I found the field of Chemistry very interesting. Saw the article Anodic oxidation triggered divergent 1,2-and 1,4-group transfer reactions of beta-hydroxycarboxylic acids enabled by electrochemical regulation published in 2020. COA of Formula: C14H10O, Reprint Addresses Mo, FY (corresponding author), Peking Univ, Coll Engn, Dept Energy & Resources Engn, Beijing 100871, Peoples R China.; Mo, FY (corresponding author), Jiangsu Donghai Silicon Ind S&T Innovat Ctr, Donghai 222300, Jiangsu, Peoples R China.. The CAS is 90-44-8. Through research, I have a further understanding and discovery of Anthrone
We report a set of electrochemically regulated protocols for the divergent synthesis of ketones and beta-keto esters from the same beta-hydroxycarboxylic acid starting materials. Enabled by electrochemical control, the anodic oxidation of carboxylic acids proceeded in either a one-electron or a two-electron pathway, leading to a 1,4-aryl transfer or a semipinacol-type 1,2-group transfer product with excellent chemoselectivity. The 1,4-aryl transfer represents an unprecedented example of carbon-to-oxygen group transfer proceeding via a radical mechanism. In contrast to previously reported radical group transfer reactions, this 1,4-group transfer process features the migration of electron-rich aryl substituents. Furthermore, with these chemoselective electrochemical oxidation protocols, a range of ketones and beta-keto esters including those possessing a challenging-to-access medium-sized ring could be synthesized in excellent yields.
COA of Formula: C14H10O. Welcome to talk about 90-44-8, If you have any questions, you can contact Zhang, ZX; Zhang, L; Zhang, XH; Yang, JX; Yin, YX; Jiang, YY; Zeng, CC; Lu, G; Yang, Y; Mo, FY or send Email.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem