HPLC of Formula: C13H10O. I found the field of Chemistry very interesting. Saw the article Nucleophilic reactivity of the gold atom in a diarylborylgold(i) complex toward polar multiple bonds published in 2021.0, Reprint Addresses Yamashita, M (corresponding author), Nagoya Univ, Grad Sch Engn, Dept Mol & Macromol Chem, Chikusa Ku, Nagoya, Aichi 4648603, Japan.; Lin, ZY (corresponding author), Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Clear Water Bay, Hong Kong, Peoples R China.. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone.
A di(o-tolyl)borylgold complex was synthesized via the metathesis reaction of a gold alkoxide with tetra(o-tolyl)diborane(4). The resulting diarylborylgold complex exhibited a Lewis acidic boron center and a characteristic visible absorption that arises from its HOMO-LUMO excitation, which is narrower than that of a previously reported dioxyborylgold complex. The diarylborylgold complex reacted with isocyanide in a stepwise fashion to afford single- and double-insertion products and a C-C coupled product. Reactions of this diarylborylgold complex with C = O/N double bond species furnished addition products under concomitant formation of Au-C and B-O/N bonds, which suggests nucleophilic reactivity of the gold metal center. DFT calculations provided details of the underlying reaction mechanism, which involves an initial coordination of the C = O/N bond to the boron vacant p-orbital of the diarylboryl ligand followed by a migration of the gold atom from the tetracoordinate sp(3)-hybridized boron center, which is analogous to the reactivity of the conventional sp(3)-hybridized borate species. The DFT calculations also suggested a stepwise mechanism for the reaction of this diarylborylgold complex with isocyanide, which afforded three different reaction products depending on the applied reaction conditions.
HPLC of Formula: C13H10O. Bye, fridends, I hope you can learn more about C13H10O, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem