In 2021.0 ORGANOMETALLICS published article about HOMOLEPTIC LANTHANIDE COMPLEXES; STRUCTURAL-CHARACTERIZATION; METAL COMPLEXES; PRECURSORS; REACTIVITY; CHEMISTRY; CATALYSTS; CRYSTAL; AMIDES; SCANDIUM(III) in [Boteju, Kasuni C.; Venkatesh, Amrit; Wan, Suchen; Rossini, Aaron J.; Sadow, Aaron D.] Iowa State Univ, US DOE, Ames Lab, Ames, IA 50011 USA; [Boteju, Kasuni C.; Venkatesh, Amrit; Chu, Yang-Yun; Ellern, Arkady; Rossini, Aaron J.; Sadow, Aaron D.] Iowa State Univ, Dept Chem, Ames, IA 50011 USA in 2021.0, Cited 54.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9. HPLC of Formula: C13H10O
Three new hydridosilazido ligands, -N(SiHMe2)Aryl (Aryl = Ph, 2,6-C6Me2H3 (dmp), 2,6-C(6)iPr(2)H(3) (dipp)) and their rare-earth complexes Ln{N(SiHMe2)Aryl}(3)(THF)(n) (Ln = Sc, Y, Lu; Aryl = Ph, n = 2; Aryl = dmp, n = 1; Aryl = dipp, n = 0) were synthesized to study the relationships among ligand steric properties, secondary Ln <- H-Si bonding, and the reactivity of amide and SiH groups. In these compounds, the steric encumbrance of the aryl group was systematically increased from phenyl to 2,6-dimethylphenyl to 2,6-diisopropylphenyl. NMR, IR, and X-ray diffraction studies of the complexes characterize the number of secondary interactions and additional THF ligands coordinated to the rare-earth centers. The complexes with the smallest phenylsilazido ligands, Ln{N(SiHMe2)PH}(3)(THF)(2), contain features associated with three nonbridging 2-center-2-electron (2c-2e) Si-H bonds. Characterization of intermediate-sized Ln{N(SiHMe2)dmp}(3)THF reveals three and two Li <- H-Si interactions for yttrium and lutetium analogues, respectively, with both metals having one coordinated THF per complex Ln{N(SiHMe2)dipp}(3) is formed solvent-free, and all three ligands adopt Li <- H-Si bonding modes. The reaction between Ln{N(SiHMe2)dipp}(3) and ketones provides the hydrosilylated product via addition of C=O and Si-H bonds, which occurs rapidly even at low temperature. This reaction is proposed to occur through an associative mechanism on the basis of negative activation entropy measured for substitution of pyridine in Ln{N(SiHMe2)dipp}(3)center dot NC5H5. Bye, fridends, I hope you can learn more about C13H10O, If you have any questions, you can browse other blog as well. See you lster.. HPLC of Formula: C13H10O
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem