Category: 99-61-6

Category: thiomorpholine. Authors Ma, RN; Xiao, ZY; Zhong, W; Lu, CX; Shen, ZQ; Zhao, D; Liu, XM in WILEY published article about in [Ma, Ruonan; Xiao, Zhiyin; Zhong, Wei; Lu, Chunxin; Shen, Zhongquan; Liu, Xiaoming] Jiaxing Univ, Coll Biol Chem Sci & Engn, Jiaxing 314001, Peoples R China; [Ma, Ruonan; Zhao, Dan; Liu, Xiaoming] Nanchang Univ, Sch Chem, Nanchang 330031, Jiangxi, Peoples R China in 2021.0, Cited 35.0. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6

Cuprous halides, best described as (CuX)(n) (X = Cl-, Br-, and I-) in their solid state, catalyse selective aerobic oxidation of alcohols with the assistance of both NMI (N-methylimidazole) and TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl), and the iodide generally demonstrates the highest activity, for example, in the oxidation of 1-octanol at ambient temperature under 24 h’ reaction. However, in the aerobic oxidation of benzylic alcohols, the chloride showed superiority to the iodide in that the aerobic oxidation was quantitatively completed within 3 h at ambient temperature whereas the iodide showed only about half the activity of the chloride analogue. By probing the system using electrochemistry, electric conductivity, and H-1 NMR titration, it was revealed that the surprising anomaly was due to the difference in the rate of forming active species, [Cu (NMI)(2)X(MeCN)], from the polymeric solid in a two-stage process. Substrates expansion of 11 benzylic alcohols indicated that CuCl/NMI/TEMPO system demonstrated quantitative conversion of benzylic alcohols into corresponding aldehydes within 3 h and showed great tolerance to the substituents on the phenyl ring of the substrates. Furthermore, electron-withdrawing substituent was beneficial to the oxidation and could offset the steric effect at orthro-substituent. Such a behaviour suggested that in the catalysis, increasing the acidity of the hydroxyl group (OH) of the substrates could ease the oxidation, which implied that the deprotonation via an internal pathway might be one of the rate-determining steps. Our results also showed that the anion halide participated actively in the catalysis by coordinating to Cu(I) in the active species.

Category: thiomorpholine. About 3-Nitrobenzaldehyde, If you have any questions, you can contact Ma, RN; Xiao, ZY; Zhong, W; Lu, CX; Shen, ZQ; Zhao, D; Liu, XM or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article A novel anionic di-oxido vanadium(V) Schiff base complex: Synthesis, spectral characterization, X ray crystal structure, catalytic activity for the preparation of tetrahydro-4H-chromene derivatives and antibacterial properties WOS:000647729000005 published article about IN-VITRO; BINDING; DNA in [Khosravan, Mehrji; Abdolahi, Leila; Ebrahimipour, S. Yousef] Shahid Bahonar Univ Kerman, Fac Sci, Dept Chem, Kerman 7616914111, Iran; [Abdolahi, Leila] Shahid Bahonar Univ Kerman, Young Researchers Soc, POB 76175-133, Kerman, Iran in 2021.0, Cited 33.0. COA of Formula: C7H5NO3. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6

In this work, a tridentate ONO Schiff base ligand,1-[(((2-hydroxyphenyl)imino)methyl)]naphthalen-2-ol [H2L] and its di-oxido vanadium(V) complex [(VO2(L)](NHET3) have been synthesized and fully characterized using elemental analysis, molar conductivity and FT-IR, UV-Vis, and 1HNMR spectroscopies. Single crystal X-ray diffraction was also used to accomplish the crystal structure of di-oxido vanadium(V) complex. The catalytic activity of the complex was also evaluated for the synthesis of tetrahydro-4H-chromene derivatives. The synthesized [VO2(L)](NHET3) complex showed superior catalytic characteristics in comparison to the previously reported catalysts. Furthermore,the antimicrobial properties of the complex against both gram-positive and gram-negative pathogens were evaluated, that an enhanced antibacterial activity was obtained with MIC values in the range of 100-200 mu g/ml.

About 3-Nitrobenzaldehyde, If you have any questions, you can contact Khosravan, M; Abdolahi, L; Ebrahimipour, SY or concate me.. COA of Formula: C7H5NO3

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

In 2021 APPL ORGANOMET CHEM published article about HYDROXYAPATITE-CORE-SHELL-GAMMA-FE2O3 NANOPARTICLES; 5-SUBSTITUTED 1H-TETRAZOLES; MAGNETIC NANOPARTICLES; HETEROGENEOUS CATALYST; RECYCLABLE CATALYST; HIGHLY EFFICIENT; FACILE SYNTHESIS; DERIVATIVES in [Sorkhabi, Serve; Mozafari, Roya; Ghadermazi, Mohammad] Univ Kurdistan, Fac Sci, Dept Chem, Sanandaj, Iran in 2021, Cited 77. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6. SDS of cas: 99-61-6

In the current research, much attention is paid to heterogenized nanostructure. Herein, we report the green synthesis magnetic nanoparticles (MNPs) of cobalt ferrite by the immobilization of erbium (Er) coated with folic acid (FA) which show effective catalytic properties and recyclability. Full characterizations with field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), X-ray atomic mapping, thermal gravimetric analysis (TGA), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), inductively coupled plasma-optical emission spectrometry (ICP-OES), and Fourier-transform infrared (FT-IR) spectroscopy techniques were undertaken to uncover structural properties of the prepared magnetic catalyst. The obtained nanohybrid complexes as efficient, recyclable, and green heterogeneous systems pave the way for producing pyrano[2,3-d]pyrimidinone and dihydropyrano[3,2-c]chromenes derivatives by the one-pot three-component condensation reaction of various aldehydes, malononitrile, and hydroxycoumarin or barbituric acid in green condition. This easily prepared organometalic catalyst presents many superiorities such as operational simplicity, high yield, short reaction time, utilization of commercially available or easily accessible starting materials, eco-friendly properties, and excellent purity. Most importantly, erbium-FA-coated CoFe2O4 can be easily separated and recycled from the reaction system using an external magnetic field. The magnetically recoverable biocatalyst can be recycled and reused six times while maintaining high activities. The activity of the magnetic catalyst can be maintained at more than 80% of that of the previous cycle. This research solves the recovery problem encountered in industrial applications of biocatalysts and presents a clean and green method for preparing pyrimidinones and chromenes.

SDS of cas: 99-61-6. About 3-Nitrobenzaldehyde, If you have any questions, you can contact Sorkhabi, S; Mozafari, R; Ghadermazi, M or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Efficient and Facile Synthesis of Chromenopyrano[2,3-b]pyridine Derivatives Catalyzed by Sodium Carbonate WOS:000662885300008 published article about REGIOSELECTIVE SYNTHESIS; BIOLOGICAL EVALUATION; COUMARIN; PYRIDINE; HETEROCYCLES; PROTOCOL; PYRAZOLE; DOCKING; DESIGN in [Keshavarz, Raziyeh; Farahi, Mahnaz; Karami, Bahador] Univ Yasuj, Dept Chem, POB 353, Yasuj 7591874831, Iran in 2021.0, Cited 42.0. Application In Synthesis of 3-Nitrobenzaldehyde. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6

In this research, a number of new and known chromenopyrano [2,3-b]pyridine derivatives have been prepared. Initially, according to the reported procedure, pyrano [2,3-c] chromene derivatives were synthesized by the reaction between 4-hydroxycoumarin, aromatic aldehydes and malononitrile using silica sodium carbonate (SSC) as the catalyst. Next, the prepared pyrano [2,3-c] chromenes were reacted by dimethyl acetylenedicarboxylate (DMAD) or cyclohexanone in the presence of sodium carbonate to produce chromenopyrano [2,3-b]pyridine derivatives. The presented protocol avoids the use of expensive catalysts and gives useful potentially bioactive heterocycles in excellent to high yields.

Application In Synthesis of 3-Nitrobenzaldehyde. About 3-Nitrobenzaldehyde, If you have any questions, you can contact Keshavarz, R; Farahi, M; Karami, B or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Product Details of 99-61-6. In 2021.0 DRUG DEVELOP RES published article about BIOLOGICAL EVALUATION; ANTIOXIDANT in [Iraji, Aida; Edraki, Najmeh; Khoshneviszadeh, Mahsima; Khoshneviszadeh, Mehdi] Shiraz Univ Med Sci, Med & Nat Prod Chem Res Ctr, Shiraz, Iran; [Panahi, Zahra; Khoshneviszadeh, Mehdi] Shiraz Univ Med Sci, Fac Pharm, Dept Med Chem, Shiraz, Iran in 2021.0, Cited 30.0. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6.

Due to the fact that tyrosinase is responsible for biosynthesis and regulation of melanins and browning food products, tyrosinase inhibitors can be favorable agents in cosmetics and medicinal industries. A series of novel 2-hydroxy-4-methoxybenzohydrazide were designed, synthesized, and their new application as tyrosinase inhibitors was also disclosed. Based on in vitro tyrosinase inhibitory assay, 4d as the strongest inhibitor of tyrosinase with an IC50 value of 7.57 mu M showed approximately 2.5-fold better inhibition than kojic acid as positive control followed by two compounds 4b (IC50 = 8.19 +/- 0.25 mu M) and 4j (IC50 = 8.92 +/- 0.016) which displayed preferable tyrosinase inhibitory activity. Detailed investigations on the mechanism of action of the 4d reported mix type of inhibition. More importantly, molecular modeling assessments proposed the ability of 4d for potential interaction with Cu (metal)-His (residue) within tyrosinase active site. Overall, 4d is a promising candidate for the development of anti-tyrosinase agents.

Product Details of 99-61-6. About 3-Nitrobenzaldehyde, If you have any questions, you can contact Iraji, A; Panahi, Z; Edraki, N; Khoshneviszadeh, M; Khoshneviszadeh, M or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

In 2021.0 SYNTHETIC COMMUN published article about ONE-POT SYNTHESIS; VISIBLE-LIGHT PHOTOCATALYSIS; PHOTOREDOX CATALYSIS; EFFICIENT SYNTHESIS; ANTIMICROBIAL EVALUATION; MULTICOMPONENT SYNTHESIS; TREATED SOLUTIONS; RAPID SYNTHESIS; DERIVATIVES; ACID in [Dutta, Arup; Rahman, Noimur; Nongkhlaw, Rishanlang] North Eastern Hill Univ, Dept Chem, Shillong, Meghalaya, India; [Kumar, John Elisa] North Eastern Hill Univ, Photocatalysis Lab, Shillong, Meghalaya, India; [Rabha, Jintu; Phukan, Tridip] Gauhati Univ, Dept Bot, Gauhati, Assam, India in 2021.0, Cited 59.0. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6. Product Details of 99-61-6

A convenient and eco-friendly, one-pot synthetic protocol for pharmaceutically important pyran-based heterocyclic compounds is repeated herein. The reactions were carried out at room temperature in a water-ethanol solvent mixture under direct irradiation of UV365 light source in the absence of photocatalyst. The merits of the present protocol include mild and catalyst-free reactions, green procedures, and high yields. The added advantage of this protocol is that it can be applied for large-scale synthesis of various pyran-based heterocyclic compounds without employing any expensive catalyst. Also, in vitro antibacterial screening of pyran derivative was investigated against both Gram-positive Bacillus cereus (B. cereus) and Gram-negative bacteria Escherichia coli (E. coli).

About 3-Nitrobenzaldehyde, If you have any questions, you can contact Dutta, A; Rahman, N; Kumar, JE; Rabha, J; Phukan, T; Nongkhlaw, R or concate me.. Product Details of 99-61-6

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Recommanded Product: 3-Nitrobenzaldehyde. Recently I am researching about BROMINATION; ACETALS, Saw an article supported by the Natural Science Foundation and Education Department of Anhui Province [1808085MB28, gxyq2018081, KJHS2019B11]. Published in BENTHAM SCIENCE PUBL LTD in SHARJAH ,Authors: Zheng, ZB; Han, BB; Hu, JJ; Li, XW. The CAS is 99-61-6. Through research, I have a further understanding and discovery of 3-Nitrobenzaldehyde

The applications of a new supported tribromide reagent (poly(vinylbenzyltrimethylammonium tribromide) resin) were reported. This supported tribromide resin was used as a catalyst in the acetalization and diacetylation of benzaldehydes under mild conditions with high efficiency. The effects of solvents, and amount of the supported tribromide resin on the reactions were investigated. Under the optimal conditions, most of acetal and 1,1-diacetates of benzaldehydes were selectively obtained in excellent yields.

Recommanded Product: 3-Nitrobenzaldehyde. About 3-Nitrobenzaldehyde, If you have any questions, you can contact Zheng, ZB; Han, BB; Hu, JJ; Li, XW or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article High-efficient synthesis of 2-imino-2H-chromenes and dihydropyrano[c]chromenes using novel and green catalyst (CaO@SiO2@AIL) WOS:000578875700001 published article about ONE-POT SYNTHESIS; 3-COMPONENT SYNTHESIS; CHROMENE DERIVATIVES; MULTICOMPONENT; MALONONITRILE; NANOPARTICLES; BISCOUMARIN; RECOVERY; WASTE in [Sameri, Fatemeh; Mobinikhaledi, Akbar; Bodaghifard, Mohammad Ali] Arak Univ, Fac Sci, Dept Chem, Arak 3815688138, Iran; [Sameri, Fatemeh; Mobinikhaledi, Akbar; Bodaghifard, Mohammad Ali] Arak Univ, Inst Nanosci & Nanotechnol, Arak 3815688138, Iran in 2021, Cited 54. Formula: C7H5NO3. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6

In this work, 1,3,5,7-tetraazaadamantan-1-ium chloride (AIL) functionalized silica-coated calcium oxide hybrid nanocatalyst (CaO@SiO2@AIL) as a novel, efficient, green and recyclable heterogeneous ionic liquid catalyst was synthesized. Catalytic activity of the CaO@SiO2@AIL hybrid nanoparticles was investigated for synthesis of the pharmaceutically valuable 2-imino-2H-chromene and dihydropyrano[c]chromene derivatives. A wide range of amines and aromatic aldehydes containing either electron-withdrawing or electron-donating substituent were examined using optimized conditions to produce the desired products. 2-Imino-2H-chromenes were synthesized under solvent-free condition, and dihydropyrano[c]chromenes were prepared in aqueous medium as green conditions within short reaction times, high yields and using easy workup procedures. Structure confirmation and surface properties of the core/shell hybrid nanoparticles were considered via Fourier transform infrared spectroscopy, X-ray powder diffraction, scanning electron microscope, energy-dispersive X-ray spectroscopy, WDS map scan, thermogravimetric and elemental analyses. This IL-supported heterogeneous nanocatalyst can be reused at least six times without considerable loss of its performance.

Formula: C7H5NO3. About 3-Nitrobenzaldehyde, If you have any questions, you can contact Sameri, F; Mobinikhaledi, A; Bodaghifard, MA or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Formula: C7H5NO3. Authors Al-Adhami, HJ; Al-Majidi, SMH in MAIK NAUKA/INTERPERIODICA/SPRINGER published article about in [Al-Adhami, H. J.; Al-Majidi, S. M. H.] Univ Baghdad, Coll Sci, Dept Chem, Baghdad 10071, Iraq in 2021.0, Cited 26.0. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6

The condensation of 6-amino-1,3-dimethyluracil with substituted benzaldehydes gave six Schiff base derivatives which were brought into cyclizations with sodium azide, anthranilic acid, and 2-sulfanylbenzoic acid to afford new dihydrotetrazoles, dihydroquinazolin-4-ones, and 1,3-benzothiazine-4-ones containing a 1,3-di-methyluracil fragment. The structure of the newly synthesized compounds was confirmed by FTIR and NMR spectroscopy, and their in vitro antioxidant and antimicrobial activities against some bacterial and fungal strains were evaluated.

Formula: C7H5NO3. About 3-Nitrobenzaldehyde, If you have any questions, you can contact Al-Adhami, HJ; Al-Majidi, SMH or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Formula: C7H5NO3. Recently I am researching about NONCOVALENT INTERACTIONS; HYDROGEN-BONDS; AZO; CYANOSILYLATION; COORDINATION; DESIGN, Saw an article supported by the Science Development Foundation under the President of the Republic of AzerbaijanScience Development Foundation (SDF) – Azerbaijan [EIF/MQM/Elm-Tehsil-1-2006-1(26)-71/06/4]. Published in ARKAT USA INC in GAINESVILLE ,Authors: Shikhaliyev, NG; Maharramov, AM; Suleymanova, GT; Babayeva, GV; Mammadova, GZ; Shikhaliyeva, IM; Babazade, AA; Nenajdenko, VG. The CAS is 99-61-6. Through research, I have a further understanding and discovery of 3-Nitrobenzaldehyde

A set of 4,4-dichloro-1,2-diazabutadienes derived from 3-nitrobenzaldehyde was prepared by the copper catalyzed reaction of the corresponding hydrazones with CCl4 in the presence of TMEDA. The structure of all products was confirmed by H-1 and C-13 NMR spectra and ESI-MS. X-ray diffraction revealed Cl center dot center dot center dot O halogen binding in the crystal form for some dienes. Moreover, Br center dot center dot center dot pi and Cl center dot center dot pi types of halogen bonds are observed. Azo dyes absorb in the UV-Vis region with the lambda(max) located at about 234-437 nm in CH2Cl2, DMF and MeOH. Both absorption intensity and lambda(max) is dependent on the solvent polarity and the electron-withdrawing/donating ability of para-substituents on the aromatic moiety of the dichlorodiazadienes. [GRAPHICS]

About 3-Nitrobenzaldehyde, If you have any questions, you can contact Shikhaliyev, NG; Maharramov, AM; Suleymanova, GT; Babayeva, GV; Mammadova, GZ; Shikhaliyeva, IM; Babazade, AA; Nenajdenko, VG or concate me.. Formula: C7H5NO3

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem