Category: 104-21-2

HPLC of Formula: C10H12O3. Recently I am researching about ISOCYANIDE INSERTION REACTION; BAYLIS-HILLMAN ADDUCTS; CARBOXYLIC-ACIDS; STEREOSELECTIVE-SYNTHESIS; ONE-POT; COUPLING REACTION; ESTERIFICATION; EFFICIENT; ACCESS; ALDEHYDES, Saw an article supported by the National Key Research and Development Program of China [2017YFB0102900]; State Key Laboratory of Applied Organic Chemistry, Lanzhou UniversityLanzhou University; Natural Science Foundation of ShanghaiNatural Science Foundation of Shanghai [18ZR1413900]; Shanghai Pujiang ProgramShanghai Pujiang Program [17PJD016]. Published in GEORG THIEME VERLAG KG in STUTTGART ,Authors: Chen, YY; Li, CL; Cui, YM; Sun, MM; Jia, XS; Li, J. The CAS is 104-21-2. Through research, I have a further understanding and discovery of 4-Methoxybenzyl acetate

A novel oxidative esterification of 1-arylprop-2-en-1-ols with toluene derivatives catalyzed by tetrabutylammonium iodide (TBAI) is reported. The optimization of the reaction conditions illustrates that each of experiment parameters including the catalyst, solvent, and oxidant is significant for present oxidative functionalization. This metal-free protocol has a broad substrate scope including the halogen groups for further functionalization and enriches the reactivity profile of allyl alcohol and toluene derivatives. In addition, this protocol represents a new transformation of allyl alcohol involving C-C bond cleavage and C-O bond forming.

HPLC of Formula: C10H12O3. About 4-Methoxybenzyl acetate, If you have any questions, you can contact Chen, YY; Li, CL; Cui, YM; Sun, MM; Jia, XS; Li, J or concate me.

Reference:
Thiomorpholine – Wikipedia,
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Authors Ghosh, T; Mohammad, A; Mobin, SM in AMER CHEMICAL SOC published article about PALLADIUM-CATALYZED CYANATION; AEROBIC OXIDATIVE CONVERSION; REDUCTIVE AMINATION; HIGHLY EFFICIENT; ARYL BROMIDES; NITRILES; ALDEHYDES; ACID; NANOPARTICLES; ALCOHOLS in [Ghosh, Topi; Mohammad, Akbar; Mobin, Shaikh M.] Indian Inst Technol Indore, Discipline Chem, Khandwa Rd, Indore 453552, Madhya Pradesh, India; [Mobin, Shaikh M.] Indian Inst Technol Indore, Discipline Met Engn & Mat Sci, Khandwa Rd, Indore 453552, Madhya Pradesh, India; [Mobin, Shaikh M.] Indian Inst Technol Indore, Discipline Biosci & Biomed Engn, Khandwa Rd, Indore 453552, Madhya Pradesh, India in 2019, Cited 91. Recommanded Product: 104-21-2. The Name is 4-Methoxybenzyl acetate. Through research, I have a further understanding and discovery of 104-21-2

Development of a low-cost, environmentally benign and robust catalyst for multipurpose industrially relevant organic transformations is highly desirable for the sustainable future of chemical industries. A hybrid cobalt doped-cerium oxide nanocatalyst (Co@CeO2NC) was prepared via simple coprecipitation method using water as the solvent. The characterization of Co@CeO2NC was performed using different techniques such as XRD, TGA, FE-SEM, HR-TEM, EDAX-mapping, BET, and XPS analysis. The structural characterization of the prepared sample by XRD and XPS analysis revealed the presence of the mixed phase of cobalt oxide and cobalt doped-cerium oxide as a hybrid (Co@CeO2NC). Industrially relevant organic transformations such as (i) nitrile formation using aldehyde with hydroxyl amine hydrochloride, (ii) reductive amination of aldehydes to form tertiary N,N-dimethyl amines, and (iii) direct acetylation of alcohols/amines with acetic acid were achieved in an excellent manner using Co@CeO2NC hybrid as the multifunctional catalyst. Excellent catalytic activity of Co@CeO2NC was noticed for the conversion of 4-chlorobenzaldehyde to 4-chlorobenzonitrile with 99% conversion and 99% selectivity and 100% conversion of benzaldehyde to N,N-dimethylbenzylamine using DMF as NMe2 source, reductant, and solvent. Moreover, acetylation of 4-methoxybenzyl alcohol and 2-methyl aniline gave excellent conversion and selectivity toward the formation of -O and -N acetyl. The scope of the Co@CeO2NC was further evaluated for other aldehydes, alcohols, and amines with an excellent conversion and high selectivity.

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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

I found the field of Science & Technology – Other Topics very interesting. Saw the article Acetylation of alcohols, phenols and amines using waste plant extract published in 2020. Name: 4-Methoxybenzyl acetate, Reprint Addresses Chetia, B (corresponding author), Dibrugarh Univ, Dept Chem, Dibrugarh 786004, Assam, India.. The CAS is 104-21-2. Through research, I have a further understanding and discovery of 4-Methoxybenzyl acetate

The acetylation of alcohols, phenols and amines using water extract of waste plant extract of rice straw ash and seed husk of Vigna mungo ash at room temperature is reported here. The easy availability of plants, high yields, mild reaction conditions, cost effectiveness of the catalyst proved to be an excellent and green protocol for the acetylation reaction.

Name: 4-Methoxybenzyl acetate. About 4-Methoxybenzyl acetate, If you have any questions, you can contact Chutia, R; Chetia, B or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Authors Roser, C; Toth, C; Renner, M; Herpel, E; Schirmacher, P in BMC published article about in [Roser, Christoph; Toth, Csaba; Renner, Marcus; Herpel, Esther; Schirmacher, Peter] Heidelberg Univ Hosp, Inst Pathol, Neuenheimer Feld 224, D-69120 Heidelberg, Germany; [Roser, Christoph] Heidelberg Univ Hosp, Dept Orthodont & Dentofacial Orthopaed, Neuenheimer Feld 400, D-69120 Heidelberg, Germany; [Herpel, Esther] Natl Ctr Tumor Dis NCT, Tissue Bank, Neuenheimer Feld 224, D-69120 Heidelberg, Germany; [Toth, Csaba] Trier MVZ Histol Cytol & Mol Diagnost, Max Planck Str 5, D-54296 Trier, Germany in 2021, Cited 53. HPLC of Formula: C10H12O3. The Name is 4-Methoxybenzyl acetate. Through research, I have a further understanding and discovery of 104-21-2

Background: Colorectal familial adenomatous polyposis (FAP) adenomas exhibit a uniform pathogenetic basis caused by a germline mutation in the adenomatous polyposis gene (APC), but the molecular changes leading to their development are incompletely understood. However, dysregulated apoptosis is known to substantially affect the development of colonic adenomas. One of the key regulatory proteins involved in apoptosis is apoptosis repressor with caspase recruitment domain (ARC). Methods: The expression of nuclear and cytoplasmic ARC in 212 adenomas from 80 patients was analyzed by immunohistochemistry. We also compared expression levels of ARC with the expression levels of p53, Bcl-2, COX-2, and MMR proteins. Statistical analyses were performed by Spearman’s rank correlation and linear regression test. Results: ARC was overexpressed in the nuclei and cytoplasm of most FAP adenomas investigated. Cytoplasmic ARC staining was moderately stronger (score 2) in 49.1% (n = 104/212) and substantially stronger (score 3) in 32.5% (n = 69/212) of adenomas compared to non-tumorous colorectal mucosa. In 18.4% (n = 39/212) of adenomas, cytoplasmic ARC staining was equivalent to that in non-tumorous mucosa. Nuclear expression of ARC in over 75% of cells was present in 30.7% (n = 65/212) of investigated adenomas, and nuclear expression in 10-75% of cells was detected in 62.7% (n = 133/212). ARC expression in under 10% of nuclei was found in 6.6% (n = 14/212) of adenomas. The correlation between nuclear ARC expression and cytoplasmic ARC expression was highly significant (p = 0.001). Moreover, nuclear ARC expression correlated positively with overexpression of Bcl-2, COX-2 p53 and beta-catenin. Cytoplasmic ARC also correlated with overexpression of Bcl-2. Sporadic MMR deficiency was detected in very few FAP adenomas and showed no correlation with nuclear or cytoplasmic ARC. Conclusions: Our results demonstrated that both cytoplasmic and nuclear ARC are overexpressed in FAP adenomas, thus in a homogenous collective. The highly significant correlation between nuclear ARC and nuclear beta-catenin suggested that ARC might be regulated by beta-catenin in FAP adenomas. Because of its further correlations with p53, Bcl-2, and COX-2, nuclear ARC might play a substantial role not only in carcinomas but also in precursor lesions.

HPLC of Formula: C10H12O3. About 4-Methoxybenzyl acetate, If you have any questions, you can contact Roser, C; Toth, C; Renner, M; Herpel, E; Schirmacher, P or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

I found the field of General & Internal Medicine; Research & Experimental Medicine very interesting. Saw the article Relation of High Social Capital to Preferable Emotional Response to News Media Broadcasting of Natural Disasters: A Nationwide Cross-Sectional Study in Japan published in 2019. Recommanded Product: 4-Methoxybenzyl acetate, Reprint Addresses Horiuchi, S (corresponding author), Teikyo Univ, Grad Sch Publ Hlth, Itabashi Ku, 2-11-1 Kaga, Tokyo 1738605, Japan.. The CAS is 104-21-2. Through research, I have a further understanding and discovery of 4-Methoxybenzyl acetate

Media coverage of disasters potentially damages mental health. Moreover, its effects may differ as recipients may have different emotional responses toward media. The present study examined whether social capital, known to be protective against mental problems, influences a recipient’s emotional response toward news media broadcasting of natural disasters via newspapers, television and internet in Japan. Three social capital components, social participation, social support and cognitive social capital, were considered in the present study as each component reportedly had different effect on mental health. This nationwide cross-sectional survey was undertaken in 2015 among 1,200 Japanese citizens aged 15 to 79 years who were selected using the multi-stage sampling procedure. Data were collected via the drop-off pick-up method using a printed structured questionnaire. Negative and positive emotions were classified based on recipients’ responses against news media. Among 1,190 participants who reported emotions toward news media, 30.9% (368) had experienced any natural disasters, 37.4% (445) belonged to at least one formal or informal organization (social participation), 40.2% (478) had high social support, and 68.8% (819) had high cognitive social capital. High social support was associated with both reduced negative emotional response (OR 0.66, 95% Confidence Interval (CI) 0.47-0.93) and increased positive emotional response (OR 1.48, 95% CI 1.04-2.12) in multivariate analyses, while high cognitive social capital was only associated with increased positive emotional response (OR 1.62, 95% CI 1.11-2.37). These results suggest protective effects of social support and cognitive social capital against news media coverage of natural disasters.

About 4-Methoxybenzyl acetate, If you have any questions, you can contact Horiuchi, S; Ozaki, A; Inoue, M; Aida, J; Yamaoka, K or concate me.. Recommanded Product: 4-Methoxybenzyl acetate

Reference:
Thiomorpholine – Wikipedia,
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Recently I am researching about LIMITED ENGLISH PROFICIENCY; PATIENT ACTIVATION MEASURE; EMERGENCY-DEPARTMENT USE; HEALTH-CARE SERVICES; CHILDREN; PARENTS; DISPARITIES; OUTCOMES; CONTINUITY; INSURANCE, Saw an article supported by the Gordon and Betty Moore FoundationGordon and Betty Moore Foundation. Recommanded Product: 4-Methoxybenzyl acetate. Published in AMER ACAD PEDIATRICS in ELK GROVE VILLAGE ,Authors: DeCamp, LR; Godage, SK; Araujo, DV; Cortez, JD; Wu, LX; Psoter, KJ; Quintanilla, K; Rodri’guez, TR; Polk, S. The CAS is 104-21-2. Through research, I have a further understanding and discovery of 4-Methoxybenzyl acetate

BACKGROUND AND OBJECTIVES: Latino children in immigrant families experience health care disparities. Text messaging interventions for this population may address disparities. The objective of this study was to evaluate the impact of a Spanish-language text messaging intervention on infant emergency department use and well care and vaccine adherence. METHODS: The Salud al Dia intervention, an educational video and interactive text messages throughout the child’s first year of life, was evaluated via randomized controlled trial conducted in an urban, academic pediatric primary care practice from February 2016 to December 2017. Inclusion criteria were publicly insured singleton infant < 2 months of age; parent age > 18, with Spanish as the preferred health care language; and at least 1 household cellular phone. Primary outcomes were abstracted from the electronic medical record at age 15 months. Intention-to-treat analyses were used. RESULTS: A total of 157 parent-child dyads were randomly assigned to Salud al Dia (n = 79) or control groups (n = 78). Among all participants, mean parent age was 29.3 years (SD: 6.2 years), mean years in the United States was 7.3 (SD: 5.3 years), and 87% of parents had limited or marginal health literacy. The incidence rate ratio for emergency department use for the control versus intervention group was 1.48 (95% confidence interval: 1.04-2.12). A greater proportion of intervention infants received 2 flu vaccine doses compared with controls (81% vs 67%; P = .04). CONCLUSIONS: This Spanish-language text messaging intervention reduced emergency department use and increased flu vaccine receipt among a population at high risk for health care disparities. Tailored text message interventions are a promising method for addressing disparities.

Recommanded Product: 4-Methoxybenzyl acetate. About 4-Methoxybenzyl acetate, If you have any questions, you can contact DeCamp, LR; Godage, SK; Araujo, DV; Cortez, JD; Wu, LX; Psoter, KJ; Quintanilla, K; Rodri’guez, TR; Polk, S or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Effect of meteorological factors on scarlet fever incidence in Guangzhou City, Southern China, 2006-2017 WOS:000459858500022 published article about AIRBORNE BACTERIA; MOUTH-DISEASE; HONG-KONG; EPIDEMIC; IMPACT; AIR; OUTBREAK; HEALTH; KOREA; HAND in [Lu, Jian-yun; Chen, Zong-qiu; Liu, Yan-hui; Liu, Wen-hui; Ma, Yu; Li, Tie-gang] Guangzhou Ctr Dis Control & Prevent, Dept Infect Dis Control & Prevent, Baiyun Dist Qi Rd, Guangzhou 510440, Guangdong, Peoples R China; [Zhang, Zhou-bin; Yang, Zhi-cong] Guangzhou Ctr Dis Control & Prevent, Baiyun Dist Qi Rd, Guangzhou 510440, Guangdong, Peoples R China in 2019, Cited 46. Computed Properties of C10H12O3. The Name is 4-Methoxybenzyl acetate. Through research, I have a further understanding and discovery of 104-21-2

Objective: To explore the relationship between meteorological factors and scarlet fever incidence from 2006 to 2017 in Guangzhou, the largest subtropical city of Southern China, and assist public health prevention and control measures. Methods: Data for weekly scarlet fever incidence and meteorological variables from 2006 to 2017 in Guangzhou were collected from the National Notifiable Disease Report System (NNDRS) and the Guangzhou Meteorological Bureau (GZMB). Distributed lag nonlinear models (DLNMs) were conducted to estimate the effect of meteorological factors on weekly scarlet fever incidence in Guangzhou. Results: We observed nonlinear effects of temperature, relative humidity, and wind velocity. The risk was the highest when the weekly mean temperature was 31 degrees C during lag week 14, yielding a relative risk (RR) of 1.48 (95% CI: 1.01-2.17). When relative humidity was 43.5% during lag week 0, the RR was 1.49 (95% CI: 1.04-2.12); the highest RR (1.55, 95% CI: 1.20-1.99) was reached when relative humidity was 93.5% during lag week 20. When wind velocity was 4.4 m/s during lag week 13, the RR was highest at 3.41 (95% CI: 1.57-7.44). Positive correlations were observed among weekly temperature ranges and atmospheric pressure with scarlet fever incidence, while a negative correlation was detected with aggregate rainfall. The cumulative extreme effect of meteorological variables on scarlet fever incidence was statistically significant, except for the high effect of wind velocity. Conclusion: Weekly mean temperature, relative humidity, and wind velocity had double-trough effects on scarlet fever incidence; high weekly temperature range, high atmospheric pressure, and low aggregate rain fall were risk factors for scarlet fever morbidity. Our findings provided preliminary, but fundamental, information that may be useful for a better understanding of epidemic trends of scarlet fever and for developing an early warning system. Laboratory surveillance for scarlet fever should be strengthened in the future. (C) 2019 Elsevier B.V. All rights reserved.

Computed Properties of C10H12O3. About 4-Methoxybenzyl acetate, If you have any questions, you can contact Lu, JY; Chen, ZQ; Liu, YH; Liu, WH; Ma, Y; Li, TG; Zhang, ZB; Yang, ZC or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Formula: C10H12O3. Chahid, Y; Qiu, XB; van de Garde, EMW; Verberne, HJ; Booij, J in [Chahid, Youssef; Verberne, Hein J.; Booij, Jan] Univ Amsterdam, Amsterdam Univ Med Ctr, Dept Radiol & Nucl Med, Amsterdam, Netherlands; [Chahid, Youssef; Qiu, Xinbo] Univ Amsterdam, Amsterdam Univ Med Ctr, Dept Clin Pharm, Amsterdam, Netherlands; [van de Garde, Ewoudt M. W.] St Antonius Hosp, Dept Clin Pharm, Utrecht, Netherlands; [van de Garde, Ewoudt M. W.] Univ Utrecht, Dept Pharmaceut Sci, Div Pharmacoepidemiol & Clin Pharmacol, Utrecht, Netherlands published Risk factors for nonvisualization of the sentinel lymph node on lymphoscintigraphy in breast cancer patients in 2021, Cited 17. The Name is 4-Methoxybenzyl acetate. Through research, I have a further understanding and discovery of 104-21-2.

Background Accurate sentinel lymph node (SLN) staging is essential for both prognosis and treatment in patients with breast cancer. However, the preoperative lymphoscintigraphy may fail to visualize the SLN in some patients. The purpose of this retrospective study was to identify risk factors associated with SLN nonvisualization on lymphoscintigraphy. For this single-center retrospective study, all data of lymphoscintigraphy of SLN procedures from March 2011 to April 2021 were collected and reviewed from the Amsterdam UMC database. Results A total of 1886 SLN procedures were included in this study. The SLN nonvisualization rate was 25.1% on lymphoscintigraphy at 4 h post-injection. The SLN nonvisualization rate decreased to 9.4% after reinjection. Multivariable analysis showed that age >= 70 years (P < 0.001; OR: 2.27; 95% CI: 1.46-3.53), BMI >= 30 kg/m(2) (P = 0.031; OR: 1.48; 95% CI: 1.04-2.12) and nonpalpable tumors (P = 0.004; OR: 1.54; 95% CI: 1.15-2.07) were independent predictors of SLN nonvisualization. Tumor location, brand of radiopharmaceutical, injected dose and volume, experience of preparer and administrator were not associated with SLN nonvisualization. None of the patient, tumor or tracer characteristics were associated with SLN nonvisualization after radiotracer reinjection. Conclusions This study shows that risk factors for SLN nonvisualization in breast cancer patients during preoperative lymphoscintigraphy are age >= 70 years, BMI >= 30 kg/m(2) and nonpalpable tumors. Our results support the notion that SLN lymphoscintigraphy is a very robust technique that does not depend on the experience of the preparer or administrator of the radiotracer.

Formula: C10H12O3. About 4-Methoxybenzyl acetate, If you have any questions, you can contact Chahid, Y; Qiu, XB; van de Garde, EMW; Verberne, HJ; Booij, J or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Regio- and Chemoselective Deprotection of Primary Acetates by Zirconium Hydrides WOS:000464247500003 published article about IN-SITU GENERATION; ALKYLALUMINUM HYDRIDE; TERTIARY AMIDES; ONE-POT; REDUCTION; DEACETYLATION; CP2ZR(H)CL; ALDEHYDES; HYDROZIRCONATION; CYCLODEXTRINS in [Gavel, Marine; Courant, Thibaut; Joosten, Antoine Yvan Philippe; Lecourt, Thomas] Normandie Univ, INSA Rouen, CNRS, UMR 6014,COBRA,UNIROUEN, F-76000 Rouen, France in 2019, Cited 47. Recommanded Product: 4-Methoxybenzyl acetate. The Name is 4-Methoxybenzyl acetate. Through research, I have a further understanding and discovery of 104-21-2

A combination of DIBAL-H and Cp2ZrCl2 is shown to promote the regioselective cleavage of primary acetates on a broad scope of substrates, ranging from carbohydrates to terpene derivatives, with a high tolerance toward protecting groups and numerous functionalities found in natural products and bioactive compounds. Apart from providing highly valuable building blocks in only two steps from biosourced raw materials, this selective de-O-acetylation should also be strongly helpful to solve selectivity issues in organic synthesis.

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Reference:
Thiomorpholine – Wikipedia,
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Lam, YP; Wang, XY; Tan, F; Ng, WH; Tse, YLS; Yeung, YY in [Lam, Ying-Pong; Wang, Xinyan; Tan, Fei; Ng, Wing-Hin; Tse, Ying-Lung Steve; Yeung, Ying-Yeung] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China published Amide/Iminium Zwitterionic Catalysts for (Trans)esterification: Application in Biodiesel Synthesis in 2019, Cited 70. COA of Formula: C10H12O3. The Name is 4-Methoxybenzyl acetate. Through research, I have a further understanding and discovery of 104-21-2.

A class of zwitterionic organocatalysts based on an amide anion/iminium cation charge pair has been developed. The zwitterions are easily prepared by reacting aziridines with aminopyridines. They are catalytically applicable to transesterifications and dehydrative esterifications. Mechanistic studies reveal that the amide anion and iminium cation work synergistically in activating the reaction partners, with the iminium cationic moiety interacting with the carbonyl substrates through nonclassical hydrogen bonding. The reaction can be applied to large-scale synthesis of biodiesel under mild conditions.

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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem