An article Domino Processes of Arynes Reacting with Three Classes of Nucleophiles for Organic Syntheses WOS:000604339500001 published article about CARBONYL-COMPOUNDS; ASYMMETRIC-SYNTHESIS; EPOXIDATION; MILD; BENZYNE; 1,2-DIHYDROQUINOLINES; DERIVATIVES; ALDEHYDES; EPOXIDES; ACCESS in [Hwu, Jih Ru; Panja, Avijit; Gupta, Nitesh K.; Tan, Kui-Thong; Lin, Chun-Cheng; Hwang, Kuo-Chu; Huang, Wen-Chieh; Tsay, Shwu-Chen] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan; [Hwu, Jih Ru; Panja, Avijit; Gupta, Nitesh K.; Tan, Kui-Thong; Lin, Chun-Cheng; Hwang, Kuo-Chu; Huang, Wen-Chieh; Tsay, Shwu-Chen] Natl Tsing Hua Univ, Frontier Res Ctr Fundamental & Appl Sci Matters, Hsinchu 30013, Taiwan; [Hu, Yu-Chen] Natl Tsing Hua Univ, Dept Chem Engn, Hsinchu 30013, Taiwan; [Hsu, Ming-Hua] Natl Changhua Univ Educ, Dept Chem, Changhua 50007, Changhua, Taiwan in 2021.0, Cited 60.0. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6. COA of Formula: C7H5NO3
Synthetic application of arynes is broadened by their reactions with neutral N-, S-, and O-containing nucleophiles to produce three types of compounds. Accordingly, 1,2-dihydroquinolines are synthesized from Schiff bases, alkynes, and arynes through a Diels-Alder reaction. Epoxides are prepared from thioethers and arynes along with aldehydes or ketones through a Johnson-Corey-Chaykovsky reaction. Phenolic ethers are produced from allyl ethers and arynes through a Claisen-type rearrangement. These target molecules, including natural products gamma-asarone, asaricin, and a cholesteryl phenolic ether, are formed through reactions initiated by arynes. These new reactions share a prevailing feature of domino processes, which are carried out in a single flask and afford the desired products in good to high yields.
About 3-Nitrobenzaldehyde, If you have any questions, you can contact Hwu, JR; Panja, A; Gupta, NK; Hu, YC; Tan, KT; Lin, CC; Hwang, KC; Hsu, MH; Huang, WC; Tsay, SC or concate me.. COA of Formula: C7H5NO3
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem