Category: 119-61-9

I found the field of Chemistry very interesting. Saw the article Pentafluoroethylation of Carbonyl Compounds by HFC-125 via the Encapsulation of the K Cation with Glymes published in 2021. SDS of cas: 119-61-9, Reprint Addresses Shibata, N (corresponding author), Nagoya Inst Technol, Dept Life Sci & Appl Chem, Nagoya, Aichi 4668555, Japan.; Shibata, N (corresponding author), Nagoya Inst Technol, Dept Nanopharmaceut Sci, Nagoya, Aichi 4668555, Japan.; Shibata, N (corresponding author), Zhejiang Normal Univ, Inst Adv Fluorine Containing Mat, Jinhua 321004, Zhejiang, Peoples R China.. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone

A simple protocol to overcome the explosive pentafluoroethylation of carbonyl compounds by HFC-125 is described. The use of potassium (K) bases with triglyme or tetraglyme as a solvent safely yields the pentafluoroethylation products in good to high yields. The experimental results suggest that an encapsulation of the K cation by glymes as K(glyme)(2) inhibits the contact between the K cation and the reactive anionic pentafluoroethyl counterion, preventing their transformation into KF and explosive tetrafluoroethylene (TFE). The generation of sterically demanding [K(G3)(2)](+) and [K(G4)(2)](+) is an effective way as an unstable pentafluoroethyl anion reservoir.

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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Authors Biliskov, N in AMER CHEMICAL SOC published article about in [Biliskov, Nikola] Rudjer Boskovic Inst, Dept Organ Chem & Biochem, Zagreb 10000, Croatia in 2021.0, Cited 19.0. Name: Benzophenone. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

Diphenylamine reacts with benzophenone in the solid state through the formation of a eutectic liquid intermediate, from which the final product, in the form of a hydrogen-bonded cocrystal, is finally formed. By a simple experiment, the phase diagram of the benzophenone/diphenylamine system is effectively divided into two parts, which enabled monitoring of the overall process from the side of each reactant separately. Accompanied by isothermal and nonisothermal spectroscopic monitoring of the system, this provides additional details of the mechanistic pathway of the process of cocrystal formation through a metastable liquid intermediate phase.

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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

SDS of cas: 119-61-9. Authors Wang, YH; Zhao, JW; Xu, F; Zhang, QD; Ai, ZL; Li, BY in WILEY published article about in [Wang, Yuan-Hui; Ai, Zhi-Lu] Henan Agr Univ, Minist Agr & Rural Affairs Peoples Republ China, Key Lab Staple Grain Proc, Zhengzhou, Peoples R China; [Wang, Yuan-Hui; Zhao, Jing-Wen; Xu, Fei; Li, Bo-Yu] Henan Univ Technol, Coll Food Sci & Technol, Zhengzhou, Peoples R China; [Zhang, Qi-Dong] Zhengzhou Tobacco Res Inst CNTC, Zhengzhou, Peoples R China in 2021.0, Cited 31.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

The volatile compounds of Jiaozi-steamed breads (JSBs) fermented by Jiaozi starters from eight regions in China were extracted using simultaneous distillation and extraction (SDE) and headspace solid-phase microextraction and determined using gas chromatography-mass spectrometry (GC-MS). 1-Hexanol, 3-methyl-1-butanol, phenylethyl alcohol, benzaldehyde, naphthalene, ethanol, acetic acid, and n-hexadecanoic acid were the main volatiles of JSBs. Principal component analysis exhibited that the volatiles of JSBs from Nanyang City, Xi’an City, and Zhumadian City was negatively correlated to that of other five JSB samples. Cluster analysis demonstrated that the volatile characteristics of JSBs from Heze City, Minqin County, Taian City, Weinan City, and Yuncheng City belonged to a category, and the JSBs of Nanyang City, Xi’an City, and Zhumadian City were different from other five JSBs. It demonstrated that the volatile components of steamed breads in North China and South China were different. Practical applications From this study, it can be seen that simultaneous distillation and extraction (SDE) can completely extract volatile compositions of steamed breads fermented by Chinese traditional starter Jiaozi. SDE/GC-MS was suitable for the analysis of JSBs volatile composition. The relative contents of 1-hexanol, 3-methyl-1-butanol, phenylethyl alcohol, benzaldehyde, naphthalene, ethanol, acetic acid, and n-hexadecanoic acid in JSBs were at high level, and their contents could be used as a marker to identify JSBs. The volatile compositions of JSBs made of Jiaozi starters from Heze City, Minqin County, Taian City, Weinan City, and Yuncheng City were similar. However, JSBs of Nanyang City, Xi’an City, and Zhumadian City were different from other five JSBs. The volatile components of steamed breads in North China and South China were different, which reflected the difference in dietary habit in the southern and northern areas of China.

SDS of cas: 119-61-9. Bye, fridends, I hope you can learn more about C13H10O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Recently I am researching about LIGHT PHOTOCATALYTIC ACTIVITY; PERFORMANCE; ADSORPTION; G-C3N4; NANOSHEETS; DISORDER; ATRAZINE, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [22006131, 22076168, 52000158]; Zhejiang Provincial Natural Science Foundation of ChinaNatural Science Foundation of Zhejiang Province [LQ20B070010]; China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [2020T130598, 2019M662106]; Zhejiang University of Technology Startup [2018129007129]; Zhejiang Provincial Ten Thousand Talent Program [2018R52013]. Formula: C13H10O. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Zhu, C; Shen, Y; Wang, SB; Song, S; Fang, QL; Wang, D; Xu, HM; Liu, RL; He, ZQ. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone

Defect engineering of nanomaterials has emerged as a promising approach to improve their performance for pollutant removal. However, various nanomaterial defects play variant roles in environmental applications. It is still a challenge to construct multiple defects of composite materials into advantageous aggregates to deal with complicated matrix pollution. In this work, we investigated a series of three-dimensional defect-optimized aerogels (3D DOAs) of graphene oxide (GO) with a covalent triazine framework (CTF) for improved adsorption and photoregeneration performance via tailoring duet carbon and nitrogen defects. Using chemical reduction, carbon defects in GO were gradually repaired and nitrogen defects in CTF were created simultaneously. The carbon defect engineering generated additional nonpolarized electron-depleted sites in GO of 3D DOA for increased adsorption capacities (2417 mu mol/g for benzophenone, 2209 mu mol/g for 4-hydroxybenzophenone, 1957 mu mol/g for 2,2′,4,4′-tetrahydroxybenzophenone). Meanwhile, increasing nitrogen defects of the CTF in 3D DOA would produce midgap states for an extended absorption range of visible light and increased photocatalytic activity to remove adsorbed pollutants. The enhanced adsorption and the superior photocatalytic regeneration soundly corroborated that the performance of 3D DOA was improved effectively by the defect optimization strategy. Moreover, the high stability of 3D DOA and its practical usage were verified in a real water matrix with a 7-day cycle test. The present work highlights an approach of defect optimization for development of a solar-driven, self-regenerative adsorbent for water purification with high efficiency.

Formula: C13H10O. Welcome to talk about 119-61-9, If you have any questions, you can contact Zhu, C; Shen, Y; Wang, SB; Song, S; Fang, QL; Wang, D; Xu, HM; Liu, RL; He, ZQ or send Email.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

SDS of cas: 119-61-9. Recently I am researching about AMINO-ACID SURFACTANTS; PEPTIDE AMPHIPHILE; SODIUM; STABILITY; MICELLIZATION; FLUORESCENCE; ASSEMBLIES; GLYCINE; BOND, Saw an article supported by the National Key R&D Program of China [2017YFB0308701]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21676003, 21902004, 22008002]; Beijing Natural Science Foundation of ChinaBeijing Natural Science Foundation [2204076]; Beijing Municipal Education CommissionBeijing Municipal Commission of Education [KM202110011001]; Beijing Municipal Science and Technology Project [D17110500190000]. Published in ELSEVIER in AMSTERDAM ,Authors: Zhang, JY; Li, QN; Wang, SN; Zhang, GJ; He, S; Liu, CY; Wang, C; Xu, BC. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone

With the growing concern about safety and environmental issues, amino acid-based surfactants have great potential as sustainable and eco-friendly substances. In the present study, six N-acyl oligopeptide surfactants were synthesized using fatty acid methyl esters (i.e., methyl caprate, methyl laurate, and methyl myristate) and glycyl oligopeptides (i.e., glycylglycine and glycylglycylglycine). Surface active properties and aggregation behaviors of these surfactants were investigated using surface tension, fluorescence probe, dynamic light scattering, and microscopy measurements. The adsorption at the air-water interface and aggregation in the aqueous solution depend on the structure of both hydrophilic head-groups and hydrophobic tails. Spherical vesicles were observed in the aqueous solutions of glycylglycine derivatives, whereas short tubular aggregates were found in that of corresponding glycylglycylglycine products. Intermolecular hydrogen-bonding interaction between the amide head-groups might be responsible for the different self-assembly behavior and microstructure of N-acyl oligopeptide surfactants in the aqueous solution.

SDS of cas: 119-61-9. Welcome to talk about 119-61-9, If you have any questions, you can contact Zhang, JY; Li, QN; Wang, SN; Zhang, GJ; He, S; Liu, CY; Wang, C; Xu, BC or send Email.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Computed Properties of C13H10O. In 2021.0 CHIRALITY published article about RECOGNITION; PHASE in [Phyo, Ye’ Zaw; Kijjoa, Anake] Univ Porto, ICBAS Inst Ciencias Biomed Abel Salazar, Porto, Portugal; [Phyo, Ye’ Zaw; Teixeira, Joana; Palmeira, Andreia; Tiritan, Maria Elizabeth; Bousbaa, Hassan; Pinto, Madalena M. M.; Fernandes, Carla; Kijjoa, Anake] Interdisciplinary Ctr Marine & Environm Res CIIMA, Matosinhos, Portugal; [Teixeira, Joana; Palmeira, Andreia; Tiritan, Maria Elizabeth; Pinto, Madalena M. M.; Fernandes, Carla] Fac Farm, Lab Quim Organ & Farmaceut, Dept Ciencias Quim, Rua Jorge Viterbo Ferreira 228, P-4050313 Porto, Portugal; [Goncalves, Ricardo; Tiritan, Maria Elizabeth; Bousbaa, Hassan] Inst Invest & Formacao Avancada Ciencias & Tecnol, Cooperat Ensino Super Politecn & Univ, Gandra, Portugal in 2021.0, Cited 57.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9.

Liquid chromatography enantioseparation and determination of enantiomeric purity of synthetized xanthone and benzophenone derivatives comprising one or more chiral moieties are reported. High enantioselectivity and resolution were observed in (S,S)-Whelk-O1 chiral stationary phase (CSP) for the enantiomeric mixtures of compounds comprising an aromatic ring linked to the stereogenic center(s), with alpha values ranging from 1.35 to 4.15 and Rs values ranging from 2.22 to 13.87. Among all the tested enantiomeric mixtures, those comprising three chiral moieties positioned in the xanthone scaffold gave the best chromatographic results. Enantiomers comprising an alkyl chain linked to the stereogenic centers were enantioseparated on a Lux (R) Celullose-2 CSP. For both CSPs, the elution was performed in polar organic mode. The enantiomeric ratio (e.r.) values were always higher than 99%. Additionally, assessment of chiral recognition mechanisms on (S,S)-Whelk-O1 CSP was performed by molecular docking approach, which are in accordance with the chromatographic parameters. The nature and number of chiral moieties in the central aromatic scaffold of either xanthone or benzophenone derivatives are proved to be crucial for enantiorecognition. The evaluation of the growth inhibition of human tumor cell lines revealed that (S,S)-(+)-5 was the most potent compound, with values of GI(50) of 12.83 +/- 2.09 mu M for A375-C5 melanoma, 12.40 +/- 1.16 mu M for MCF-7 breast adenocarcinoma, and 13.06 +/- 1.29 mu M for NCI-H460 non-small cell lung cancer. In some cases, the growth inhibitory effects demonstrated to be dependent on the stereochemistry of the compounds.

Computed Properties of C13H10O. Welcome to talk about 119-61-9, If you have any questions, you can contact Phyo, YZ; Teixeira, J; Goncalves, R; Palmeira, A; Tiritan, ME; Bousbaa, H; Pinto, MMM; Fernandes, C; Kijjoa, A or send Email.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Recently I am researching about RADICAL CYCLIZATION; ALKYL RADICALS; GENERATION; ANNULATION, Saw an article supported by the BMBFFederal Ministry of Education & Research (BMBF) [16GW0202]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Schulz, G; Kirschning, A. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone. Formula: C13H10O

The smooth oxidative radical decarboxylation of carboxylic acids with TEMPO and other derivatives as radical scavengers is reported. The key to success was the use of a two-phase solvent system to avoid otherwise predominant side reactions such as the oxidation of TEMPO by persulfate and enabled the selective formation of synthetically useful alkoxyamines. The method does not require transition metals and was successfully used in a new synthetic approach for the antidepressant indatraline.

Formula: C13H10O. Bye, fridends, I hope you can learn more about C13H10O, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Name: Benzophenone. Authors Dmitrienko, A; Pilkington, M; Nikonov, GI in WILEY-V C H VERLAG GMBH published article about in [Dmitrienko, Anton; Pilkington, Melanie; Nikonov, Georgii I.] Brock Univ, Dept Chem, 1812 Sir Isaac Brock Way, St Catharines, ON L2S 3A1, Canada in 2021.0, Cited 22.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

The Al-I compound NacNacAl (1, NacNac = [ArNC(Me)CHC(Me)NAr](-), Ar = 2,6-iPr(2)C(6)H(3)) serves as a template for the chemoselective coupling between carbonyls (benzophenone, fenchone, isophorone, p-tolyl benzoate, N,N-dimethylbenzamide, (1-phenylethylidene)aniline) and pyridine. With the CH-acidic ketone (1R)-(+) camphor, the reaction affords a hydrido alkoxide compound of Al, formed as the result of enolization, whereas an enolizable imine, (1-phenylethylidene)aniline, and the bulky ketone isophorone, still chemoselectively couple with pyridine. In contrast, reaction with the ester p-tolyl benzoate results in cleavage of the ester bond together with replacement of the alkoxy group by a hydrogen atom of the pyridine moiety. This study demonstrates that for carbonyl substrates featuring phenyl substituents, the reaction proceeds via intermediate formation of eta(2)(C,X)-coordinated (X = O, N) carbonyl adducts, whereas the reaction of 1 with (R)-(-)-fenchone in the absence of pyridine leads to CH activation in the pendant isopropyl group of the Ar substituent of the NacNac ligand.

Welcome to talk about 119-61-9, If you have any questions, you can contact Dmitrienko, A; Pilkington, M; Nikonov, GI or send Email.. Name: Benzophenone

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Authors Wang, H; Qu, JP; Kang, YB in AMER CHEMICAL SOC published article about in [Wang, Hua; Kang, Yan-Biao] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China; [Qu, Jian-Ping] Nanjing Tech Univ, Jiangsu Natl Synerget Innovat Ctr Adv Mat, Sch Chem & Mol Engn, Inst Adv Synth, Nanjing 211816, Peoples R China in 2021.0, Cited 18.0. Safety of Benzophenone. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

A recyclable organic photoreductant (1 mol % CBZ6)-catalyzed reductive (pinacol) coupling of aldehydes, ketones, and imines has been developed. Irradiated by purple light (407 nm) using triethylamine as an electron donor, a variety of 1,2-diols and 1,2-diamines could be prepared. The oxidation potential of the excited state of CBZ6 is established as -1.92 V (vs saturated calomel electrode (SCE)). The relative high reductive potential enables the reductive coupling of carbonyl compounds and their derivatives. CBZ6 can be prepared in gram scale and is acid/base- or air-stable. It could be applied in large-scale photoreductive synthesis and recovered in high yield after the reaction.

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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Quality Control of Benzophenone. In 2021.0 CHEM-EUR J published article about ONE-POT SYNTHESIS; COBALT NANOPARTICLES; PRIMARY AMINES; SELECTIVE HYDROGENATION; AMINATION; CATALYST; CARBON; CO; HYDROAMINATION; ALCOHOLS in [Schoenauer, Timon; Kaiser, Leah; Kempe, Rhett] Univ Bayreuth, Inorgan Chem Catalyst Design 2, D-95440 Bayreuth, Germany; [Thomae, Sabrina L. J.; Zobel, Mirijam] Univ Bayreuth, Dept Chem, Mesostruct Mat, D-95440 Bayreuth, Germany in 2021.0, Cited 45.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9.

The development of C-N bond formation reactions is highly desirable due to their importance in biology and chemistry. Recent progress in 3d metal catalysis is indicative of unique selectivity patterns that may permit solving challenges of chemical synthesis. We report here on a catalytic C-N bond formation reaction-the reductive alkylation of nitriles. Aldehydes or ketones and nitriles, all abundantly available and low-cost starting materials, undergo a reductive coupling to form secondary alkylamines and inexpensive hydrogen is used as the reducing agent. The reaction has a very broad scope and many functional groups, including hydrogenation-sensitive examples, are tolerated. We developed a novel cobalt catalyst, which is nanostructured, reusable, and easy to handle. The key seems the earth-abundant metal in combination with a porous support material, N-doped SiC, synthesized from acrylonitrile and a commercially available polycarbosilane.

Quality Control of Benzophenone. Welcome to talk about 119-61-9, If you have any questions, you can contact Schonauer, T; Thoma, SLJ; Kaiser, L; Zobel, M; Kempe, R or send Email.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem