Category: 119-61-9

Computed Properties of C13H10O. I found the field of Chemistry very interesting. Saw the article A decatungstate-based ionic liquid exhibiting a very low dielectric constant suitable for acting as a solvent and a catalyst for the oxidation of organic substrates published in 2021.0, Reprint Addresses Pegot, B; Floquet, S (corresponding author), Univ Paris Saclay, Univ Versailles St Quentin Yvelines, CNRS, Inst Lavoisier Versailles,UMR 8180, F-78035 Versailles, France.. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone.

In this contribution, a new POM-based ionic liquid, namely (P-6,P-6,P-6,P-14)(4)[W10O32], was fully characterized. Its viscosity and its very low dielectric constant make this hybrid ionic liquid suitable to be used as a solvent for organic transformations. As a proof of concept, this unique ionic liquid having both solvent and catalyst properties was tested for the catalytic oxidation of various alcohols and alkenes in the presence of H2O2.

Computed Properties of C13H10O. About Benzophenone, If you have any questions, you can contact Martinetto, Y; Pegot, B; Roch-Marchal, C; Haouas, M; Cottyn-Boitte, B; Camerel, F; Jeftic, J; Morineau, D; Magnier, E; Floquet, S or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Authors Xie, P; Xue, C; Wang, CC; Du, DD; Shi, SS in ROYAL SOC CHEMISTRY published article about VISIBLE-LIGHT PHOTOCATALYSIS; ALPHA-OXOCARBOXYLIC ACIDS; METAL-FREE CATALYST; C-H ACTIVATION; CARBOXYLIC-ACIDS; OXIDATIVE CLEAVAGE; TRANSITION-METAL; PHOTOREDOX CATALYSIS; SELECTIVE OXIDATION; BRANCHED ALDEHYDES in [Xie, Pan; Xue, Cheng; Wang, Cancan; Du, Dongdong; Shi, SanShan] Shaanxi Univ Sci Technol, Coll Chem & Chem Engn, Shaanxi Key Lab Chem Addit Ind, Xian 710021, Peoples R China in 2021.0, Cited 86.0. Application In Synthesis of Benzophenone. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

A CF3SO2Na/Pd(OAc)(2) co-catalysis strategy was developed to produce aryl ketones via visible-light-induced decarboxylative cross-coupling of alpha-oxocarboxylic acids and aryl boronic acids. This process was performed under air at room temperature, furnishing aromatic ketones in moderate to good yields. Various sensitive functional groups were well tolerated in this reaction. A synergistic catalytic mechanism involving O-2 was also proposed based on the experimental observations.

Application In Synthesis of Benzophenone. About Benzophenone, If you have any questions, you can contact Xie, P; Xue, C; Wang, CC; Du, DD; Shi, SS or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Recommanded Product: 119-61-9. Authors Balakrishnan, V; Murugesan, V; Chindan, B; Rasappan, R in AMER CHEMICAL SOC published article about in [Balakrishnan, Venkadesh; Murugesan, Vetrivelan; Chindan, Bincy; Rasappan, Ramesh] Indian Inst Sci Educ & Res Thiruvananthapuram, Sch Chem, Thiruvananthapuram 695551, Kerala, India in 2021.0, Cited 59.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

Benzylic stereocenters are found in bioactive and drug molecules, as enantiopure benzylic alcohols have been used to build such a stereogenic center, but are limited to the construction of a C-C bond. Silylation of alkyl alcohols has the potential to build bioactive molecules and building blocks; however, the development of such a process is challenging and unknown. Herein, we describe an unprecedented AgF-assisted nickel catalysis in the enantiospecific silylation of benzylic ethers.

Recommanded Product: 119-61-9. About Benzophenone, If you have any questions, you can contact Balakrishnan, V; Murugesan, V; Chindan, B; Rasappan, R or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Copper(II)-Ethanolamine Triazine Complex on Chitosan-Functionalized Nanomaghemite for Catalytic Aerobic Oxidation of Benzylic Alcohols WOS:000545059000001 published article about SELECTIVE OXIDATION; ALDEHYDES; EFFICIENT; NANOPARTICLES; LIGAND; NANOCATALYST; KETONES; SYSTEM; GREEN in [Hasanpour, Benyamin; Jafarpour, Maasoumeh; Feizpour, Fahimeh; Rezaeifard, Abdolreza] Univ Birjand, Fac Sci, Dept Chem, Catalysis Res Lab, Birjand 97179414, Iran in 2021.0, Cited 52.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9. Formula: C13H10O

In this study a novel, effective and recoverable Cu(II)-catalyst was synthesized by incorporating of Cu(OAc)(2) within ethanolamine-triazine derivative (TAETA) attached to chitosan (Chs)-functionalized gamma-Fe2O3 nanoparticles [MNP@Chs/TAETACu(II)]. It was characterized by different techniques such as FT-IR, EDS, ICP, TEM, TGA and VSM. The as-prepared nanocomposite demonstrated high oxidation activity and desired selectivity in the aerobic oxidation of structurally diverse set of benzyl alcohols. Spectral results and leaching experiments revealed that this magnetically recoverable heterogeneous catalyst preserved its structure after it was reused several times. This protocol offers some beneficial features such as the use of oxygen as an ideal oxidant, stability of nanocomplex, easily catalyst separation by using an external magnetic field and efficient recycling as well as the lack of by-products. [GRAPHICS] .

About Benzophenone, If you have any questions, you can contact Hasanpour, B; Jafarpour, M; Feizpour, F; Rezaeifard, A or concate me.. Formula: C13H10O

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article In situ photografting during direct laser writing in thermoplastic microchannels WOS:000659147000014 published article about 2-PHOTON POLYMERIZATION; GRAFT-POLYMERIZATION; SURFACE; CHIP in [Han, Jung Y.; Warshawsky, Sarah; DeVoe, Don L.] Univ Maryland, Dept Mech Engn, College Pk, MD 20742 USA; [Han, Jung Y.; DeVoe, Don L.] Univ Maryland, Robert E Fischell Inst Biomed Devices, College Pk, MD 20742 USA in 2021.0, Cited 29.0. Recommanded Product: Benzophenone. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

A method for in situ photografting during direct laser writing by two-photon polymerization is presented. The technique serves as a powerful approach to the formation of covalent bonds between 3D photoresist structures and thermoplastic surfaces. By leveraging the same laser for both pattern generation and localized surface reactions, crosslinking between the bulk photoresist and thermoplastic surface is achieved during polymerization. When applied to in-channel direct laser writing for microfluidic device fabrication, the process yields exceptionally strong adhesion and robust bond interfaces that can withstand pressure gradients as high as 7 MPa through proper channel design, photoinitiator selection, and processing conditions.

Recommanded Product: Benzophenone. About Benzophenone, If you have any questions, you can contact Han, JY; Warshawsky, S; DeVoe, DL or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

In 2021.0 INORG CHEM published article about LITHIUM-MEDIATED ALUMINATION; CATALYTIC NITRENE TRANSFER; STRUCTURAL-CHARACTERIZATION; LACTIDE POLYMERIZATION; COORDINATION CHEMISTRY; CRYSTAL-STRUCTURES; AMIDE COMPLEXES; MAGNESIUM; LIGAND; METAL in [Gauld, Richard M.; Lynch, Jennifer R.; Kennedy, Alan R.; Mulvey, Robert E.] Univ Strathclyde, Dept Pure & Appl Chem, WestCHEM, Glasgow G1 1XL, Lanark, Scotland; [Barker, Jim; Reid, Jacqueline] Innospec Ltd, Ellesmere Port CH6S 4EY, Cheshire, England in 2021.0, Cited 67.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9. HPLC of Formula: C13H10O

Homoleptic LiNacNac forms simple donor-acceptor complexes with N,N’-dicyclohexylcarbodiimide (CyN=C=NCy), triphenylphosphine oxide (Ph3P=O), and benzophenone (Ph2CO). These crystallographically characterized compounds could be regarded as model intermediates en route to reducing the N=C, P=O, and C=O bonds of unsaturated substrates. Heteroleptic NacNacMg(TMP) intriguingly functions as a TMP nucleophile both with t-BuNCO and t-BuNCS, producing a urea or thiourea derivative respectively attached to Mg, though the NacNac ligand in the former reaction also engages noninnocently with a second t-BuNCO molecule via insertion at the reactive NacNac backbone gamma-carbon site.

About Benzophenone, If you have any questions, you can contact Gauld, RM; Lynch, JR; Kennedy, AR; Barker, J; Reid, J; Mulvey, RE or concate me.. HPLC of Formula: C13H10O

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Name: Benzophenone. Authors Yang, SS; Wang, XJ; Hu, ZQ; Guo, DC in ELSEVIER published article about in [Yang, Shuaishuai; Hu, Zhongqian; Guo, Dongcai] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemobiosensing & Chemometr, Changsha 410082, Peoples R China; [Wang, Xingjing] Cardiff Univ, Cardiff Sch Chem, Cardiff CF10 3AT, Wales in 2021.0, Cited 47.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

The organic ligands with good coordination ability to Eu(III) ion attracted great attention, but the preparation of multifunctional organic ligands with excellent performance and the potential application was still a challenge in the field of rare earth coordination. In this work, a series of Schiff-base ligands and their corresponding Eu(III) complexes were successfully prepared. The ligands L1-4 exhibited typical AIE properties with various fluorescence emissions and high fluorescence quantum yields in an aggregated state. The luminescence intensity and luminescence lifetime of Eu(III) complexes were investigated by comparing different substituents of ligands. Density functional theory (DFT) calculations suggested that the electronegativity of the ligands L1-4 changed with the change of the substituents on the salicylaldehyde, which led to the phenomenon that the ligands exhibited diverse fluorescence emission from green to orange (maximum emission wavelengths were 525 nm, 546 nm 569 nm and 582 nm, respectively). All target Eu(III) complexes exhibited red luminescence of Eu(III) ions, accompanied by outstanding thermal stability and long luminescence lifetime. The effect of various substituent groups on luminescence intensity and luminescence lifetime of complexes was ordered: EuL3(Phen) (NO3)(3) > EuL2(Phen)(NO3)(3) > EuL1(Phen)(NO3)(3) > EuL4(Phen)(NO3)(3). Based on the above results, all ligands and corresponding target Eu(III) complexes had good application prospects in the field of optical materials.

About Benzophenone, If you have any questions, you can contact Yang, SS; Wang, XJ; Hu, ZQ; Guo, DC or concate me.. Name: Benzophenone

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

I found the field of Chemistry; Engineering; Polymer Science very interesting. Saw the article Preparation and photochemical properties of PEG based alpha-hydroxyalkylphenone photoinitiator published in 2021.0. Application In Synthesis of Benzophenone, Reprint Addresses Wang, JX (corresponding author), Hebei Univ Technol, Sch Chem Engn & Technol, 8 Guang Rong Dao, Tianjin 300130, Peoples R China.. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone

A novel emulsified photoinitiator (named as OP10-IPDI-2959) was prepared by the reaction of isophorone diisocyanate (IPDI) with 2-hydroxy-4?-(2-hydroxyethoxy)-2-methylpropiophenone (Ir-2959) and nonylphenol polyoxyethylene ether (OP-10). The structure of OP10-IPDI-2959 was characterized by FT-IR, 1H NMR, UV?vis and high-resolution mass spectrometry. The photochemical behavior of OP10-IPDI-2959 was investigated through the photolysis and polymerization of neopentyl glycol diacrylate (NPGDA), mixture of epoxy acrylate resin and 1,6-hexanediol diacrylate (HDDA). Under irradiation of UV light, the OP10-IPDI-2959 has similar photochemical properties with the Ir-2959. Combined with benzophenone, the photoinitiated rate of OP10-IPDI-2959 is higher than that of Ir-2959. The polyoxyethylene fragment of OP10-IPDI-2959 is not only an alternative to toxic amine as hydrogen donor, but also a hydrophilic unit for interface between oil and water. The OP10-IPDI-2959 can effectively emulsify the epoxy acrylate resin and 1,6-hexanediol diacrylate mixture to form low viscosity emulsion. Compared with Ir-2959, OP10-IPDI-2959 has good photoinitiation activity, lower migration and good water emulsification performance.

About Benzophenone, If you have any questions, you can contact Huo, S; Zhou, HY; Wang, JX or concate me.. Application In Synthesis of Benzophenone

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Recommanded Product: Benzophenone. Maslov, DK; Bukatov, GD in [Maslov, D. K.; Bukatov, G. D.] Boreskov Inst Catalysis SB RAS, Novosibirsk, Russia published Titanium-magnesium catalysts for propylene polymerization: Study of interrelations between composition, structure and activity in 2021.0, Cited 21.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9.

Propylene polymerization titanium-magnesium catalysts (TMCs) were synthesized from different magnesium compounds with diphenylketone (DPK) as the internal donor. The catalysts differed by an order of magnitude and more in the content of titanium and donor, activity, specific surface area and pore size. Sizes of MgCl2 crystallites with 110 or 104 lateral cuts were calculated from the Ti/Mg and DPK/Mg values. For highly active TMCs the composition, XRD and specific surface area were in agreement with the MgCl2 crystallites with 104 lateral cuts, TiCl4 adsorption on one magnesium ion and elongated in the 001 direction. For low-activity TMCs obtained by reacting Mg with BuCl, the sizes of MgCl2 crystallites in different directions were close. Activity of the catalysts was inversely proportional to the crystallite size calculated from the TMC composition. This dependence was preserved for the catalysts obtained via the substitution of ketone by phthalate.

Recommanded Product: Benzophenone. About Benzophenone, If you have any questions, you can contact Maslov, DK; Bukatov, GD or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Recommanded Product: Benzophenone. Blanco-Zubiaguirre, L; Zabaleta, I; Prieto, A; Olivares, M; Zuloaga, O; Elizalde, MP in [Blanco-Zubiaguirre, L.; Zabaleta, I; Prieto, A.; Olivares, M.; Zuloaga, O.; Elizalde, M. P.] Univ Basque Country, UPV EHU, Fac Sci & Technol, Dept Analyt Chem, POB 644, Bilbao 48080, Spain; [Prieto, A.; Olivares, M.; Zuloaga, O.] Univ Basque Country, UPV EHU, Res Ctr Expt Marine Biol & Biotechnol PIE, E-48620 Areatza Zg, Plentzia, Spain published Migration of photoinitiators, phthalates and plasticizers from paper and cardboard materials into different simulants and foodstuffs in 2021.0, Cited 27.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9.

The migration of photoinitiators, phthalates and plasticizers from two paper and cardboard materials into food simulants (50% and 95% EtOH and Tenax) and foodstuffs (rice, cereals and milk powder) was studied. In the case of liquid simulants migration was observed to reach the equilibrium after 60 min and depended on the material type and the physicochemical parameters of the migrants, whereas the temperature (room temperature and 60 degrees C) did not show significant effects. The study of migration of the compounds from a baking paper to Tenax at high temperatures (150 and 250 degrees C) evidenced an increment of migration when increasing temperature, except for the most volatile analytes. Finally, the migration to foodstuffs was studied using fully validated analytical protocols. Overall, the comparison of the migration rates demonstrated that Tenax was adequate for the simulation of the migration to rice and cereals, but underestimated the migration to infant milk powder, for which 95% EtOH resulted a more suitable simulant.

About Benzophenone, If you have any questions, you can contact Blanco-Zubiaguirre, L; Zabaleta, I; Prieto, A; Olivares, M; Zuloaga, O; Elizalde, MP or concate me.. Recommanded Product: Benzophenone

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem