Extracurricular laboratory: Synthetic route of 3-Nitrobenzaldehyde

SDS of cas: 99-61-6. About 3-Nitrobenzaldehyde, If you have any questions, you can contact Li, HF; Khan, I; Li, MQ; Wang, Z; Wu, X; Ding, KL; Zhang, YJ or concate me.

An article Pd-Catalyzed Regio- and Enantioselective Aminoarylation of Allenols with Aryl Iodides and 2-Pyridones WOS:000649477300064 published article about STRUCTURE-BASED DESIGN; DECARBOXYLATIVE CYCLOADDITION; VINYLETHYLENE CARBONATES; BIOLOGICAL EVALUATION; INHIBITOR; CONSTRUCTION; ALLYLATION; LIGANDS in [Li, Hongfang; Khan, Ijaz; Li, Meiqi; Ding, Kuiling; Zhang, Yong Jian] Shanghai Jiao Tong Univ, Frontiers Sci Ctr Transformat Mol, Shanghai Key Lab Mol Engn Chiral Drugs, Shanghai 200240, Peoples R China; [Li, Hongfang; Wu, Xue; Zhang, Yong Jian] Yanbian Univ, Coll Sci, Dept Chem, Yanji 133002, Jilin, Peoples R China; [Wang, Zheng; Ding, Kuiling] Chinese Acad Sci, Ctr Excellence Mol Synth, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China in 2021.0, Cited 51.0. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6. SDS of cas: 99-61-6

A new asymmetric catalytic protocol for the synthesis of enantioenriched N-allyl 2-pyrodones has been developed via the first Pd-catalyzed regio- and enantioselective aminoarylation of allenols with aryl iodides and 2-pyridones. By using a palladium complex generated in situ from Pd-2(dba)(3)center dot CHCl3 and (S,S,S)-SKP as a catalyst, the three-component aminoarylation proceeded smoothly to afford a variety of functionalized N-allylic 2-pyridones in high yields with good regioselectivities and excellent enantioselectivities.

SDS of cas: 99-61-6. About 3-Nitrobenzaldehyde, If you have any questions, you can contact Li, HF; Khan, I; Li, MQ; Wang, Z; Wu, X; Ding, KL; Zhang, YJ or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem