Recommanded Product: 119-61-9. Recently I am researching about N-HETEROCYCLIC CARBENE; C-C; BORROWING HYDROGEN; CLEAVAGE; KETONES; OLEFIN; FUNCTIONALIZATION; METATHESIS; ALDEHYDES; INSERTION, Saw an article supported by the European Research Council (ERC)European Research Council (ERC)European Commission [757608]; Swiss National Science Foundation (SNF)Swiss National Science Foundation (SNSF) [184658]; ETH ZurichETH Zurich; German Academic Scholarship Foundation. Published in CELL PRESS in CAMBRIDGE ,Authors: Lutz, MDR; Gasser, VCM; Morandi, B. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone
The advent of transfer hydrogenation and borrowing hydrogen reactions paved the way to manipulate simple alcohols in previously unthinkable manners and circumvented the need for hydrogen gas. Analogously, transfer hydrocarbylation could greatly increase the versatility of tertiary alcohols. However, this reaction remains unexplored because of the challenges associated with the catalytic cleavage of unactivated C-C bonds. Herein, we report a rhodium(I)-catalyzed shuttle arylation cleaving the C(sp(2))-C(sp(3)) bond in unstrained triaryl alcohols via a redox-neutral beta-carbon elimination mechanism. A selective transfer hydrocarbylation of substituted (hetero)aryl groups from tertiary alcohols to ketones was realized, employing benign alcohols as latent C-nucleophiles. All preliminary mechanistic experiments support a reversible b-carbon elimination/migratory insertion mechanism. In a broader context, this novel reactivity offers a new platform for the manipulation of tertiary alcohols in catalysis.
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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem