Day: October 18, 2021

Formula: C7H8N2O. In 2020.0 EUR J ORG CHEM published article about CALCIUM-CHANNEL BLOCKERS; HETEROCYCLIC CARBENE; KINETIC RESOLUTION; STEREOSELECTIVE-SYNTHESIS; COOPERATIVE CATALYSIS; ASYMMETRIC-SYNTHESIS; REDOX AMIDATIONS; ACID-ESTERS; ALDEHYDES; POTENT in [Brandolese, Arianna; Ragno, Daniele; Leonardi, Costanza; Bortolini, Olga; De Risi, Carmela; Massi, Alessandro] Univ Ferrara, Dept Chem & Pharmaceut Sci, Via L Borsari 46, I-44121 Ferrara, Italy; [Di Carmine, Graziano] Univ Manchester, Sch Chem Engn & Analyt Sci, Sackville St, Manchester M13 9PL, Lancs, England in 2020.0, Cited 92.0. The Name is 1-Phenylurea. Through research, I have a further understanding and discovery of 64-10-8.

The oxidative N-acylation reaction of 3,4-dihydropyrimidin-2-(1H)-ones (DHPMs) with enals and N-heterocyclic carbene (NHC) catalysts is described. The reaction proceeds in the presence of quinone oxidant without additional acyl transfer agents and in the asymmetric variant produces pharmaceutically relevant N3-acylated products with good-to-moderate enantioselectivity.

About 1-Phenylurea, If you have any questions, you can contact Brandolese, A; Ragno, D; Leonardi, C; Di Carmine, G; Bortolini, O; De Risi, C; Massi, A or concate me.. Formula: C7H8N2O

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Sun, ZZ; Jiang, YB; Zeng, L; Huang, LM in [Sun, Zongzhao] Harbin Inst Technol, Sch Chem & Chem Engn, Harbin 150001, Heilongjiang, Peoples R China; [Sun, Zongzhao; Jiang, Yabin; Zeng, Lei; Huang, Limin] Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China published Intramolecular Charge Transfer and Extended Conjugate Effects in Donor–Acceptor-Type Mesoporous Carbon Nitride for Photocatalytic Hydrogen Evolution in 2019.0, Cited 80.0. Application In Synthesis of 1-Phenylurea. The Name is 1-Phenylurea. Through research, I have a further understanding and discovery of 64-10-8.

Inspired by donor-acceptor (D-A) polymers in organic solar cell and the extended conjugation effect, a conceptual design of D–A-type mesoporous carbon nitride with benzene or thiophene as a -spacer is proposed as an efficient photocatalyst for hydrogen evolution. The photocatalyst was successfully synthesized by a one-pot thermopolymerization based on nucleophilic substitution and a Schiff-base chemical reaction. On the molecular level, the insertion of an in-plane benzene as a -spacer by forming covalent bonds C=N (acceptor) and C-N (donor) interrupts the continuity of tri-s-triazine units and maintains the intrinsic – conjugated electronic system. Synchronously, the enlarged electron delocalization and the intramolecular charge transfer induced by polarization provide force-directed migration of electrons, leading to boosted optical absorption capability and enhanced photogenerated carrier separation. With the synergistic effects of the mesoporous structure and excellent optical and electronic properties, a fivefold increase in the H-2 evolution rate compared with that of pristine g-C3N4 was achieved with robust performance. In addition, other simple aromatic heterocyclic compounds (e.g., pyridine, thiophene and furan)-based D–A structures with a higher hydrogen evolution rate (up to sevenfold increase) were also explored to broaden the application for the design of novel photocatalysts.

Application In Synthesis of 1-Phenylurea. About 1-Phenylurea, If you have any questions, you can contact Sun, ZZ; Jiang, YB; Zeng, L; Huang, LM or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Synthesis and antitumor activities of novel bis-quinazolin-4(3H)-ones WOS:000505757300001 published article about BREAST-CANCER; DERIVATIVES; QUINAZOLINONES; 2-AMINOBENZAMIDES in [Rahmannejadi, Nasrin] Islamic Azad Univ, Dept Chem Sci, Tehran, Iran; [Rahmannejadi, Nasrin] Islamic Azad Univ, Res Branch, Tehran, Iran; [Yavari, Issa] Tarbiat Modares Univ, Dept Chem, POB 14115-175, Tehran, Iran; [Khabnadideh, Soghra] Shiraz Univ Med Sci, Pharmaceut Sci Res Ctr, Shiraz, Iran in 2020, Cited 28. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6. Category: thiomorpholine

With the aim of obtaining new antitumor agents, a series of bis-quinazolin-4(3H)-ones (3a-3 f) were designed and synthesized. These products contain 4-oxo-1,2,3,4-tetrahydro-quinazoline and 3H-quinazolin-4-one moieties linked together via a propyl chain. Cytotoxic activities of 3a-3 f were evaluated against lung adenocarcinoma (A549), breast carcinoma (MCF-7) and ovarian cancer (SKOV3) cell lines using MTT method. Cisplatin was used as a positive control. Among the tested compounds 3a, 3b, and 3e showed the best cytotoxic activities against all cancerous cell lines with IC50 values even less than cisplatin. Compounds 3d and 3f also showed desirable cytotoxic activities especially against A549 and MCF-7.

Category: thiomorpholine. About 2-Aminobenzamide, If you have any questions, you can contact Rahmannejadi, N; Yavari, I; Khabnadideh, S or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

In 2021.0 RSC ADV published article about AGGREGATION-INDUCED EMISSION; OPTICAL WAVE-GUIDE; RATIONAL DESIGN; SINGLE-CRYSTAL; TEMPERATURE; TETRAPHENYLETHYLENE; PHOTOLUMINESCENCE; FLUORESCENCE; CARBAZOLE; HYDROGEL in [Xu, Zixuan; Chen, Xiaofen; Yang, Ying] Lanzhou Univ, Coll Chem & Chem Engn, Key Lab Nonferrous Met Chem & Resources Utilizat, Lanzhou 730000, Gansu, Peoples R China; [Su, Linhan] 940th Hosp Joint Logist Support Force Chinese PLA, Lanzhou 730050, Gansu, Peoples R China in 2021.0, Cited 34.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9. Name: Benzophenone

A novel ionic liquid [TPE-Dim-DMe] (Br)(2) was successfully synthesiszed. With the change of temperature, quadruple transformations of structure were observed in the [TPE-Dim-DMe] (Br)(2) crystal, and it simultaneously displayed mechanochromic phenomena. In addition, its excellent solubility in water makes it a novel bioimaging agent.

Name: Benzophenone. About Benzophenone, If you have any questions, you can contact Xu, ZX; Su, LN; Chen, XF; Yang, Y or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Safety of 4-Methoxybenzyl acetate. In 2020 SN APPL SCI published article about HIGHLY EFFICIENT CATALYST; ACETIC-ANHYDRIDE; HETEROGENEOUS CATALYST; VERSATILE CATALYST; RAPID ACETYLATION; N-ACETYLATION; RICE STRAW; SOLVENT; THIOLS; ACYLATION in [Chutia, Rituparna; Chetia, Bolin] Dibrugarh Univ, Dept Chem, Dibrugarh 786004, Assam, India in 2020, Cited 44. The Name is 4-Methoxybenzyl acetate. Through research, I have a further understanding and discovery of 104-21-2.

The acetylation of alcohols, phenols and amines using water extract of waste plant extract of rice straw ash and seed husk of Vigna mungo ash at room temperature is reported here. The easy availability of plants, high yields, mild reaction conditions, cost effectiveness of the catalyst proved to be an excellent and green protocol for the acetylation reaction.

Safety of 4-Methoxybenzyl acetate. About 4-Methoxybenzyl acetate, If you have any questions, you can contact Chutia, R; Chetia, B or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article ompg-C3N4/SO3H: an efficient and recyclable organocatalyst for the facile synthesis of 2,3-dihydroquinazolin-4(1H)-ones WOS:000486518900019 published article about ACIDIC IONIC LIQUID; CARBON NITRIDE; MESOPOROUS CARBON; MULTICOMPONENT SYNTHESIS; SULFATED ZIRCONIA; HIGHLY EFFICIENT; CATALYST; G-C3N4; DERIVATIVES; GREEN in [Ghafuri, Hossein; Goodarzi, Nahal; Rashidizadeh, Afsaneh; Fard, Mohammad Ali Douzandegi] Iran Univ Sci & Technol, Dept Chem, Catalysts & Organ Synth Res Lab, Tehran 1684613114, Iran in 2019, Cited 48. Safety of 2-Aminobenzamide. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6

In the present work, sulfonated highly ordered mesoporous graphitic carbon nitride (ompg-C3N4/SO3H) was synthesized successfully and employed as an efficient and reusable heterogeneous solid acid catalyst for the rapid and one-pot synthesis of 2,3-dihydroquinazolin-4(1H)-ones via the condensation of anthranilamide with aldehydes or ketones in good to excellent yields. The organocatalyst was characterized by Fourier transform infrared spectroscopy, X-ray diffraction, field emission scanning electron microscopy, energy-dispersive X-ray spectrometer, Brunauer-Emmett-Teller surface area, and thermal gravimetric and differential thermal analysis. The substantial advantages of this procedure involve short reaction times, high catalytic activity, easy workup, high purity of the products, and easy recovery and reusability of the catalyst.

Safety of 2-Aminobenzamide. About 2-Aminobenzamide, If you have any questions, you can contact Ghafuri, H; Goodarzi, N; Rashidizadeh, A; Fard, MAD or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Authors Dandia, A; Bansal, S; Sharma, R; Mahawar, DK; Rathore, KS; Meena, ML; Parewa, V in ELSEVIER SCIENCE SA published article about ARYL ALKYL ETHERS; PHOTOCATALYTIC DEGRADATION; ANTITUMOR BENZOTHIAZOLES; SELECTIVE DEPROTECTION; HETEROGENEOUS CATALYST; HYDROGEN-PRODUCTION; GREEN SYNTHESIS; QUANTUM DOTS; ORGANIC-DYES; IONIC LIQUID in [Dandia, Anshu; Bansal, Sarika; Sharma, Ruchi; Mahawar, Dinesh Kumar; Meena, Mohan Lal; Parewa, Vijay] Univ Rajasthan, Dept Chem, Ctr Adv Studies, Jaipur, Rajasthan, India; [Rathore, Kuldeep S.] Arya Coll Engn & IT, Dept Phys, Jaipur, Rajasthan, India; [Meena, Mohan Lal] Natl Taiwan Univ, Dept Chem Engn, Taipei, Taiwan in 2020, Cited 91. Recommanded Product: 2-Aminobenzamide. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6

ZnS and Cu:ZnS nanoparticles were prepared by aqueous chemical method and characterized by several analytical tools. Nanoparticles have an average size of about similar to 18 nm and possess highly open mesopores, moderate surface area, and uniform morphology. UV-vis spectra designate that doping of Cu shifted the optical response of the ZnS nanoparticles in to a visible region. These Cu:ZnS nanoparticles were employed as a photocatalyst for chemoselective synthesis of 2-substituted azoles by the reaction of benzyl bromides and 1,2-Diaminobenzene or 2-Mercaptoaniline in visible light. Analogous experiments confirmed that the reaction were proceeds through one pot C-N arylation/ CSp(3)- H oxidation/ cyclization/dehydration sequence. The enhanced catalytic activity by doping could be attributed to the presence of trapping level generated by copper doping which augments the relaxation time of electron and holes so that they are easily available for the reaction. The method was also applicable for the synthesis of quinazolin-4(3H)-ones.

Recommanded Product: 2-Aminobenzamide. About 2-Aminobenzamide, If you have any questions, you can contact Dandia, A; Bansal, S; Sharma, R; Mahawar, DK; Rathore, KS; Meena, ML; Parewa, V or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Authors Jakobsson, JE; Lu, SY; Telu, S; Pike, VW in WILEY-V C H VERLAG GMBH published article about MEDIATED SYNTHESIS; MONOXIDE; C-11; RECEPTOR in [Jakobsson, Jimmy E.; Lu, Shuiyu; Telu, Sanjay; Pike, Victor W.] NIMH, Mol Imaging Branch, NIH, 10 Ctr Dr, Bethesda, MD 20892 USA in 2020, Cited 35. Computed Properties of C7H8N2O. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6

Herein, the synthesis and use of [C-11]carbonyl difluoride for labeling heterocycles with [C-11]carbonyl groups in high molar activity is described. A very mild single-pass gas-phase conversion of [C-11]carbon monoxide into [C-11]carbonyl difluoride over silver(II) fluoride provides easy access to this new synthon in robust quantitative yield for labeling a broad range of cyclic substrates, for example, imidazolidin-2-ones, thiazolidin-2-ones, and oxazolidin-2-ones. Labeling reactions may utilize close-to-stoichiometric precursor quantities and short reaction times at room temperature in a wide range of solvents while also showing high water tolerability. The overall radiosynthesis protocol is both simple and reproducible. The required apparatus can be constructed from widely available parts and is therefore well suited to be automated for PET radiotracer production. We foresee that this straightforward method will gain wide acceptance for PET radiotracer syntheses across the radiochemistry community.

Computed Properties of C7H8N2O. About 2-Aminobenzamide, If you have any questions, you can contact Jakobsson, JE; Lu, SY; Telu, S; Pike, VW or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Facile access toN-formyl imide as anN-formylating agent for the direct synthesis ofN-formamides, benzimidazoles and quinazolinones WOS:000553219600023 published article about ACID-CATALYZED TRANSAMIDATION; N-SUBSTITUTED FORMAMIDES; CARBON-DIOXIDE; EFFICIENT SYNTHESIS; AMINES; DERIVATIVES; CARBOXAMIDES; METHANOL; OXIDATION; CO2 in [Huang, Hsin-Yi; Lin, Xiu-Yi; Yen, Shih-Yao; Liang, Chien-Fu] Natl Chung Hsing Univ, Dept Chem, Taichung 402, Taiwan in 2020, Cited 91. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6. Safety of 2-Aminobenzamide

N-Formamide synthesis usingN-formyl imide with primary and secondary amines with catalytic amounts ofp-toluenesulfonic acid monohydrate (TsOH center dot H2O) is described. This reaction is performed in water without the use of surfactants. Moreover,N-formyl imide is efficiently synthesized using acylamidines with TsOH center dot H2O in water. In addition,N-formyl imide was successfully used as a carbonyl source in the synthesis of benzimidazole and quinazolinone derivatives. Notable features ofN-formylation of amines by usingN-formyl imide include operational simplicity, oxidant- and metal-free conditions, structurally diverse products, and easy applicability to gram-scale operation.

Safety of 2-Aminobenzamide. About 2-Aminobenzamide, If you have any questions, you can contact Huang, HY; Lin, XY; Yen, SY; Liang, CF or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Computed Properties of C10H12O3. Authors Tang, ZY; Chen, XY; Zhang, WR; Sun, XF; Hou, QZ; Li, YJ; Feng, X; Chen, YR; Lv, J; Ji, L; Ding, GY; Li, D in FRONTIERS MEDIA SA published article about in [Tang, Zhaoyang; Chen, Xueyu; Zhang, Wenran; Hou, Qingzhi; Li, Yuejin; Feng, Xia; Chen, Yanru; Lv, Jian; Ji, Long; Ding, Guoyong; Li, Dong] Shandong First Med Univ & Shandong Acad Med Sci, Sch Publ Hlth, Dept Epidemiol, Tai An, Shandong, Peoples R China; [Sun, Xiangfu] Taian Traff Hosp, Tai An, Shandong, Peoples R China; [Li, Dong] Shandong First Med Univ, Affiliated Hosp 2, Tai An, Shandong, Peoples R China in 2021, Cited 48. The Name is 4-Methoxybenzyl acetate. Through research, I have a further understanding and discovery of 104-21-2

Background: Dementia, as a global public health problem, is becoming increasingly serious. As a precursor of dementia, mild cognitive impairment (MCI) plays an important role in the diagnosis and prevention of dementia. Recent studies have found a correlation between gamma-glutamyl transferase (GGT) levels and cognitive function in men. The relationship between GGT levels and cognitive function in women remains unclear because GGT activity and expression differ between the sexes. Method: We recruited a total of 2,943 Chinese women from Jidong and Taian in 2019. We grouped the participants according to GGT levels, diagnosed MCI using the Montreal Cognitive Assessment (MOCA) scale, and modeled the study outcomes using logistic regression to explore the relationship between GGT level and MCI. We also analyzed the interaction of obesity, sleep duration, and hyperuricemia with GGT in the development of MCI. Results: The prevalence of MCI increased with increasing GGT level, from the lowest quartile to the highest quartile of GGT: 8.4% (66/786), 14.2% (119/840), 17.6% (108/613), and 21.4% (151/704), respectively. At the same time, as GGT levels increased, so did the risk of MCI. In the fully adjusted model, compared with those for participants in the lowest GGT quartiles, the odds ratios (ORs), and 95% confidence intervals (CIs) for MCI for participants in the second, third, and fourth GGT quartiles were 1.49 (1.04-2.12), 1.53(1.06-2.21), and 1.88 (1.33-2.65), respectively. The risk of developing MCI was further increased in people with high GGT levels who were obese (OR = 1.96, 95% CI: 1.39-2.76, P < 0.001), slept less (OR = 1.91, 95% CI: 1.35-2.71, P < 0.001), had high levels of uric acid (OR = 1.55, 95% CI: 1.03-2.32, P < 0.001), or after menopause (OR = 2.92, 95% CI: 2.07-4.12, P < 0.001). Conclusion: We found that MCI is more common in women with elevated GGT levels, so GGT could be a potential diagnostic marker for MCI. Meanwhile, our findings indicated that women with high GGT levels had an increased risk of MCI when they were obese, sleep deprived, had high serum uric acid (SUA) levels or underwent menopause. About 4-Methoxybenzyl acetate, If you have any questions, you can contact Tang, ZY; Chen, XY; Zhang, WR; Sun, XF; Hou, QZ; Li, YJ; Feng, X; Chen, YR; Lv, J; Ji, L; Ding, GY; Li, D or concate me.. Computed Properties of C10H12O3

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem