Day: October 18, 2021

An article Microwave-Assisted Green Synthesis of 2,3-Dihydroquinazolinones under Base- and Catalyst-Free conditions WOS:000656866400005 published article about ONE-POT SYNTHESIS; HIGHLY ENANTIOSELECTIVE SYNTHESIS; INTRAMOLECULAR AMIDATION; FACILE SYNTHESIS; EFFICIENT; QUINAZOLINONES; MILD; NANOPARTICLES; DERIVATIVES; WATER in [Kerdphon, Sutthichat; Channei, Duangdao] Naresuan Univ, Dept Chem, Fac Sci, Phitsanulok 65000, Thailand; [Jongcharoenkamol, Jira] Naresuan Univ, Fac Pharmaceut Sci, Dept Pharmaceut Chem & Pharmacognosy, Phitsanulok 65000, Thailand; [Chatwichien, Jaruwan] Chulabhorn Royal Acad, Chulabhorn Grad Inst, Program Chem Sci, Bangkok 10210, Thailand; [Singh, Thishana] Univ Kwazulu Natal, Sch Chem & Phys, Private Bag X54001, ZA-4000 Durban, South Africa; [Choommongkol, Vachira] Maejo Univ, Dept Chem, Fac Sci, Chiang Mai 50290, Thailand; [Rithchumpon, Puracheth; Meepowpan, Puttinan] Chiang Mai Univ, Dept Chem, Fac Sci, Chiang Mai 50200, Thailand; [Rithchumpon, Puracheth; Meepowpan, Puttinan] Chiang Mai Univ, Grad Sch, Chiang Mai 50200, Thailand; [Meepowpan, Puttinan] Chiang Mai Univ, Ctr Excellence Mat Sci & Technol, Chiang Mai 50200, Thailand in 2021, Cited 47. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6. Recommanded Product: 2-Aminobenzamide

A facile and green one-pot synthesis of 2,3-dihydroquinazolinones, using microwave irradiation, has been developed. Dihydroquinazolinones were synthesized from 2-aminobenzamide derivatives and various aldehydes in aqueous solution under base and catalyst free reaction conditions. The desired products, from aliphatic and aromatic aldehydes substrates, were obtained in 5 minutes with up to 99 % isolated yields.

Recommanded Product: 2-Aminobenzamide. About 2-Aminobenzamide, If you have any questions, you can contact Kerdphon, S; Jongcharoenkamol, J; Chatwichien, J; Singh, T; Channei, D; Choommongkol, V; Rithchumpon, P; Meepowpan, P or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Copper-Catalyzed One-Pot Synthesis of 2,3-Dihydroquinazolin-4(1 H )-ones from 2-Nitrobenzonitriles and Carbonyl Compounds Mediated by Diboronic Acid in Methanol-Water WOS:000509900900013 published article about AROMATIC O-AMINONITRILE; GREEN SYNTHESIS; COMBINATORIAL SYNTHESIS; COORDINATION POLYMER; FACILE SYNTHESIS; AQUEOUS-MEDIA; QUINAZOLINONES; DERIVATIVES; ALDEHYDES; EFFICIENT in [Liu, Qixing; Sui, Yuebo; Zhang, Yin; Zhang, Kaili; Chen, Yongsheng; Zhou, Haifeng] China Three Gorges Univ, Coll Biol & Pharmaceut Sci, Res Ctr Green Pharmaceut Technol & Proc, Hubei Key Lab Nat Prod Res & Dev, Yichang 443002, Peoples R China in 2020, Cited 50. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6. Quality Control of 2-Aminobenzamide

A copper-catalyzed one-pot synthesis of 2,3-dihydroquinazolin-4(1 H )-ones with diboronic acid as a reductant in an aqueous medium is described. Various 2,3-dihydroquinazolin-4(1 H )-ones were prepared with good functional-group tolerance in good yields under mild conditions from readily available 2-nitrobenzonitriles and various carbonyl compounds.

About 2-Aminobenzamide, If you have any questions, you can contact Liu, QX; Sui, YB; Zhang, Y; Zhang, KL; Chen, YS; Zhou, HF or concate me.. Quality Control of 2-Aminobenzamide

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Simple practical method for synthesis of trisubstituted imidazoles: an efficient copper catalyzed multicomponent reaction WOS:000667711300005 published article about LACTIM-LACTAM TAUTOMERISM; PHOTOPHYSICAL PROPERTIES; SUBSTITUTED IMIDAZOLES; SPECTROSCOPIC APPROACH; ANTIFUNGAL AGENTS; IONIC LIQUIDS; GREEN; OXIDATION; HYDROGEN; SYSTEM in [Kadu, Vikas D.; Mali, Ganesh A.; Khadul, Siddheshwar P.; Kothe, Gokul J.] Punyashlok Ahilyadevi Holkar Solapur Univ, Sch Chem Sci, Solapur 413255, Maharashtra, India in 2021.0, Cited 59.0. Category: thiomorpholine. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6

A rapid practical process has been developed for synthesis of 2,4,5-trisubstituted-imidazoles in excellent yields up to 95% from readily available starting materials. In this CuI catalyzed synthesis, trisubstituted imidazoles were afforded in short reaction times, wherein the substrate scope is well explored with benzoin as well as benzil reacting with different aldehydes in the presence of ammonium acetate as the nitrogen source.

Category: thiomorpholine. About 3-Nitrobenzaldehyde, If you have any questions, you can contact Kadu, VD; Mali, GA; Khadul, SP; Kothe, GJ or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Nano-pistachio hull-OSO3H: synthesis, characterization and application as an effective and novel nanocatalyst for one-pot synthesis of dihydropyrano [3, 2-b] chromene dione derivatives WOS:000606344100001 published article about CATALYST; GREEN; NANOCOMPOSITE; NANOPARTICLES; EFFICIENT; DESIGN; SHELL in [Kamali-Gharamaleki, Maryam; Rouhani, Morteza; Mirjafary, Zohreh] Islamic Azad Univ, Dept Chem, Sci & Res Branch, Tehran, Iran; [Sadeghi, Bahareh] Islamic Azad Univ, Yazd Branch, Dept Chem, Yazd, Iran in 2021, Cited 34. Category: thiomorpholine. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6

In this work, the novel pistachio hull-OSO3H catalyst was synthesized via preparing pistachio hull as a support followed by treatment with chlorosulfonic acid (ClSO3H) and identified by Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy (FE-SEM), X-ray diffraction spectroscopy (EDX), Thermogravimetric analysis (TG) and X-ray powder diffraction (XRD). The size of the pistachio hull-OSO3H nanocatalyst was shown by a scanning electron microscope below 100 nm. The catalytic activity of the solid acid catalyst has been successfully examined in a one-pot, three-component condensation reaction of aromatic aldehydes, dimedone and kojic acid under solvent-free condition to furnish dihydropyrano [3,2-b] chromen dione derivatives. The proposed approach has some advantages as excellent yields, mild reaction conditions, short reaction times, use of agricultural waste and eco-friendly nature.

Category: thiomorpholine. About 3-Nitrobenzaldehyde, If you have any questions, you can contact Kamali-Gharamaleki, M; Sadeghi, B; Rouhani, M; Mirjafary, Z or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Authors Xie, ZB; Li, HX; Liu, LS; Lan, J; Hu, ZY; Le, ZG in SCIENCE PRESS published article about ONE-POT SYNTHESIS; ENZYME; 2,3-DIHYDROQUINAZOLIN-4(1H)-ONES; EFFICIENT; NANOCATALYST; PROMISCUITY; ACYLASE; MILD in [Xie, Zongbo; Li, Hongxia; Liu, Liansheng; Lan, Jin; Hu, Zhiyu; Le, Zhanggao] East China Univ Technol, Dept Appl Chem, Nanchang 330013, Jiangxi, Peoples R China in 2019, Cited 41. Product Details of 88-68-6. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6

Alkaline protease-catalyzed synthesis of quinazolinone derivatives was developed between beta-keotester and o-aminobenzamide. Because ethanol is one kind of eco-friendly solvents, this method can reduce the impact of solvents on the environment. Alkaline protease as a biocatalyst has many advantages, e.g. high catalytic activity, environmentally friendly, wide variety of sources and simple operation. In addition, a variety of quinazolinone derivatives was obtained with good to excellent yields just using 2000 U alkaline protease as catalyst.

Product Details of 88-68-6. About 2-Aminobenzamide, If you have any questions, you can contact Xie, ZB; Li, HX; Liu, LS; Lan, J; Hu, ZY; Le, ZG or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Formula: C14H10O. In 2021 ORG LETT published article about REACTIVITY in [Ueno, Keisuke; Nishii, Yuji; Miura, Masahiro] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan in 2021, Cited 46. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8.

Herein, we disclose a unique directing effect of 9-substituted triptycenes in electrophilic substitution to achieve the regioselective functionalization of the triptycene core. The Hirshfeld population analysis was adopted to predict the selectivity in electrophilic substitution. TMS and t-Bu groups were found to considerably accelerate the reaction at C2 positions to produce C3symmetric isomers. Correlation between distortion and charge distribution within benzene rings was systematically examined.

Formula: C14H10O. About Anthrone, If you have any questions, you can contact Ueno, K; Nishii, Y; Miura, M or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article HFIP-mediated 2-aza-Cope rearrangement: metal-free synthesis of alpha-substituted homoallylamines at ambient temperature WOS:000640673100001 published article about FLUORINATED ALCOHOLS in [Gadde, Karthik; Maes, Bert U. W.; Abbaspour Tehrani, Kourosch] Univ Antwerp, Dept Chem, Groenenborgerlaan 171, B-2020 Antwerp, Belgium in 2021.0, Cited 80.0. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6. Application In Synthesis of 3-Nitrobenzaldehyde

An efficient metal-free strategy for the synthesis of alpha-substituted homoallylamine derivatives has been developed via a 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP)-promoted 2-aza-Cope rearrangement of aldimines, generated in situ by condensation of aldehydes with easily accessible 1,1-diphenylhomoallylamines. This reaction provides rapid access to alpha-substituted homoallylamines with excellent functional group tolerance and yields. The reaction takes place at room temperature and no chromatographic purification is required for product isolation. The synthetic utility of the current method is further demonstrated by the transformation of the obtained benzophenone ketimines into N-unprotected homoallylamines, an alpha-amino alcohol and an alpha-amino amide.

Application In Synthesis of 3-Nitrobenzaldehyde. About 3-Nitrobenzaldehyde, If you have any questions, you can contact Gadde, K; Maes, BUW; Tehrani, KA or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Recently I am researching about LIMITED ENGLISH PROFICIENCY; PATIENT ACTIVATION MEASURE; EMERGENCY-DEPARTMENT USE; HEALTH-CARE SERVICES; CHILDREN; PARENTS; DISPARITIES; OUTCOMES; CONTINUITY; INSURANCE, Saw an article supported by the Gordon and Betty Moore FoundationGordon and Betty Moore Foundation. Published in AMER ACAD PEDIATRICS in ELK GROVE VILLAGE ,Authors: DeCamp, LR; Godage, SK; Araujo, DV; Cortez, JD; Wu, LX; Psoter, KJ; Quintanilla, K; Rodri’guez, TR; Polk, S. The CAS is 104-21-2. Through research, I have a further understanding and discovery of 4-Methoxybenzyl acetate. Computed Properties of C10H12O3

BACKGROUND AND OBJECTIVES: Latino children in immigrant families experience health care disparities. Text messaging interventions for this population may address disparities. The objective of this study was to evaluate the impact of a Spanish-language text messaging intervention on infant emergency department use and well care and vaccine adherence. METHODS: The Salud al Dia intervention, an educational video and interactive text messages throughout the child’s first year of life, was evaluated via randomized controlled trial conducted in an urban, academic pediatric primary care practice from February 2016 to December 2017. Inclusion criteria were publicly insured singleton infant < 2 months of age; parent age > 18, with Spanish as the preferred health care language; and at least 1 household cellular phone. Primary outcomes were abstracted from the electronic medical record at age 15 months. Intention-to-treat analyses were used. RESULTS: A total of 157 parent-child dyads were randomly assigned to Salud al Dia (n = 79) or control groups (n = 78). Among all participants, mean parent age was 29.3 years (SD: 6.2 years), mean years in the United States was 7.3 (SD: 5.3 years), and 87% of parents had limited or marginal health literacy. The incidence rate ratio for emergency department use for the control versus intervention group was 1.48 (95% confidence interval: 1.04-2.12). A greater proportion of intervention infants received 2 flu vaccine doses compared with controls (81% vs 67%; P = .04). CONCLUSIONS: This Spanish-language text messaging intervention reduced emergency department use and increased flu vaccine receipt among a population at high risk for health care disparities. Tailored text message interventions are a promising method for addressing disparities.

Computed Properties of C10H12O3. About 4-Methoxybenzyl acetate, If you have any questions, you can contact DeCamp, LR; Godage, SK; Araujo, DV; Cortez, JD; Wu, LX; Psoter, KJ; Quintanilla, K; Rodri’guez, TR; Polk, S or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Application In Synthesis of Benzophenone. Recently I am researching about NICKEL PHOSPHIDE; HYDROGEN EVOLUTION; PRIMARY AMINES; DOPED CARBON; CHEMOSELECTIVE HYDROGENATION; SELECTIVE HYDROGENATION; MOLECULAR-HYDROGEN; GENERAL-SYNTHESIS; NANOPARTICLES; EFFICIENT, Saw an article supported by the JSPS KAKENHIMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of ScienceGrants-in-Aid for Scientific Research (KAKENHI) [26105003, 17H03457, 18H01790, 20H02523, 20H05879]; Cooperative Research Program of Institute for Catalysis, Hokkaido University [19A1002, 20B1027]; Nanotechnology Platform Program at Hokkaido University, Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan [A-20-HK-0011]; Nanotechnology Open Facilities in Osaka University, Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan [A-20-OS-0025]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Sheng, M; Fujita, S; Yamaguchi, S; Yamasaki, J; Nakajima, K; Yamazoe, S; Mizugaki, T; Mitsudome, T. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone

The development of metal phosphide catalysts for organic synthesis is still in its early stages. Herein, we report the successful synthesis of single-crystal cobalt phosphide nanorods (Co2P NRs) containing coordinatively unsaturated Co-Co active sites, which serve as a new class of air-stable, highly active, and reusable heterogeneous catalysts for the reductive amination of carbonyl compounds. The Co2P NR catalyst showed high activity for the transformation of a broad range of carbonyl compounds to their corresponding primary amines using an aqueous ammonia solution or ammonium acetate as a green amination reagent at 1 bar of H-2 pressure; these conditions are far milder than previously reported. The air stability and high activity of the Co2P NRs is noteworthy, as conventional Co catalysts are air-sensitive (pyrophorous) and show no activity for this transformation under mild conditions. P-alloying is therefore of considerable importance for nanoengineering air-stable and highly active non-noble-metal catalysts for organic synthesis.

About Benzophenone, If you have any questions, you can contact Sheng, M; Fujita, S; Yamaguchi, S; Yamasaki, J; Nakajima, K; Yamazoe, S; Mizugaki, T; Mitsudome, T or concate me.. Application In Synthesis of Benzophenone

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article T3P mediated intramolecular rearrangement of o-aminobenzamide to o-ureidobenzonitrile using isothiocyanates WOS:000616581600001 published article about PRIMARY AMIDES; UREA; DISCOVERY; DERIVATIVES; INHIBITORS; AMINES; TRANSFORMATION; EFFICIENT; KINASE; MAP in [Shamanth, Sadashivamurthy; Sagar, Kunigal S.; Narayana, Yatheesh; Rangappa, Kanchugarakoppal S.; Kempegowda, Mantelingu] Univ Mysore, DOS Chem, Manasagangotri, Mysuru 570006, Karnataka, India; [Nagarakere, Sandhya C.] St Philomenas Coll, PG Dept Studies Chem, Mysuru, India; [Nagarakere, Sandhya C.] St Philomenas Coll, Res Ctr, Mysuru, India; [Mamatha, Mahesha] SRSMN Govt First Grade Coll, Barkur, India in 2021, Cited 38. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6. Name: 2-Aminobenzamide

Current work describes the environmentally benign approach for the synthesis of o-ureidobenzonitriles, from o-aminobenzamides and isothiocyanates using T3P. Here, the conversion of thiourea to urea and amide to nitrile take place simultaneously via unprecedented intramolecular rearrangement. This protocol is operationally facile and offers wide variety of o-ureidobenzonitriles at room temperature in good to excellent yields.

Name: 2-Aminobenzamide. About 2-Aminobenzamide, If you have any questions, you can contact Shamanth, S; Nagarakere, SC; Sagar, KS; Narayana, Y; Mamatha, M; Rangappa, KS; Kempegowda, M or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem