Category: 119-61-9

Authors Wang, YH; Zhao, JW; Xu, F; Zhang, QD; Ai, ZL; Li, BY in WILEY published article about in [Wang, Yuan-Hui; Ai, Zhi-Lu] Henan Agr Univ, Minist Agr & Rural Affairs Peoples Republ China, Key Lab Staple Grain Proc, Zhengzhou, Peoples R China; [Wang, Yuan-Hui; Zhao, Jing-Wen; Xu, Fei; Li, Bo-Yu] Henan Univ Technol, Coll Food Sci & Technol, Zhengzhou, Peoples R China; [Zhang, Qi-Dong] Zhengzhou Tobacco Res Inst CNTC, Zhengzhou, Peoples R China in 2021.0, Cited 31.0. Application In Synthesis of Benzophenone. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

The volatile compounds of Jiaozi-steamed breads (JSBs) fermented by Jiaozi starters from eight regions in China were extracted using simultaneous distillation and extraction (SDE) and headspace solid-phase microextraction and determined using gas chromatography-mass spectrometry (GC-MS). 1-Hexanol, 3-methyl-1-butanol, phenylethyl alcohol, benzaldehyde, naphthalene, ethanol, acetic acid, and n-hexadecanoic acid were the main volatiles of JSBs. Principal component analysis exhibited that the volatiles of JSBs from Nanyang City, Xi’an City, and Zhumadian City was negatively correlated to that of other five JSB samples. Cluster analysis demonstrated that the volatile characteristics of JSBs from Heze City, Minqin County, Taian City, Weinan City, and Yuncheng City belonged to a category, and the JSBs of Nanyang City, Xi’an City, and Zhumadian City were different from other five JSBs. It demonstrated that the volatile components of steamed breads in North China and South China were different. Practical applications From this study, it can be seen that simultaneous distillation and extraction (SDE) can completely extract volatile compositions of steamed breads fermented by Chinese traditional starter Jiaozi. SDE/GC-MS was suitable for the analysis of JSBs volatile composition. The relative contents of 1-hexanol, 3-methyl-1-butanol, phenylethyl alcohol, benzaldehyde, naphthalene, ethanol, acetic acid, and n-hexadecanoic acid in JSBs were at high level, and their contents could be used as a marker to identify JSBs. The volatile compositions of JSBs made of Jiaozi starters from Heze City, Minqin County, Taian City, Weinan City, and Yuncheng City were similar. However, JSBs of Nanyang City, Xi’an City, and Zhumadian City were different from other five JSBs. The volatile components of steamed breads in North China and South China were different, which reflected the difference in dietary habit in the southern and northern areas of China.

Application In Synthesis of Benzophenone. About Benzophenone, If you have any questions, you can contact Wang, YH; Zhao, JW; Xu, F; Zhang, QD; Ai, ZL; Li, BY or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Recommanded Product: 119-61-9. Zhang, XY; Wei, DB; Sun, XF; Bai, CZ; Du, YG in [Zhang, Xinyi; Wei, Dongbin; Sun, Xuefeng; Bai, Chenzhong; Du, Yuguo] Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China; [Zhang, Xinyi; Wei, Dongbin; Sun, Xuefeng; Bai, Chenzhong; Du, Yuguo] Univ Chinese Acad Sci, Beijing 100049, Peoples R China published Free available chlorine initiated Baeyer-Villiger oxidation: A key mechanism for chloroform formation during aqueous chlorination of benzophenone UV filters in 2021, Cited 41. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9.

Chloroform, a regulated disinfection by-product in water, is often generated during chlorination disinfection treatment. However, the formation of chloroform is heavily dependent on the molecular structures of precursors. Moreover, compounds containing ketone moiety are ubiquitous in water environments. However, it is unclear if they can generate chloroform during chlorination. In this study, 14 benzophenones (BPs), efficient and widely used UV filters, with different substituents were selected to explore chloroform formation during chlorination. All 14 BPs generated chloroform, with yields dependent on their molecular structures and operational conditions. Compounds 2,2′,4,4′-tetrahydroxy-BP and benzophenone produced the highest and lowest chloroform of 0.313 and 0.013 g/g, respectively, corresponding to the fastest and slowest formation rate constants of 1.41 x 10(-1) and 2.71 x 10(-2) min(-1). Alkaline conditions and high chlorine dosages were favorable to chloroform formation. Three reactions played key roles in chloroform formation from BPs: (1) chlorine initiated Baeyer Villiger oxidation converted ketone moieties of BP molecules into esters; (2) the esters further underwent hydrolysis and formed phenolic and benzoic products; and (3) benzoic acids underwent decarboxylation and hydrolysis to form phenolic products. Subsequently, these phenolic products could further generate chloroform in the chlorination system. More importantly, BPs could generate chloroform in the ambient water matrices during practical chlorination treatment. This work emphasized the critical role of Baeyer-Villiger oxidation for chloroform formation, implying that pollutants containing aromatic ketone moieties generate chloroform during chlorination disinfection, and their potential risk should therefore be reviewed. (C) 2020 Elsevier Ltd. All rights reserved.

About Benzophenone, If you have any questions, you can contact Zhang, XY; Wei, DB; Sun, XF; Bai, CZ; Du, YG or concate me.. Recommanded Product: 119-61-9

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Authors Zhong, FY; Ma, MY; Zhong, ZR; Lin, XR; Chen, M in ROYAL SOC CHEMISTRY published article about in [Zhong, Fuyao; Lin, Xinrong] Yunnan Univ, Sch Chem Sci & Technol, Key Lab Med Chem Nat Resource, Minist Educ,Yunnan Prov Ctr Res & Dev Nat Prod, Kunming 650091, Yunnan, Peoples R China; [Zhong, Fuyao; Ma, Mingyu; Zhong, Zhuoran; Chen, Mao] Fudan Univ, Dept Macromol Sci, State Key Lab Mol Engn Polymers, Shanghai 200433, Peoples R China in 2021.0, Cited 60.0. Product Details of 119-61-9. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

Along with high power capability and energy density, long cycle life is regarded an essential performance requirement for energy storage devices. The rapid capacitance decline of conducting polymer-based electrodes remains a major technical challenge and precludes their practical applications in supercapacitors. In this work, a polyaniline (PANI) network is synthesized via interfacial Buchwald-Hartwig polymerization for the first time, facilitating the construction of covalently connected PANI networks by ligand-promoted C-N bond formation. Particularly, the interfacial synthesis and subsequent gas release from pre-anchored protecting groups allow bottom-up and efficient access to porous cross-linked PANI (PCL-PANI) films that are free-standing and solvent-resistant. Upon assembling into supercapacitors, the PCL-PANI material enables an unprecedent long-term charge-discharge cycling performance (>18 000 times) without clear capacitance loss for an additive-free pseudocapacitive system. In addition, this synthesis affords electrodes entirely consisting of conducting polymers, yielding highly reversible gravimetric capacitance at 435 F g(electrode)(-1) in a two-electrode system, and a high gravimetric energy of 12.5 W h kg(electrode)(-1) while delivering an outstanding power density of 16 000 W kg(electrode)(-1), which is 10-fold higher than those of conventional linear PANI composite supercapacitors. This synthetic approach represents a novel and versatile strategy to generate additive/binder-free and high-performance conducting thin-films for energy storage.

Product Details of 119-61-9. About Benzophenone, If you have any questions, you can contact Zhong, FY; Ma, MY; Zhong, ZR; Lin, XR; Chen, M or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Copper-catalyzed sulfonylation of N-tosylhydrazones followed by a one-pot C-N bond formation WOS:000655654000001 published article about AMINES SYNTHESIS; HYDRAZONES; REAGENTS; DECOMPOSITION; DIHALOARENES; SULFONES; ROUTE in [Zhang, Kena; Provot, Olivier; Tran, Christine; Alami, Mouad; Hamze, Abdallah] Univ Paris Saclay, CNRS, BioCIS, Fac Pharm, F-92290 Chatenay Malabry, France in 2021.0, Cited 32.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9. Formula: C13H10O

A new methodology to synthesize sulfonyl-N-phenylaniline derivatives via the trapping of bromo-sulfone derivatives generated from N-tosylhydrazones (NTHs) with amines is described. The reaction proved successful for a wide range of NTHs and amines and tolerated various functional groups on either coupling partner (35 examples). The mechanism was studied, and we showed that the sulfone formation does not follow a radical pathway.

Formula: C13H10O. About Benzophenone, If you have any questions, you can contact Zhang, KN; Provot, O; Tran, C; Alami, M; Hamze, A or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

COA of Formula: C13H10O. Authors Yiming, BRB; Han, Y; Han, ZL; Zhang, XN; Li, Y; Lian, WZ; Zhang, MQ; Yin, J; Sun, TL; Wu, ZL; Li, TF; Fu, JZ; Jia, Z; Qu, SX in WILEY-V C H VERLAG GMBH published article about in [Yiming, Burebi; Han, Zilong; Zhang, Mingqi; Li, Tiefeng; Jia, Zheng; Qu, Shaoxing] Zhejiang Univ, Ctr X Mech, Key Lab Soft Machines & Smart Devices Zhejiang Pr, Dept Engn Mech, Hangzhou 310027, Peoples R China; [Han, Ying; Li, Yang; Yin, Jun; Fu, Jianzhong] Zhejiang Univ, Sch Mech Engn, State Key Lab Fluid Power & Mechatron Syst, Lab 3D Printing Proc & Equipment Zhejiang Prov, Hangzhou 310027, Peoples R China; [Zhang, Xinning; Wu, Ziliang] Zhejiang Univ, Dept Polymer Sci & Engn, Minist Educ, Key Lab Macromol Synth & Functionalizat, Hangzhou 310027, Peoples R China; [Lian, Weizhen; Sun, Taolin] South China Univ Technol, South China Adv Inst Soft Matter Sci & Technol, Guangzhou 510640, Peoples R China in 2021.0, Cited 51.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

Soft ionic conductors, such as hydrogels and ionogels, have enabled stretchable and transparent ionotronics, but they suffer from key limitations inherent to the liquid components, which may leak and evaporate. Here, novel liquid-free ionic conductive elastomers (ICE) that are copolymer networks hosting lithium cations and associated anions via lithium bonds and hydrogen bonds are demonstrated, such that they are intrinsically immune from leakage and evaporation. The ICEs show extraordinary mechanical versatility including excellent stretchability, high strength and toughness, self-healing, quick self-recovery, and 3D-printability. More intriguingly, the ICEs can defeat the conflict of strength versus toughness-a compromise well recognized in mechanics and material science-and simultaneously overcome the conflict between ionic conductivity and mechanical properties, which is common for ionogels. Several liquid-free ionotronics based on the ICE are further developed, including resistive force sensors, multifunctional ionic skins, and triboelectric nanogenerators (TENGs), which are not subject to limitations of previous gel-based devices, such as leakage, evaporation, and weak hydrogel-elastomer interfaces. Also, the 3D printability of the ICEs is demonstrated by printing a series of structures with fine features. The findings offer promise for a variety of ionotronics requiring environmental stability and durability.

COA of Formula: C13H10O. About Benzophenone, If you have any questions, you can contact Yiming, BRB; Han, Y; Han, ZL; Zhang, XN; Li, Y; Lian, WZ; Zhang, MQ; Yin, J; Sun, TL; Wu, ZL; Li, TF; Fu, JZ; Jia, Z; Qu, SX or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Safety of Benzophenone. Authors Ludwig, JR; Simmons, EM; Wisniewski, SR; Chirik, PJ in AMER CHEMICAL SOC published article about in [Ludwig, Jacob R.; Chirik, Paul J.] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA; [Simmons, Eric M.; Wisniewski, Steven R.] Bristol Myers Squibb Co, Chem Proc Dev, New Brunswick, NJ 08903 USA in 2021.0, Cited 49.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

A cobalt-catalyzed method for the C(sp(2))-C(sp(3)) Suzuki-Miyaura cross coupling of aryl boronic esters and alkyl bromides is described. Cobalt-ligand combinations were assayed with high-throughput experimentation, and cobalt(II) sources with trans-N,N’-dimethylcyclohexane-1,2-diamine (DMCyDA, L-1) produced optimal yield and selectivity. The scope of this transformation encompassed steric and electronic diversity on the aryl boronate nucleophile as well as various levels of branching and synthetically valuable functionality on the electrophile. Radical trap experiments support the formation of electrophile-derived radicals during catalysis.

About Benzophenone, If you have any questions, you can contact Ludwig, JR; Simmons, EM; Wisniewski, SR; Chirik, PJ or concate me.. HPLC of Formula: C13H10O

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Authors Phifer, A; Gray, G; Kratchman, J; Attene-Ramos, MS in TAYLOR & FRANCIS INC published article about DATA-ANALYSIS PIPELINE; RISK-ASSESSMENT; CHEMICALS; VISION in [Phifer, Adrienne; Gray, George; Kratchman, Jessica; Attene-Ramos, Matias S.] George Washington Univ, Dept Environm & Occupat Hlth, Milken Inst Sch Publ Hlth, Washington, DC USA in 2021.0, Cited 33.0. Name: Benzophenone. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

In vivo animal bioassays are increasingly being supplemented with in vitro assays to serve as the new standard for chemical toxicity tests. Despite this shift, investigators face challenges related to increased reliance on in vitro data. The aim of this study was to deploy a streamlined method to assess the ability of in vitro data to predict similar results as in vivo data by correlating chemical toxicity rankings obtained using Benchmark Doses and Benchmark Dose Lower Limits (BMD(L)s) derived from in vivo and in vitro assays. In vitro and in vivo assay characteristics were assessed for their impact on the predictive ability of in vitro data. Minimum best-fit BMD(L)s were calculated for chemicals using Environmental Protection Agency’s (EPA’s) Benchmark Dose Software (BMDS). Forty-one chemicals met the inclusion criteria of this study. Relative chemical toxicity rankings were assessed through Kappa statistics, Pearson correlations, and/or Ordinary Least Squares (OLS) regressions. Results illustrated likely ability of in vitro data to predict similar results as short-term in vivo data. Further, rankings derived from in vitro cytotoxicity assays, unlike stress response assays, significantly correlated with rankings derived from short-term in vivo assays. These results support the use of in vitro data as a prioritization tool within toxicity testing.

Name: Benzophenone. About Benzophenone, If you have any questions, you can contact Phifer, A; Gray, G; Kratchman, J; Attene-Ramos, MS or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

HPLC of Formula: C13H10O. I found the field of Chemistry very interesting. Saw the article Ru-containing magnetic yolk-shell structured nanocomposite: a powerful, recoverable and highly durable nanocatalyst published in 2021, Reprint Addresses Elhamifar, D (corresponding author), Univ Yasuj, Dept Chem, Yasuj 7591874831, Iran.. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone.

A novel method was used to prepare a magnetic phenylene-based periodic mesoporous organosilica nanocomposite with yolk-shell structure (Fe3O4@YSPMO). The Fe3O4@YSPMO nanomaterial was prepared by using easily accessible pluronic-P123 and cetyltrimethylammonium bromide (CTAB) surfactants under basic conditions. This material was employed for effective immobilization of potassium perruthenate to prepare an Fe3O4@YSPMO@Ru nanocatalyst for the aerobic oxidation of alcohols. The physiochemical properties of the designed Fe3O4@YSPMO@Ru nanocomposite were studied using PXRD, FT-IR, TGA, SEM, TEM, ICP, VSM and XPS analyses. Fe3O4@YSPMO@Ru was effectively employed as a highly recoverable nanocatalyst in the selective aerobic oxidation of alcohols.

HPLC of Formula: C13H10O. About Benzophenone, If you have any questions, you can contact Mirbagheri, R; Elhamifar, D; Hajati, S or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Authors Park, N; Jeon, J in PERGAMON-ELSEVIER SCIENCE LTD published article about in [Park, Naree; Jeon, Junho] Changwon Natl Univ, Grad Sch FEED Ecofriendly Offshore Struct, Chang Won 51140, Gyeongsangnamdo, South Korea; [Jeon, Junho] Changwon Natl Univ, Sch Civil Environm & Chem Engn, Chang Won 51140, Gyeongsangnamdo, South Korea; [Jeon, Junho] Changwon Natl Univ, Dept Smart Ocean Environm Energy, Chang Won 51140, Gyeongsangnamdo, South Korea in 2021.0, Cited 68.0. Name: Benzophenone. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

The extensive development and use of new anthropogenic chemicals have inevitably led to their presence in aquatic environments. Surface waters affected by sewage effluents have been exposed to these new substances. In the present study, the occurrence of anthropogenic substances, including pharmaceuticals and industrial chemicals, was investigated in one of the major rivers in Korea, the Nakdong River. Furthermore, seasonal variations in their content were determined via annual monitoring. Through the suspect and non-target screening (SNTS) technique, 58 substances were newly identified in the river and integrated in the quantitative monitoring practice. The results revealed that niflumic acid and melamine exhibited the highest median concentrations, i.e., 320 ng/L and 11,000 ng/L, respectively. The results associated with seasonal change revealed that the concentration of a considerable number of substances increased in winter when the flow rate was low. Conversely, some substances exhibited high concentrations in summer (e.g., polyethylene glycol) and spring (e.g., niflumic acid). This was attributed to the seasonal changes in the consumption, prescriptions, or the application of alternative substances. These changes were also reflected by the risk quotient (RQ) values calculated from the concentration and toxicity values. Pharmaceuticals such as telmisartan and carbamazepine and industrial chemicals such as organophosphorus flame retardants (OPFRs) and melamine accounted for approximately 90% of the total RQ. Major substances prioritized using the production of the RQ value and the detection frequency included OPFRs and telmisartan. It is recommended that these results be reflected in future water quality monitoring plans. (C) 2020 Elsevier Ltd. All rights reserved.

Name: Benzophenone. About Benzophenone, If you have any questions, you can contact Park, N; Jeon, J or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Recently I am researching about MILD CONDITIONS; SELECTIVE OXIDATION; AROMATIC-ALDEHYDES; BENZYLIC ALCOHOLS; NITROXYL RADICALS; MOLECULAR-OXYGEN; SOLID CATALYSTS; BUTYL NITRITE; POLAR; PERFORMANCE, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21501135, 21875165]; Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities; Recruitment Program of Global Experts of China. Recommanded Product: 119-61-9. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Wang, M; Liang, G; Wang, YH; Fan, T; Yuan, BL; Liu, MX; Yin, Y; Li, LC. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone

Two highly efficient metal-organic framework catalysts TJU-68-NHPI and TJU-68-NDHPI have been successfully synthesized through solvothermal reactions of which the frameworks are merged with N-hydroxyphthalimide (NHPI) units, resulting in the decoration of pore surfaces with highly active nitroxyl catalytic sites. When t-butyl nitrite (TBN) is used as co-catalyst, the as-synthesized MOFs are demonstrated to be highly efficient and recyclable catalysts for a novel three-phase heterogeneous oxidation of activated C-H bond of primary and secondary alcohols, and benzyl compounds under mild conditions. Based on the high efficiency and selectivity, an environmentally benign system with good sustainability, mild conditions, simple work-up procedure has been established for practical oxidation of a wide range of substrates.

About Benzophenone, If you have any questions, you can contact Wang, M; Liang, G; Wang, YH; Fan, T; Yuan, BL; Liu, MX; Yin, Y; Li, LC or concate me.. Recommanded Product: Benzophenone

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem