Safety of 3-Nitrobenzaldehyde. Recently I am researching about LIGAND-ACCELERATED CATALYSIS; IMINODIACETIC ACID; MAGNETIC-PROPERTIES; METAL; SPECTROSCOPY; CHEMISTRY; ADDUCTS; WATER; IONS; IRON, Saw an article supported by the CAPESCoordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES); CNPqConselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPQ). Published in ELSEVIER SCIENCE SA in LAUSANNE ,Authors: de Andrade, JCD; Silva, LAT; Lima, CG; Chojnacki, J; Vasconcellos, MLAD; da Silva, RB; Alves, SA; da Silva, FF. The CAS is 99-61-6. Through research, I have a further understanding and discovery of 3-Nitrobenzaldehyde
This work reports the influence of experimental parameters (pH and counter-ion) in the synthesis of the 1D coordination polymer [Cu(IDA)(H2O)(2)](n). (IDA = iminodiacetate), named here Cu-IDA. Copper-manganese bimetallic coordination polymers were also obtained by isomorphic replacement into Cu-IDA structure, with different molar ratio of Cu2+ and Mn2+ ions, denoted here as Cu/Mn-IDA (0.9/0.1; 0.7/0.3 and 0.5/0.5). New coordination polymers are isostructural to Cu-IDA and amounts of manganese atoms inserted into crystalline structure were evaluated by single-crystal X-ray diffraction and Rietveld refinement. All coordination polymers obtained were also characterized by infrared absorption spectroscopy and thermogravimetric analysis. Homometallic and bimetallic compounds were evaluated as catalysts for Baylis-Hillman reaction with yields and reaction times comparable or superior to those in the literature. Compounds containing manganese cations shows higher catalytic performance, especially Cu/Mn-IDA (0.9/0.1) with yield 91% in 5 h of reaction. Results also indicate an important role played by the metallic centre in the catalytic mechanism.
Safety of 3-Nitrobenzaldehyde. About 3-Nitrobenzaldehyde, If you have any questions, you can contact de Andrade, JCD; Silva, LAT; Lima, CG; Chojnacki, J; Vasconcellos, MLAD; da Silva, RB; Alves, SA; da Silva, FF or concate me.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem