidation of benzyl group to ketones at ambient conditions, while using water as the sole oxygen source. Water addition reduces the onset potential of anodic C-H oxidation, and produces 1-tetralone with satisfying conversion and excellent ketone to alcohol ratio. Layered MnO2 catalysts (with rich oxygen vacancies) further adjust the water affinity and facilitate the oxidation, leading to a significantly improved faradaic efficiency.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Formula: C7H5NO3. Mousapour, M; Shirini, F in [Mousapour, Maryam; Shirini, Farhad] Univ Guilan, Dept Chem, Coll Sci, Rasht 4133519141, Iran published Piperazinium Nano Silica Sulfonate: An Efficient Catalyst for the Hantzsch Reaction in 2021.0, Cited 67.0. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6.

Piperazinium nano silica sulfonate (PNSS) is simply prepared by the reaction of piperazine with nano sized silica sulfuric acid. After preparation it was completely characterized using different techniques including FT-IR, XRD, TGA, FESEM, EDS and TEM analysis. In continue PNSS was efficiently used for the promotion of the synthesis of polyhydroquinolines and 1,8-dioxo-decahydroacridines through unsymmetrical and symmetrical Hantzsch condensation reaction. High yields, short reaction times, ease of preparation and reusability of the catalyst, easy work-up procedure and solvent-free conditions are among the most important advantages of this method.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

In 2020 CHEM COMMUN published article about LOW-COST ADSORBENTS; SUPRAMOLECULAR ASSEMBLIES; AQUEOUS-SOLUTION; METHYLENE-BLUE; SINGLET OXYGEN; ORGANIC-DYES; REMOVAL; ADSORPTION; PHOTOLYSIS; KINETICS in [Guan, Xinran; Chen, Yong; Guo, Peng; Li, Pei-Yu; Liu, Yu] Nankai Univ, Coll Chem, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China; [Chen, Yong; Liu, Yu] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China in 2020, Cited 38. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8. Product Details of 90-44-8

Four water-soluble macrocycles were chosen to explore the photodecomposition behaviours of quaternized 9-alkoxy-substituted anthracene (AnQA). Significantly, a highly charged macrocyclic skeleton leads to extremely close packing among the anthryl rings, providing a favourable hydrophobic environment for singlet oxygen, leading to rapid oxidation to produce the photoproducts under sunlight irradiation.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Recently I am researching about ANTIMICROBIAL ACTIVITY; EXPRESSION; COX-2; ANTIBACTERIAL; NANOPARTICLES; INHIBITION; ANTIFUNGAL; INFECTION; DELIVERY, Saw an article supported by the . Published in ELSEVIER in AMSTERDAM ,Authors: Mohamed, NA; Abd El-Ghany, NA; Abdel-Aziz, MM. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone. Quality Control of Benzophenone

Chitosan (Cs) was cross-linked with four various quantities of 4,4′-(5,5′-carbonylbis(1,3-dioxoisoindoline-5,2-diyl) )dibenzoyl isothiocyanate. Elemental analysis, FTIR and H-1 NMR spectroscopy assured that the amino groups of chitosan reacted with the isothiocyanate groups of the cross-linker producing four new hydrogels namely as BBTU-Cs-1, BBTU-Cs-2, BBTU-Cs-3, and BBTU-Cs-4 according to the increment of their cross-linking content, respectively. SEM showed their porous structures and XRD indicated their amorphous nature. Their swell ability increased with decreasing the medium pH value and with increasing cross-linking density. In comparison with the popular COX inhibitor Celecoxib, these hydrogels showed an inhibition activity towards COX enzymes with selective inhibition towards COX-2. Their inhibition activity could be arranged as follows: Celecoxib > BBTU-Cs-4 > BBTU-Cs-3 > BBTU-Cs-2 > BBTU-Cs-1. BBTU-CS-4 hydrogel exhibited a potent inhibition against COX-2 (IC50 0.42 mu g/ml) compared with that observed for the standard Celecoxib (IC50 026 mu g/ml). BBTIJ-Cs-4 is more potent against H. pylori compared to the other hydrogels. BBTU-Cs-4 at a concentration of 7.81 mu g/ml is able to kill 100% of the H. pylori and exhibits a preferential ability to inhibit 8935% of COX-2 than COX-1 (0%). These findings make BBTU-Cs-4 a promising anti-H. pylori and selective anti-inflammatory agent. (C) 2021 Elsevier B.V. All rights reserved.

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Thiomorpholine – Wikipedia,
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Quality Control of 4-Methoxybenzyl acetate. Ghosh, T; Mohammad, A; Mobin, SM in [Ghosh, Topi; Mohammad, Akbar; Mobin, Shaikh M.] Indian Inst Technol Indore, Discipline Chem, Khandwa Rd, Indore 453552, Madhya Pradesh, India; [Mobin, Shaikh M.] Indian Inst Technol Indore, Discipline Met Engn & Mat Sci, Khandwa Rd, Indore 453552, Madhya Pradesh, India; [Mobin, Shaikh M.] Indian Inst Technol Indore, Discipline Biosci & Biomed Engn, Khandwa Rd, Indore 453552, Madhya Pradesh, India published Hybrid Cobalt Doped-Cerium Oxide as a Multifunctional Nanocatalyst for Various Organic Transformations in 2019, Cited 91. The Name is 4-Methoxybenzyl acetate. Through research, I have a further understanding and discovery of 104-21-2.

Development of a low-cost, environmentally benign and robust catalyst for multipurpose industrially relevant organic transformations is highly desirable for the sustainable future of chemical industries. A hybrid cobalt doped-cerium oxide nanocatalyst (Co@CeO2NC) was prepared via simple coprecipitation method using water as the solvent. The characterization of Co@CeO2NC was performed using different techniques such as XRD, TGA, FE-SEM, HR-TEM, EDAX-mapping, BET, and XPS analysis. The structural characterization of the prepared sample by XRD and XPS analysis revealed the presence of the mixed phase of cobalt oxide and cobalt doped-cerium oxide as a hybrid (Co@CeO2NC). Industrially relevant organic transformations such as (i) nitrile formation using aldehyde with hydroxyl amine hydrochloride, (ii) reductive amination of aldehydes to form tertiary N,N-dimethyl amines, and (iii) direct acetylation of alcohols/amines with acetic acid were achieved in an excellent manner using Co@CeO2NC hybrid as the multifunctional catalyst. Excellent catalytic activity of Co@CeO2NC was noticed for the conversion of 4-chlorobenzaldehyde to 4-chlorobenzonitrile with 99% conversion and 99% selectivity and 100% conversion of benzaldehyde to N,N-dimethylbenzylamine using DMF as NMe2 source, reductant, and solvent. Moreover, acetylation of 4-methoxybenzyl alcohol and 2-methyl aniline gave excellent conversion and selectivity toward the formation of -O and -N acetyl. The scope of the Co@CeO2NC was further evaluated for other aldehydes, alcohols, and amines with an excellent conversion and high selectivity.

Quality Control of 4-Methoxybenzyl acetate. Welcome to talk about 104-21-2, If you have any questions, you can contact Ghosh, T; Mohammad, A; Mobin, SM or send Email.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem