Category: 119-61-9

Product Details of 119-61-9. In 2021.0 J ENVIRON CHEM ENG published article about BARRIER DISCHARGE REACTOR; BY-PRODUCTS; PHOTOCATALYTIC ACTIVITIES; ATMOSPHERIC-PRESSURE; VISIBLE-LIGHT; GAS-PHASE; REMOVAL; DECOMPOSITION; CONVERSION; OXIDATION in [Li, Mengyu; Li, Dandan; Zhang, Ziqi; Ji, Chunjie; Zhou, Shuo; Guo, Wenwen; Zhao, Chaocheng; Liu, Fang; Han, Fenglei] China Univ Petr East China, Sch Chem Engn, Qingdao 266580, Shandong, Peoples R China; [Zhao, Chaocheng; Liu, Fang; Han, Fenglei] Minist Sci & Technol, Key Lab Petr & Petrochem Pollut Control & Treatme, Beijing, Peoples R China in 2021.0, Cited 54.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9.

The degradation of toluene in dielectric barrier discharge (DBD) reactor packed with supported photocatalysts TiO2/gamma-Al2O3, Ce-TiO2/gamma-Al2O3, Ag-TiO2/gamma-Al2O3, La-TiO2/gamma-Al2O3, and Co-TiO2/gamma-Al2O3 was investigated.The supported catalysts were prepared by sol-gel and impregnation methods and were characterized in detail using N-2 adsorption,XRD,TEM,XPS and UV-Vis analysis technology. Compared to the non-thermal plasma (NTP) alone system, the degradation rate of toluene and CO2 selectivity improved significantly with the combination of plasma and photocatalysts, meanwhile, the CO selectivity and the by-products NO2 and O-3 reduced. When the photocatalyst Ag-TiO2/gamma-Al2O3 was packed into the discharge region,this plasma-photocatalytic system could completely remove toluene with above 81% CO2 selectivity and greatly reduced concentration of poisonous byproducts (O-3 and NO2) at 5 kJ.L-1, while exhibiting superior stability. The energy efficiency of the hybrid system was increased by about 1.4-3 times, compared with the separated NTP. The main energy loss was the formation of by-products and the loss of light and heat. Finally, the intermediate products of the toluene degradation process of different catalyst systems were analyzed by GC-MS, and the mechanism of toluene degradation by the NTP-photocatalytic system was concluded. The process of NTP synergistic photocatalytic degradation of toluene mainly included three aspects: NTP degradation of toluene, photocatalytic oxidation degradation of toluene, and the synergistic effect between the two. The results can provide a theoretical basis for the study on the performance of VOCs degradation by NTP, and have certain guiding significance for the application and mechanism research of VOCs degradation by NTP.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Lutz, MDR; Gasser, VCM; Morandi, B in [Lutz, Marius D. R.; Gasser, Valentina C. M.; Morandi, Bill] Swiss Fed Inst Technol, Lab Organ Chem, Dept Chem & Appl Biosci, Vladimir Prelog Weg 3, CH-8093 Zurich, Switzerland published Shuttle arylation by Rh(I) catalyzed reversible carbon-carbon bond activation of unstrained alcohols in 2021.0, Cited 54.0. COA of Formula: C13H10O. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9.

The advent of transfer hydrogenation and borrowing hydrogen reactions paved the way to manipulate simple alcohols in previously unthinkable manners and circumvented the need for hydrogen gas. Analogously, transfer hydrocarbylation could greatly increase the versatility of tertiary alcohols. However, this reaction remains unexplored because of the challenges associated with the catalytic cleavage of unactivated C-C bonds. Herein, we report a rhodium(I)-catalyzed shuttle arylation cleaving the C(sp(2))-C(sp(3)) bond in unstrained triaryl alcohols via a redox-neutral beta-carbon elimination mechanism. A selective transfer hydrocarbylation of substituted (hetero)aryl groups from tertiary alcohols to ketones was realized, employing benign alcohols as latent C-nucleophiles. All preliminary mechanistic experiments support a reversible b-carbon elimination/migratory insertion mechanism. In a broader context, this novel reactivity offers a new platform for the manipulation of tertiary alcohols in catalysis.

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,Thiomorpholine | C4H9NS – PubChem

Product Details of 119-61-9. Authors Feng, XJ; Lerch, S; Biller, H; Micksch, M; Schmidt, M; Baitinger, M; Strassner, T; Grin, Y; Bohme, B in WILEY-V C H VERLAG GMBH published article about in [Feng, Xian-Juan; Schmidt, Marcus; Baitinger, Michael; Grin, Yuri; Boehme, Bodo] Max Planck Inst Chem Phys Fester Stoffe, Abt Chem Met Kunde, Nothnitzer Str 40, D-01187 Dresden, Germany; [Lerch, Swantje; Biller, Harry; Micksch, Maik; Strassner, Thomas] Tech Univ Dresden, Fachrichtung Chem & Lebensmittelchem, Phys Organ Chem, D-01062 Dresden, Germany in 2021.0, Cited 35.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

Substituted imidazolium ionic liquids (ILs) were investigated for their reactivity towards Na12Ge17 as a model system containing redox-sensitive Zintl cluster anions. The ILs proved widely inert for imidazolium cations with a 1,2,3-trisubstitution at least by alkyl groups, and for the anion bis(trifluoromethylsulfonyl)azanide (TFSI). A minute conversion of Na12Ge17 observed on long-time contact with such ILs was not caused by dissolution of the salt-like compound, and did thus not provide dissolved Ge clusters. Rather, a cation exchange led to the transfer of Na+ ions into solution. In contrast, by using benzophenone as an oxidizer, heterogeneous redox reactions of Na12Ge17 were initiated, transferring a considerable part of Na+ into solution. At optimized conditions, an X-ray amorphous product NaGe6.25 was obtained, which was thermally convertible to the crystalline type-II clathrate Na24-delta Ge136 with almost completely Na-filled polyhedral cages, and alpha-Ge. The presented method thus provides unexpected access to Na24-delta Ge136 in bulk quantities.

Product Details of 119-61-9. Welcome to talk about 119-61-9, If you have any questions, you can contact Feng, XJ; Lerch, S; Biller, H; Micksch, M; Schmidt, M; Baitinger, M; Strassner, T; Grin, Y; Bohme, B or send Email.

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Thiomorpholine – Wikipedia,
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Authors Sayago-Ayerdi, SG; Venema, K; Tabernero, M; Sarria, B; Bravo, LL; Mateos, R in ELSEVIER published article about PLANT FOODS; BIOAVAILABILITY; PRODUCTS; ACID; QTOF in [Sayago-Ayerdi, Sonia G.] Tecnol Nacl Mexico, Inst Tecnol Tepic, Av Inst Tecnol 2595, Tepic 63175, Nayarit, Mexico; [Venema, Koen] Maastricht Univ, Ctr Hlth Eating & Food Innovat, Campus Venlo,St Jansweg 20, NL-5928 RC Venlo, Netherlands; [Tabernero, Maria] CEI UAM CSIC, IMDEA Food Inst, Carretera Canto Blanco 8, Madrid 28049, Spain; [Sarria, Beatriz; Bravo, L. Laura; Mateos, Raquel] CSIC, Inst Food Sci Technol & Nutr ICTAN CSIC, Jose Antonio Novais 10, Madrid 28040, Spain in 2021.0, Cited 28.0. Application In Synthesis of Benzophenone. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

Gut microbiota bioconversion of polyphenols in predigested mango ‘Ataulfo’ peel was studied using a validated, dynamic in vitro human colon model (TIM-2) with faecal microbial inoculum. Dried peels were predigested with enzymatic treatment, followed by TIM-2 fermentation (72 h). Samples were taken at 0, 24, 48 and 72 h and analyzed by HPLC-QToF. Derivatives of hydroxyphenylpropionic, hydroxyphenylacetic and hydroxybenzoic acids, as well as, pyrogallol were the main polyphenols identified. These metabolites might derivate from flavonoid (flavanols and flavonols), gallate and gallotannin biotransformation. Despite the high content of ellagic acid in mango peel, low amounts were detected in TIM-2 samples due to transformation into urolythins A and C, mainly. Xanthone and benzophenone derivatives, specific to mango, remained after the colonic biotransformation, contrary to flavonoids, which completely disappeared. In conclusion, microbial-derived metabolites, such as xanthone and benzophenone derivatives, among others, are partially stable after colonic fermentation, and thus have the potential to contribute to mango peel bioactivity.

Application In Synthesis of Benzophenone. Bye, fridends, I hope you can learn more about C13H10O, If you have any questions, you can browse other blog as well. See you lster.

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Thiomorpholine – Wikipedia,
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An article Waste-Minimized Cyanosilylation of Carbonyls Using Fluoride on Polymeric Ionic Tags in Batch and under Continuous Flow Conditions WOS:000644738000026 published article about METAL-ORGANIC FRAMEWORKS; SELECTIVE ALDEHYDE CYANOSILYLATION; SOLVENT-FREE CYANOSILYLATION; LEWIS-BASE ACTIVATION; ENANTIOSELECTIVE CYANOSILYLATION; KNOEVENAGEL CONDENSATION; TRIMETHYLSILYL CYANIDE; EFFICIENT SYNTHESIS; CHEMICAL-REACTIONS; BETA-AZIDATION in [Ferlin, Francesco; Valentini, Federica; Brufani, Giulia; Vaccaro, Luigi] Univ Perugia, Lab Green SOC, Dipartimento Chim Biol & Biotecnol, I-06123 Perugia, Italy; [Lanari, Daniela] Univ Perugia, Dipartimento Sci Farmaceut, I-06123 Perugia, Italy in 2021.0, Cited 82.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9. Recommanded Product: Benzophenone

Herein, we report the development of a tailor-made fluoride-based heterogeneous catalyst, POLITAG-F, for the waste-minimized continuous production of cyanohydrin silyl ethers. The careful designing of the polymeric support and the choice of fluoride ion as the anionic species resulted in the improvement of catalytic efficiency and allowed the effective conversion of different carbonyls (aldehydes, ketones, and unsaturated ketones). The POLITAG-F catalyst, employed under flow conditions, led to the conversion of large amounts (over 100 mmol) of the substrate with a productivity of 0.1 mmol min(-1). In addition, flow conditions allowed to minimize the waste production reaching an associated E-factor value of 0.04. An exhaustive evaluation of the environmental impact of our protocol has been reported by considering several green metrics (process mass intensity, atom economy, and reaction mass efficiency) and also the benign index and the safety hazard index of the process.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

I found the field of Chemistry very interesting. Saw the article Continuous Flow Sodiation of Substituted Acrylonitriles, Alkenyl Sulfides and Acrylates published in 2021.0. Application In Synthesis of Benzophenone, Reprint Addresses Knochel, P (corresponding author), Ludwig Maximilians Univ Munchen, Dept Chem, Butenandtstr 5-13,Haus F, D-81377 Munich, Germany.. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone

The sodiation of substituted acrylonitriles and alkenyl sulfides in a continuous flow set-up using NaDA (sodium diisopropylamide) in EtNMe2 or NaTMP (sodium 2,2,6,6-tetramethylpiperidide).TMEDA in n-hexane provides sodiated acrylonitriles and alkenyl sulfides, which are subsequently trapped in batch with various electrophiles such as aldehydes, ketones, disulfides and allylic bromides affording functionalized acrylonitriles and alkenyl sulfides. This flow-procedure was successfully extended to other acrylates by using Barbier-type conditions.

Application In Synthesis of Benzophenone. Welcome to talk about 119-61-9, If you have any questions, you can contact Harenberg, JH; Weidmann, N; Karaghiosoff, K; Knochel, P or send Email.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

HPLC of Formula: C13H10O. In 2021.0 CHEMCATCHEM published article about UNSATURATED TRIS(TRIMETHYLSILYL)SILYL COMPLEXES; IRON-CATALYZED HYDROSILYLATION; SELECTIVE REDUCTION; CARBONYL; NICKEL; COBALT; METAL in [Saito, Kyoka] Chuo Univ, Fac Sci & Engn, Dept Appl Chem, Bunkyo Ku, 1-13-27 Kasuga, Tokyo, Japan; [Ito, Tatsuyoshi] Kanagawa Inst Ind Sci & Technol KISTEC, Meguro Ku, 4-6-1 Komaba, Tokyo, Japan; [Arata, Shogo; Sunada, Yusuke] Univ Tokyo, Sch Engn, Dept Appl Chem, Meguro Ku, 4-6-1 Komaba, Tokyo, Japan; [Sunada, Yusuke] Univ Tokyo, Inst Ind Sci, Meguro Ku, 4-6-1 Komaba, Tokyo, Japan in 2021.0, Cited 49.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9.

The coordinatively unsaturated manganase(II) bis(supersilyl) complex Mn[Si(SiMe3)(3)](2)(THF)(2) (2) was synthesized in one step via the reaction of MnBr2 with two equivalents of KSi(SiMe3)(3) in THF. Complex 2 acts as an effective precatalyst for the catalytic hydrosilylation of aldehydes and ketones with 1,1,3,3-tetramethyldisiloxane (TMDS). The catalytic efficiency can be improved by combining 2 and adamantyl isocyanide (CNAd). The stoichiometric reaction of 2 and two equivalents of CNAd led to the isolation of Mn[Si(SiMe3)(3)](2)(CNAd)(2) (3) in high yield. Complex 3 shows superior catalytic performance than 2 in the hydrosilylation of relatively unreactive ketones.

Welcome to talk about 119-61-9, If you have any questions, you can contact Saito, K; Ito, T; Arata, S; Sunada, Y or send Email.. HPLC of Formula: C13H10O

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Authors Dale, HJA; Nottingham, C; Poree, C; Lloyd-Jones, GC in AMER CHEMICAL SOC published article about in [Dale, Harvey J. A.; Nottingham, Chris; Poree, Carl; Lloyd-Jones, Guy C.] Univ Edinburgh, Sch Chem, Edinburgh EH9 3FJ, Midlothian, Scotland in 2021.0, Cited 50.0. Name: Benzophenone. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

Alkylidene carbenes undergo rapid inter- and intramolecular reactions and rearrangements, including 1,2-migrations of beta-substituents to generate alkynes. Their propensity for substituent migration exerts profound influence over the broader utility of allcylidene carbene intermediates, yet prior efforts to categorize 1,2-migratory aptitude in these elusive species have been hampered by disparate modes of carbene generation, ultrashort carbene lifetimes, mechanistic ambiguities, and the need to individually prepare a series of C-13-labeled precursors. Herein we report on the rearrangement of C-13-alkylidene carbenes generated in situ by the homologation of carbonyl compounds with [C-13]-Li-TMS-diazomethane, an approach that obviates the need for isotopically labeled substrates and has expedited a systematic investigation (C-13{H-1} NMR, DLPNO-CCSD(T)) of migratory aptitudes in an unprecedented range of more than 30 alkylidene carbenes. Hammett analyses of the reactions of 26 differentially substituted benzophenones reveal several counterintuitive features of 1,2-migration in alkylidene carbenes that may prove of utility in the study and synthetic application of unsaturated carbenes more generally.

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Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Authors Wu, K; Ling, YC; Sun, N; Hu, BX; Shen, ZL; Jin, LQ; Hu, XQ in ROYAL SOC CHEMISTRY published article about in [Wu, Ke; Ling, Yichen; Sun, Nan; Hu, Baoxiang; Shen, Zhenlu; Jin, Liqun; Hu, Xinquan] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310032, Peoples R China; [Jin, Liqun; Hu, Xinquan] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China in 2021.0, Cited 50.0. SDS of cas: 119-61-9. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

A nickel-catalyzed reductive decyanation of aromatic nitriles has been developed, in which the readily available and abundant ethanol was applied as the hydride donor. Various functional groups on the aromatic rings, such as alkoxyl, amino, imino and amide, were compatible in this catalytic protocol. Heteroaryl, benzylic and alkenyl nitriles were also tolerated. Mechanistic investigation indicated that ethanol provided hydride efficiently via beta-hydride elimination in this reductive decyanation.

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Thiomorpholine – Wikipedia,
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SDS of cas: 119-61-9. In 2021.0 J ETHNOPHARMACOL published article about ANTIOXIDANT ACTIVITY; SIGNALING PATHWAYS; OXIDATIVE STRESS; OSTEOPONTIN; DERIVATIVES; DYSFUNCTION; APOPTOSIS; DISEASE; MAPK in [Singh, Anubha; Nandi, Shoma Paul; Tandon, Chanderdeep] Amity Univ, Amity Inst Biotechnol, Noida, India; [Tandon, Simran] Amity Univ, Amity Inst Mol Med & Stem Cell Res, Noida, India; [Kaur, Tanzeer] Panjab Univ, Dept Biophys, Chandigarh, India in 2021.0, Cited 68.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9.

Ethnopharmacological relevance: In the Indian traditional system of medicine, Bergenia ligulata (Wall.) Engl. has been used for treatment of umlithiasis. Its efficacious nature has led to its incorporation in various commercial herbal formulations such as Cystone and Neeri which are prescribed for kidney related ailments. Aim of the study: To assess whether ethanolic extract of B. ligulata can mitigate the cascade of inflammatory responses that cause oxidative stress and ultimately cell death in renal epithelial cells exposed to hyperoxaluric conditions. Material and methods: Bioactivity guided fractionation using solvents of varying polarities was employed to evaluate the potential of the extracts of B. ligulata to inhibit the crystallization process. Modulation of crystal morphology was visualized through Scanning electron microscopy (SEM) analysis. Cell death was assessed using flow cytometry based assays. Alteration in the inflammatory mediators was evaluated using real time PCR and immunocytochemistry. Phytochemical characterization of the ethanolic extract was carried out using FTIR, LCMS and GC-MS. Results: Bioactivity guided fractionation for the assessment of antilithiatic activity revealed dose dependent inhibition of nucleation and aggregation process of calcium oxalate crystals in the presence of various extracts, however ethanolic extract showed maximum inhibition and was chosen for further experiments. Studies on renal epithelial NRK-52E cells showed, cytoprotective efficacy of B. ligulata extract against oxalate injury. SEM anaysis further revealed the potential of the extract to modulate the crystal structure and adhesion to renal cell surface. Exposure of the renal cells to the extract led to conversion of the calcium oxalate monohydrate (COM) crystals to the less injurious calcium oxalate dihydrate (COD) form. Expression analysis for oxidative stress and inflammatory biomarkers in NRK-52E cells revealed up-regulation of Mitogen activated protein kinase (MAPK), Osteopontin (OPN) and Nuclear factor-kappa B (NF-kappa B), in response to calcium oxalate insult; which was drastically reduced in the presence of B. ligulata extract. Flow cytometric evaluation pointed to caspase 3 mediated apoptotic cell death in oxalate injured cells, which was attenuated by B. ligulata extract. Conclusion: Considering the complex multifactorial etiology of urolithiasis, ethanolic extract from B. ligulata can be a promising option for the management of kidney stones, as it has the potential to limit inflammation and the subsequent cell death.

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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem