Ma, WP; Liu, LC; An, K; He, T; He, W in [Ma, Wenpeng; Liu, Li-Chuan; An, Kun; He, Tao; He, Wei] Tsinghua Univ, MOE Key Lab Bioorgan Phosphorus Chem & Chem Biol, Beijing 100084, Peoples R China; [Ma, Wenpeng; Liu, Li-Chuan; An, Kun; He, Tao; He, Wei] Tsinghua Univ, Sch Pharmaceut Sci, Beijing 100084, Peoples R China; [Ma, Wenpeng; Liu, Li-Chuan; An, Kun; He, Tao; He, Wei] Tsinghua Univ, Tsinghua Peking Joint Ctr Life Sci, Beijing 100084, Peoples R China published Rhodium-Catalyzed Synthesis of Chiral Monohydrosilanes by Intramolecular C-H Functionalization of Dihydrosilanes in 2021.0, Cited 76.0. Name: Benzophenone. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9.
The preparation of chiral monohydrosilanes remains a rarely achieved goal. To this end a Rh-catalyzed desymmetrization of dihydrosilanes by way of intramolecular C(sp(2))-H functionalization under simple and mild conditions has now been developed. This method provides easy access to a broad range of chiral monohydrosilanes in good yields with excellent enantioselectivities (up to >99 % ee). The resulting monohydrosilanes constitute a good platform to access stereogenic silicon compounds, as well as useful compounds to probe silicon stereochemistry.
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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem